公开(公告)号：WO2010062493A2

公开(公告)日：2010-06-03

申请号：PCT/US2009/061026

申请日：2009-10-16

Applicant: CHEVRON U.S.A. INC. ,  TIMKEN, Hye-Kyung ,  ELOMARI, Saleh ,  HARRIS, Thomas, V. ,  ZIEMER, James, N.

Inventor： TIMKEN, Hye-Kyung ,  ELOMARI, Saleh ,  HARRIS, Thomas, V. ,  ZIEMER, James, N.

IPC: B01J38/00 ,  B01J37/34 ,  B01J31/14 ,  C07C2/66

CPC classification number: B01J38/48 ,  B01J31/0284 ,  B01J31/40 ,  C07C2/58 ,  C10G29/205 ,  Y02P20/584 ,  C07C9/16

Abstract: A process for regenerating a spent ionic liquid catalyst including (a) applying a voltage across one or more pairs of electrodes immersed in a spent ionic liquid catalyst comprising conjunct polymer-metal halide complexes to provide freed conjunct polymers and a regenerated ionic liquid catalyst; and (b) separating the freed conjunct polymers from the regenerated ionic liquid catalyst is described. An alkylation process incorporating the regeneration process is also described.

Abstract translation: 一种用于再生废弃离子液体催化剂的方法，包括（a）在浸没在包含结合的聚合物 - 金属卤化物络合物的废离子液体催化剂中的一对或多个电极上施加电压以提供释放的结合聚合物和再生的离子液体催化剂; 和（b）从再生的离子液体催化剂中分离出释放的结合聚合物。 还描述了结合再生过程的烷基化方法。

公开(公告)号：WO2007124343A3

公开(公告)日：2008-09-12

申请号：PCT/US2007066934

申请日：2007-04-19

Applicant: CHEVRON USA INC ,  ELOMARI SALEH ,  HARRIS THOMAS V ,  TIMKEN HYE KYUNG C ,  TRUMBULL STEVEN E

Inventor： ELOMARI SALEH ,  HARRIS THOMAS V ,  TIMKEN HYE KYUNG C ,  TRUMBULL STEVEN E

IPC: B01J20/34

CPC classification number: B01J38/48 ,  B01J31/0284 ,  B01J31/0298 ,  B01J31/4092

Abstract: A process for regenerating a used acidic ionic liquid catalyst comprising contacting the used ionic liquid catalyst with at teas! one metal in a regeneration zone in the absence of added hydrogen under regeneration conditions for a time sufficient to increase the activity of the ionic liquid catalyst is described. In one embodiment, regeneration is conducted in the presence of a hydrocarbon solvent.

Abstract translation: 一种再生使用的酸性离子液体催化剂的方法，包括使用过的离子液体催化剂与 描述了在再生条件下在没有加入氢的情况下再生区中的一种金属足以提高离子液体催化剂活性的时间。 在一个实施方案中，在烃溶剂存在下进行再生。

公开(公告)号：WO2007124359A3

公开(公告)日：2008-09-04

申请号：PCT/US2007066966

申请日：2007-04-19

Applicant: CHEVRON USA INC ,  ELOMARI SALEH ,  HARRIS THOMAS V

Inventor： ELOMARI SALEH ,  HARRIS THOMAS V

IPC: B01J20/34

CPC classification number: B01J38/10 ,  B01J31/0239 ,  B01J31/0284 ,  B01J31/0288 ,  B01J31/40 ,  B01J38/58 ,  B01J2231/4205

Abstract: A process for regenerating a used acidic ionic liquid catalyst comprising contacting the used ionic liquid catalyst with at least one 'regeneration' metal in a regeneration zone in the presence of added hydrogen under regeneration conditions for a time sufficient to increase the activity of the ionic liquid catalyst is described. In one embodiment, regeneration is conducted in the presence of a hydrocarbon solvent.

