公开(公告)号：WO2009152301A2

公开(公告)日：2009-12-17

申请号：PCT/US2009/047000

申请日：2009-06-11

Applicant: 3M INNOVATIVE PROPERTIES COMPANY ,  GOENNER, Emily, S. ,  GREGAR, Travis, Q. ,  KOLB, Brant, U. ,  SCHULTZ, William, J. ,  THUNHORST, Kristin, L. ,  HINE, Andrew, M. ,  NELSON, James, M.

Inventor： GOENNER, Emily, S. ,  GREGAR, Travis, Q. ,  KOLB, Brant, U. ,  SCHULTZ, William, J. ,  THUNHORST, Kristin, L. ,  HINE, Andrew, M. ,  NELSON, James, M.

IPC: C08K9/04 ,  C08J5/06 ,  C08K9/06 ,  C09C1/30 ,  C09D7/12

CPC classification number: C09C1/3081 ,  B82Y30/00 ,  C01P2004/03 ,  C01P2004/64 ,  C01P2006/22 ,  C08J5/005 ,  C08J2333/06 ,  C08K3/36 ,  C08K9/04 ,  C09C1/3063 ,  C09C1/3072 ,  C09D7/62

Abstract: Various methods of treating surface-modified nanoparticles are described. Dual-ion exchange procedures (anion exchange and cation exchange), as well-as subsequent end-capping are described. Both ionically-bonded and covalently-bonded end-capping agents are discussed. The resulting low ion content, particularly low alkali metal and alkaline metal oxide ion content, treated, surface-modified nanoparticles, including such nanoparticles in a resin system, are also disclosed. Effects of low ion content on various properties of the resulting resin system, including blister-resistance, optical clarity, and rheology are included.

Abstract translation: 描述了处理表面改性纳米颗粒的各种方法。 描述了双离子交换程序（阴离子交换和阳离子交换）以及随后的封端。 讨论了离子键合和共价键合的封端剂。 还公开了所得的低离子含量，特别是低碱金属和碱金属氧化物离子含量，在树脂体系中处理的包括这种纳米颗粒的表面改性纳米颗粒。 包括低离子含量对所得树脂体系的各种性能的影响，包括防起泡，光学透明度和流变性。

公开(公告)号：WO2008027979A2

公开(公告)日：2008-03-06

申请号：PCT/US2007077130

申请日：2007-08-29

Applicant: 3M INNOVATIVE PROPERTIES CO ,  GOENNER EMILY S ,  CREEL HOWARD S ,  HINE ANDREW M ,  KOLB BRANT U ,  PORTELLI GENE B ,  THOMPSON WENDY L

Inventor： GOENNER EMILY S ,  CREEL HOWARD S ,  HINE ANDREW M ,  KOLB BRANT U ,  PORTELLI GENE B ,  THOMPSON WENDY L

IPC: C09D7/12

CPC classification number: C09D167/06 ,  C08K3/36 ,  C08K9/06 ,  C09D7/62 ,  C09D7/67 ,  C09D7/68 ,  C08L2666/54

Abstract: Resin systems comprising a crosslinkable resin, a reactive diluent, and a plurality of reactive, surface-modified nanoparticles; and gel coats including such resin systems are described. Articles having such compositions attached to a surface of a substrate, e.g., a fibrous reinforced substrate, are also described.

Abstract translation: 包含可交联树脂，反应性稀释剂和多种反应性表面改性纳米粒子的树脂体系; 描述了包括这种树脂体系的胶衣。 还描述了具有这种组合物的物品，所述物品附着于基底的表面，例如纤维增强基底。

公开(公告)号：WO2010005710A1

公开(公告)日：2010-01-14

申请号：PCT/US2009/047465

申请日：2009-06-16

Applicant: 3M INNOVATIVE PROPERTIES COMPANY ,  THOMPSON, Wendy, L. ,  SCHULTZ, William, J. ,  KROPP, Michael, A. ,  SETH, Jayshree ,  GOETZ, Douglas, P. ,  HINE, Andrew, M.

Inventor： THOMPSON, Wendy, L. ,  SCHULTZ, William, J. ,  KROPP, Michael, A. ,  SETH, Jayshree ,  GOETZ, Douglas, P. ,  HINE, Andrew, M.

