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    IONIC LIQUID CATALYST HAVING ENHANCED ACTIVITY
    5.
    发明申请
    IONIC LIQUID CATALYST HAVING ENHANCED ACTIVITY 审中-公开
    具有增强活性的离子液体催化剂

    公开(公告)号：WO2007078381A2

    公开(公告)日：2007-07-12

    申请号：PCT/US2006041100

    申请日：2006-10-19

    Applicant: CHEVRON USA INC ,  ELOMARI SALEH ,  HARRIS THOMAS V

    Inventor： ELOMARI SALEH ,  HARRIS THOMAS V

    IPC: B01J27/132 ,  B01J27/06 ,  B01J27/135 ,  B01J27/138 ,  B01J31/00 ,  C07C15/46 ,  C07C45/46

    CPC classification number: C07D213/20 ,  B01J27/125 ,  B01J27/32 ,  B01J31/0278 ,  B01J31/0284 ,  B01J31/0288 ,  B01J31/40 ,  C07C2/62 ,  C07C2531/02 ,  Y02P20/584 ,  C07C9/16

    Abstract: A process for producing acidic ionic liquid catalyst having enhanced activity comprising combining fresh acidic ionic liquid catalyst, a metal and a Broensted acid in a reaction zone for a time sufficient to increase the activity of the ionic liquid catalyst is disclosed. A process for producing acidic ionic liquid catalyst having enhanced activity comprising the steps of combining fresh ionic liquid catalyst, a metal and HCI in a reaction zone for a time sufficient to increase the activity of the fresh ionic liquid catalyst; removing reaction product from the reaction zone and recovering at least a portion of the treated ionic liquid catalyst is also disclosed.

    Abstract translation: 公开了一种生产具有增强活性的酸性离子液体催化剂的方法，其包括在反应区中将新鲜的酸性离子液体催化剂，金属和布朗斯台德酸组合足以提高离子液体催化剂活性的时间。 一种生产具有增强活性的酸性离子液体催化剂的方法，包括以下步骤：将新鲜离子液体催化剂，金属和HCl在反应区中混合足以增加新鲜离子液体催化剂活性的时间; 从反应区除去反应产物并回收至少一部分经处理的离子液体催化剂。

    BASE OIL COMPOSITION COMPRISING OLIGOMERIZED OLEFINS
    6.
    发明申请
    BASE OIL COMPOSITION COMPRISING OLIGOMERIZED OLEFINS 审中-公开
    包含低聚烯烃的基础油组合物

    公开(公告)号：WO2011019564A4

    公开(公告)日：2011-09-01

    申请号：PCT/US2010044410

    申请日：2010-08-04

    Applicant: CHEVRON USA INC ,  ELOMARI SALEH ,  MILLER STEPHEN J

    Inventor： ELOMARI SALEH ,  MILLER STEPHEN J

    IPC: C10M105/04 ,  C07C2/22

    CPC classification number: C10M107/06 ,  C10G50/02 ,  C10G2300/1092 ,  C10G2300/301 ,  C10G2300/302 ,  C10G2300/304 ,  C10G2400/10 ,  C10M107/10 ,  C10M2205/0245 ,  C10N2220/022 ,  C10N2220/023 ,  C10N2270/00 ,  C10M2205/0285

    Abstract: We provide a base oil, comprising one or more oligomerized olefins, wherein the base oil has: a. a kinematic viscosity at 100 °C greater than 2.9 mm2/s; b. a viscosity index from 25 to 90; and c. a cloud point less than -55 °C. We provide a base oil made by oligomerizing propylene in an ionic liquid catalyst, where the base oil has a viscosity index from 25 to 90 and the base oil is colorless. We also provide a base oil made by oligomerizing an olefin feed comprising propylene in an acidic alkyl-pyridinium chloroaluminate ionic liquid, wherein the base oil has a viscosity index at 100 °C greater than 2.9 mm2/s, a viscosity index from 25 to 90, and a cloud point less than -55 °C.