Abstract translation: 一种用于再生所用酸性离子液体催化剂的方法，包括在再生条件下，在加入的氢气存在下，将所用离子液体催化剂与再生区中的至少一种“再生”金属接触一段足以提高离子液体活性的时间 催化剂。 在一个实施方案中，在烃溶剂存在下进行再生。

公开(公告)号：WO2007078607A3

公开(公告)日：2008-04-03

申请号：PCT/US2006046944

申请日：2006-12-07

Applicant: CHEVRON USA INC ,  ELOMARI SALEH ,  KRUG RUSSELL ,  HARRIS THOMAS V ,  DRIVER MICHAEL S

Inventor： ELOMARI SALEH ,  KRUG RUSSELL ,  HARRIS THOMAS V ,  DRIVER MICHAEL S

IPC: C07C2/00 ,  C07C2/58 ,  C07C2/62 ,  C10G50/02 ,  C10G53/02

CPC classification number: C10M127/02 ,  C10G2300/1081 ,  C10G2300/1088 ,  C10G2400/10 ,  C10M105/04 ,  C10M109/02 ,  C10M177/00 ,  C10M2205/0285 ,  C10N2220/022 ,  C10N2220/023 ,  C10N2230/02 ,  C10N2270/00 ,  C10M2203/0206

Abstract: A process and method for making a superior lubricant or distillate fuel component by the oligomerization of a mixture comprising olefins to form an oligomer and the alkylation of the oligomer with isoparaffins to produce an alkylated ("capped") olefin oligomer preferably using an acidic chloroaluminate ionic liquid catalyst system. Preferably the ionic liquid catalyst system comprises a Bronsted acid.

Abstract translation: 通过包含烯烃的混合物的低聚制备优异的润滑剂或馏出燃料成分的方法和方法，以形成低聚物，并用异链烷烃烷基化低聚物以产生烷基化（“封端”）烯烃低聚物，优选使用酸性氯铝酸盐离子 液体催化剂体系。 优选地，离子液体催化剂体系包含布朗斯台德酸。

公开(公告)号：WO2007124359A2

公开(公告)日：2007-11-01

申请号：PCT/US2007/066966

申请日：2007-04-19

Applicant: CHEVRON U.S.A. INC. ,  ELOMARI, Saleh ,  HARRIS, Thomas V.

Inventor： ELOMARI, Saleh ,  HARRIS, Thomas V.

IPC: B01J38/10

CPC classification number: B01J38/10 ,  B01J31/0239 ,  B01J31/0284 ,  B01J31/0288 ,  B01J31/40 ,  B01J38/58 ,  B01J2231/4205

Abstract: A process for regenerating a used acidic ionic liquid catalyst comprising contacting the used ionic liquid catalyst with at least one 'regeneration' metal in a regeneration zone in the presence of added hydrogen under regeneration conditions for a time sufficient to increase the activity of the ionic liquid catalyst is described. In one embodiment, regeneration is conducted in the presence of a hydrocarbon solvent.

Abstract translation: 一种用于再生所用酸性离子液体催化剂的方法，包括在再生条件下，在加入的氢气存在下，将所用离子液体催化剂与再生区中的至少一种“再生”金属接触一段足以提高离子液体活性的时间 描述催化剂。 在一个实施方案中，在烃溶剂的存在下进行再生。

公开(公告)号：WO2010062493A3

公开(公告)日：2010-07-22

申请号：PCT/US2009061026

申请日：2009-10-16

Applicant: CHEVRON USA INC ,  TIMKEN HYE-KYUNG ,  ELOMARI SALEH ,  HARRIS THOMAS V ,  ZIEMER JAMES N

Inventor： TIMKEN HYE-KYUNG ,  ELOMARI SALEH ,  HARRIS THOMAS V ,  ZIEMER JAMES N

IPC: B01J38/00 ,  B01J31/14 ,  B01J37/34 ,  C07C2/66

CPC classification number: B01J38/48 ,  B01J31/0284 ,  B01J31/40 ,  C07C2/58 ,  C10G29/205 ,  Y02P20/584 ,  C07C9/16

Abstract: A process for regenerating a spent ionic liquid catalyst including (a) applying a voltage across one or more pairs of electrodes immersed in a spent ionic liquid catalyst comprising conjunct polymer-metal halide complexes to provide freed conjunct polymers and a regenerated ionic liquid catalyst; and (b) separating the freed conjunct polymers from the regenerated ionic liquid catalyst is described. An alkylation process incorporating the regeneration process is also described.

Abstract translation: 一种再生包括（a）将在一个或多个对浸渍在废离子液体催化剂包含电极混合聚合物 - 金属卤化物的复合物，以提供释放的混合聚合物和再生的离子液体催化剂的电压的废离子液体催化剂的方法; 和（b）描述了从再生的离子液体催化剂中分离游离的混合聚合物。 还描述了结合再生过程的烷基化过程。

公开(公告)号：WO2009079079A1

公开(公告)日：2009-06-25

申请号：PCT/US2008/079567

申请日：2008-10-10

Applicant: CHEVRON U.S.A. INC. ,  ELOMARI, Saleh ,  TIMKEN, Hye-kyung C. ,  LACHEEN, Howard S. ,  HARRIS, Thomas V. ,  CAMPBELL, Robert W.

Inventor： ELOMARI, Saleh ,  TIMKEN, Hye-kyung C. ,  LACHEEN, Howard S. ,  HARRIS, Thomas V. ,  CAMPBELL, Robert W.

IPC: B01J20/34

CPC classification number: B01J31/40 ,  B01J27/32 ,  B01J31/0239 ,  B01J31/0284 ,  B01J31/0298 ,  B01J38/485

Abstract: A process for removing metal halides from regenerated ionic liquid catalyst comprising interacting a regenerated ammonium-based metal-halide ionic liquid catalyst or an ammonium-based metal-halide ionic liquid catalyst undergoing regeneration with either the parent ammonium halide salt from which the ionic liquid catalyst was made or a corresponding mixed salt having an ammonium halide to metal halide molar ratio of 0 to less than 2.0 is disclosed.

Abstract translation: 一种从再生离子液体催化剂除去金属卤化物的方法，包括将再生的铵基金属卤化物离子液体催化剂或经过再生的铵基金属卤化物离子液体催化剂与母体卤化铵盐相互作用，离子液体催化剂 公开了卤化铵与金属卤化物的摩尔比为0以上且小于2.0的相应的混合盐。

公开(公告)号：WO2008076722A1

公开(公告)日：2008-06-26

申请号：PCT/US2007/087121

申请日：2007-12-12

Applicant: CHEVRON U.S.A. INC. ,  HARRIS, Thomas V. ,  DRIVER, Michael ,  ELOMARI, Saleh ,  TIMKEN, Hye-kyung C.

Inventor： HARRIS, Thomas V. ,  DRIVER, Michael ,  ELOMARI, Saleh ,  TIMKEN, Hye-kyung C.

IPC: C07C2/56

CPC classification number: C10G29/205 ,  C10G2300/1081 ,  C10G2300/1088 ,  C10G2400/02 ,  Y10S585/906

Abstract: A process for the production of a high quality gasoline blending components from refinery process streams by the alkylation of light isoparaffins with olefins using an ionic liquid catalyst is disclosed. The alkylation process comprises contacting a hydrocarbon mixture comprising at least one olefin having from 2 to 6 carbon atoms and at least one isoparaffin having from 3 to 6 carbon atoms under alkylation conditions, said catalyst comprising a mixture of at least one acidic ionic liquid and at least one alkyl halide. The alkylhalide by reacting to at least a portion of the olefin with a hydrogen halide.