    Abstract translation: 我们提供一种基础油，其包含一种或多种低聚烯烃，其中所述基础油具有：a。 100℃下的运动粘度大于2.9 mm2 / s; 湾 粘度指数为25〜90; 和c。 浊点小于-55°C。 我们提供通过在离子液体催化剂中使丙烯低聚制得的基础油，其中基础油的粘度指数为25至90，基础油为无色。 我们还提供通过在酸性烷基 - 氯铬酸吡啶鎓离子液体中将包含丙烯的烯烃进料低聚制得的基础油，其中基油在100℃下的粘度指数大于2.9mm 2 / s，粘度指数为25至90 ，浊点小于-55℃。

    AN IONIC LIQUID CATALYST HAVING A HIGH MOLAR RATIO OF ALUMINUM TO NITROGEN
    7.
    发明申请
    AN IONIC LIQUID CATALYST HAVING A HIGH MOLAR RATIO OF ALUMINUM TO NITROGEN 审中-公开
    一种离子液体催化剂，具有较高的铝比摩尔比的氮对氮

    公开(公告)号：WO2010074835A3

    公开(公告)日：2010-08-19

    申请号：PCT/US2009064596

    申请日：2009-11-16

    Applicant: CHEVRON USA INC ,  LACHEEN HOWARD S ,  ELOMARI SALEH

    Inventor： LACHEEN HOWARD S ,  ELOMARI SALEH

    IPC: B01J31/18 ,  B01J27/10 ,  B01J27/24 ,  B01J31/14

    CPC classification number: B01J31/0278 ,  B01J31/0284 ,  B01J31/26 ,  B01J31/40 ,  B01J2231/32 ,  C07C2/60 ,  C07C2531/14 ,  C10G29/205 ,  C10G2300/1081 ,  C10G2300/1088 ,  C10G2300/305 ,  Y02P20/584 ,  C07C9/00

    Abstract: An ionic liquid catalyst is provided comprising an ammonium chloroaluminate salt, and having a molar ratio of Al to N greater than 2.0 when held at a temperature at or below 25°C for at least two hours. There is also provided an ionic liquid catalyst comprising an alkyl-pyridinium haloaluminate and an impurity, wherein the ionic liquid catalyst has a molar ratio of Al to N greater than 2.0 when held at a temperature at or below 25°C for at least two hours. In a third embodiment, there is provided an ionic liquid system for isoparaffin/olefin alkylation, comprising a quaternary ammonium chloroaluminate, a conjunct polymer, and a hydrogen chloride. The ionic liquid system has a molar ratio of Al to N from 2.1 to 8.0. Less than 0.1 wt% AlCl3 precipitates from the ionic liquid system when it is held for three hours or longer at or below 25°C.

    Abstract translation: 提供一种离子液体催化剂，其包含氯铝酸铵盐，并且当在等于或低于25℃的温度下保持至少2小时时Al与N的摩尔比大于2.0。 还提供了包含烷基 - 吡啶鎓卤代铝酸盐和杂质的离子液体催化剂，其中当在25℃或低于25℃的温度下保持至少2小时时，离子液体催化剂的Al与N的摩尔比大于2.0 。 在第三个实施方案中，提供了用于异链烷烃/烯烃烷基化的离子液体体系，其包含季铵氯铝酸盐，混合聚合物和氯化氢。 该离子液体体系具有2.1至8.0的Al与N的摩尔比。 当其在25℃或低于25℃下保持三小时或更长时，小于0.1重量％的AlCl3从离子液体体系中沉淀。

    PROCESS TO MAKE A LIQUID CATALYST HAVING A HIGH MOLAR RATIO OF ALUMINUM TO NITROGEN
    8.
    发明申请
    PROCESS TO MAKE A LIQUID CATALYST HAVING A HIGH MOLAR RATIO OF ALUMINUM TO NITROGEN 审中-公开
    制备具有高铝比的氮气的液体催化剂

    公开(公告)号：WO2010074836A2

    公开(公告)日：2010-07-01

    申请号：PCT/US2009064600

    申请日：2009-11-16

    Applicant: CHEVRON USA INC ,  LACHEEN HOWARD S ,  ELOMARI SALEH

    Inventor： LACHEEN HOWARD S ,  ELOMARI SALEH

    IPC: B01J31/18 ,  B01J27/24 ,  B01J31/14 ,  B01J37/04 ,  C07C2/58

    CPC classification number: C10G45/04 ,  B01J31/0284 ,  B01J31/0298 ,  B01J31/06 ,  B01J2231/32 ,  C07C2/58 ,  C10G29/205 ,  C10G45/00 ,  C10G45/46 ,  C10G47/02 ,  C10G50/00 ,  C10G2300/305 ,  C10G2400/02 ,  C07C9/16