Abstract translation: 公开了一种通过使用离子液体催化剂通过烯烃使轻质异链烷烃烷基化从炼厂工艺流中生产高品质汽油调和组分的方法。 烷基化方法包括在烷基化条件下使包含至少一种具有2至6个碳原子的烯烃和至少一种具有3至6个碳原子的异链烷烃的烃混合物接触，所述催化剂包含至少一种酸性离子液体和 至少一种烷基卤化物。 通过使烷基卤与至少一部分烯烃与卤化氢反应。

公开(公告)号：WO2007073441A1

公开(公告)日：2007-06-28

申请号：PCT/US2006/041064

申请日：2006-10-19

Applicant: CHEVRON U.S.A. INC. ,  ELOMARI, Saleh ,  HARRIS, Thomas, V.

Inventor： ELOMARI, Saleh ,  HARRIS, Thomas, V.

IPC: B01J20/34

CPC classification number: B01J31/4092 ,  B01J27/30 ,  B01J27/32 ,  B01J31/0284 ,  B01J31/0288 ,  B01J31/0298 ,  B01J35/12 ,  B01J38/50 ,  B01J38/54 ,  B01J2231/12 ,  B01J2231/20 ,  B01J2231/4205 ,  B01J2231/44 ,  B01J2531/31 ,  C01B17/905 ,  C07D213/20 ,  Y02P20/584

Abstract: A process for regenerating a used acidic catalyst which has been deactivated by conjunct polymers by removing the conjunct polymers so as to increase the activity of the catalyst is disclosed. Methods for removing the conjunct polymers include hydrogenation, addition of a basic reagent and alkylation. The methods are applicable to all acidic catalysts and are described with reference to certain ionic liquid catalysts.

Abstract translation: 公开了一种通过除去结合聚合物以使催化剂的活性提高而使结构聚合物失活的酸性催化剂再生的方法。 去除结合聚合物的方法包括氢化，加入碱性试剂和烷基化。 该方法适用于所有的酸性催化剂，并参照某些离子液体催化剂进行了描述。

公开(公告)号：WO2007073440A1

公开(公告)日：2007-06-28

申请号：PCT/US2006/041063

申请日：2006-10-19

Applicant: CHEVRON U.S.A. INC. ,  ELOMARI, Saleh ,  HARRIS, Thomas, V.

Inventor： ELOMARI, Saleh ,  HARRIS, Thomas, V.

IPC: B01J21/20 ,  B01J38/48

CPC classification number: B01J27/32 ,  B01J27/125 ,  B01J31/0278 ,  B01J31/0284 ,  B01J31/0287 ,  B01J31/0288 ,  B01J31/40 ,  C07C2/862 ,  Y02P20/584

Abstract: A used acidic ionic liquid catalyst, which has been deactivated by conjunct polymers, is regenerated by combining the used catalyst, a metal and a Broensted acid to hydrogenate the conjunct polymer. Regenerating a used acidic ionic liquid catalyst, which has been deactivated by conjunct polymers, includes: combining the used ionic liquid catalyst, a metal and HCI in a reaction zone under hydrogenation conditions to hydrogenate a portion of the conjunct polymer; removing reaction product from the reaction zone; mixing the removed reaction product with a hydrocarbon solvent in which the hydrogenated conjunct polymers are soluble; allowing the mixture to separate into a lighter phase which contains the hydrogenated conjunct polymers, and a heavier phase which contains a regenerated ionic liquid catalyst; and recovering at least a portion of the heavier phase is also disclosed.

Abstract translation: 已经通过结合聚合物失活的已使用的酸性离子液体催化剂通过组合使用的催化剂，金属和布朗斯台德酸来氢化结合聚合物来再生。 已经被结合聚合物失活的废酸性离子液体催化剂的再生包括：在氢化条件下将反应区中使用的离子液体催化剂，金属和HCl混合，氢化一部分结合聚合物; 从反应区除去反应产物; 将除去的反应产物与其中氢化结合聚合物可溶的烃溶剂混合; 允许混合物分离成包含氢化结合聚合物的较轻相和含有再生离子液体催化剂的较重相; 并且还公开了至少一部分较重相的回收。