    Abstract: A process to make a liquid catalyst having a molar ratio of Al to N greater than 2.0, comprising: a) using an ammonium-based ionic liquid catalyst to catalyze a reaction, wherein the ammonium-based ionic liquid catalyst builds up an impurity during the reaction; and b) mixing the ammonium-based ionic liquid catalyst, having an impurity, with aluminum. There is also provided a process for isoparaffin/olefin alkylation, wherein the ionic liquid catalyst comprises a quaternary ammonium ionic liquid salt; and wherein the ionic liquid catalyst has a molar ratio of Al to N greater than 2.0 when held at a temperature at or below 25°C for at least two hours. There is also provided a method for making a catalyst having a molar ratio of Al to N greater than 2.0, and a process for hydroconversion comprising maintaining a level of conjunct polymer in an ionic liquid catalyst.

    Abstract translation: 一种制备Al与N的摩尔比大于2.0的液体催化剂的方法，包括：a）使用铵基离子液体催化剂催化反应，其中所述铵基离子液体催化剂在 反应; 和b）将具有杂质的铵基离子液体催化剂与铝混合。 还提供了异链烷烃/烯烃烷基化方法，其中离子液体催化剂包含季铵离子液体盐; 并且其中当将所述离子液体催化剂在等于或低于25℃的温度下保持至少2小时时，Al与N的摩尔比大于2.0。 还提供了制备Al与N摩尔比大于2.0的催化剂的方法，以及加氢转化方法，包括保持离子液体催化剂中的结合聚合物的含量。

    AN IONIC LIQUID CATALYST HAVING A HIGH MOLAR RATIO OF ALUMINUM TO NITROGEN
    9.
    发明申请
    AN IONIC LIQUID CATALYST HAVING A HIGH MOLAR RATIO OF ALUMINUM TO NITROGEN 审中-公开
    具有铝的高摩尔比的离子液体催化剂

    公开(公告)号：WO2010074835A2

    公开(公告)日：2010-07-01

    申请号：PCT/US2009064596

    申请日：2009-11-16

    Applicant: CHEVRON USA INC ,  LACHEEN HOWARD S ,  ELOMARI SALEH

    Inventor： LACHEEN HOWARD S ,  ELOMARI SALEH

    IPC: B01J31/18 ,  B01J27/10 ,  B01J27/24 ,  B01J31/14

    CPC classification number: B01J31/0278 ,  B01J31/0284 ,  B01J31/26 ,  B01J31/40 ,  B01J2231/32 ,  C07C2/60 ,  C07C2531/14 ,  C10G29/205 ,  C10G2300/1081 ,  C10G2300/1088 ,  C10G2300/305 ,  Y02P20/584 ,  C07C9/00

    Abstract: An ionic liquid catalyst is provided comprising an ammonium chloroaluminate salt, and having a molar ratio of Al to N greater than 2.0 when held at a temperature at or below 25°C for at least two hours. There is also provided an ionic liquid catalyst comprising an alkyl-pyridinium haloaluminate and an impurity, wherein the ionic liquid catalyst has a molar ratio of Al to N greater than 2.0 when held at a temperature at or below 25°C for at least two hours. In a third embodiment, there is provided an ionic liquid system for isoparaffin/olefin alkylation, comprising a quaternary ammonium chloroaluminate, a conjunct polymer, and a hydrogen chloride. The ionic liquid system has a molar ratio of Al to N from 2.1 to 8.0. Less than 0.1 wt% AlCl3 precipitates from the ionic liquid system when it is held for three hours or longer at or below 25°C.

    Abstract translation: 提供离子液体催化剂，其包含氯铝酸铵盐，并且当在25℃或低于25℃的温度保持至少2小时时，Al与N的摩尔比大于2.0。 还提供了一种离子液体催化剂，其包含烷基吡啶鎓卤化铝酸盐和杂质，其中离子液体催化剂的摩尔比Al大于2.0时，保持在25℃或低于25℃的温度下至少2小时 。 在第三个实施方案中，提供了一种用于异链烷烃/烯烃烷基化的离子液体体系，其包括氯铝酸季铵，结合聚合物和氯化氢。 离子液体体系的Al与N的摩尔比为2.1〜8.0。 当离子液体系统在25℃或更低温度下保持3小时或更长时间时，小于0.1重量％的AlCl 3会沉淀出来。

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