IPC: C08K3/00 ,  C08L63/00

CPC classification number: C08L63/00 ,  C08K9/04 ,  C08L51/003 ,  C08L2666/04 ,  C08L2666/54

Abstract: Toughened curable compositions are described. The curable compositions include a curable resin, surface-modified nanoparticles, and rubber nano-domains. Both core-shell rubber nano-domains, and nano-rubber domains arising from self-assembled block co-polymers are disclosed. Toughened, cured resin compositions, and articles comprising such cured compositions are also discussed.

Abstract translation: 描述了增韧的可固化组合物。 可固化组合物包括可固化树脂，表面改性纳米颗粒和橡胶纳米结构域。 公开了两种核 - 壳橡胶纳米域和由自组装嵌段共聚物引起的纳米橡胶畴。 还讨论了增韧的固化树脂组合物和包含这种固化组合物的制品。

公开(公告)号：WO2008027979A3

公开(公告)日：2008-03-06

申请号：PCT/US2007/077130

申请日：2007-08-29

Applicant: 3M INNOVATIVE PROPERTIES COMPANY ,  GOENNER, Emily, S. ,  CREEL, Howard, S. ,  HINE, Andrew, M. ,  KOLB, Brant, U. ,  PORTELLI, Gene, B. ,  THOMPSON, Wendy, L.

Inventor： GOENNER, Emily, S. ,  CREEL, Howard, S. ,  HINE, Andrew, M. ,  KOLB, Brant, U. ,  PORTELLI, Gene, B. ,  THOMPSON, Wendy, L.

IPC: C09D7/12

Abstract: Resin systems comprising a crosslinkable resin, a reactive diluent, and a plurality of reactive, surface-modified nanoparticles; and gel coats including such resin systems are described. Articles having such compositions attached to a surface of a substrate, e.g., a fibrous reinforced substrate, are also described.

公开(公告)号：WO2009152301A3

公开(公告)日：2010-02-11

申请号：PCT/US2009047000

申请日：2009-06-11

Applicant: 3M INNOVATIVE PROPERTIES CO ,  GOENNER EMILY S ,  GREGAR TRAVIS Q ,  KOLB BRANT U ,  SCHULTZ WILLIAM J ,  THUNHORST KRISTIN L ,  HINE ANDREW M ,  NELSON JAMES M

Inventor： GOENNER EMILY S ,  GREGAR TRAVIS Q ,  KOLB BRANT U ,  SCHULTZ WILLIAM J ,  THUNHORST KRISTIN L ,  HINE ANDREW M ,  NELSON JAMES M

IPC: C08K9/04 ,  C08J5/00 ,  C08K9/06 ,  C09C1/30 ,  C09D7/12

CPC classification number: C09C1/3081 ,  B82Y30/00 ,  C01P2004/03 ,  C01P2004/64 ,  C01P2006/22 ,  C08J5/005 ,  C08J2333/06 ,  C08K3/36 ,  C08K9/04 ,  C09C1/3063 ,  C09C1/3072 ,  C09D7/62

Abstract: Various methods of treating surface-modified nanoparticles are described. Dual-ion exchange procedures (anion exchange and cation exchange), as well-as subsequent end-capping are described. Both ionically-bonded and covalently-bonded end-capping agents are discussed. The resulting low ion content, particularly low alkali metal and alkaline metal oxide ion content, treated, surface-modified nanoparticles, including such nanoparticles in a resin system, are also disclosed. Effects of low ion content on various properties of the resulting resin system, including blister-resistance, optical clarity, and rheology are included.

Abstract translation: 描述了处理表面改性纳米颗粒的各种方法。 描述了双离子交换程序（阴离子交换和阳离子交换）以及随后的封端。 讨论了离子键合和共价键合的封端剂。 还公开了所得到的低离子含量，特别是低碱金属和碱金属氧化物离子含量，在树脂体系中处理的包括这种纳米颗粒的表面改性纳米颗粒。 包括低离子含量对所得树脂体系的各种性能的影响，包括防起泡，光学透明度和流变性。

公开(公告)号：WO2009152296A1

公开(公告)日：2009-12-17

申请号：PCT/US2009/046992

申请日：2009-06-11

Applicant: 3M INNOVATIVE PROPERTIES COMPANY ,  GOENNER, Emily, S. ,  GREGAR, Travis, Q. ,  KOLB, Brant, U. ,  SCHULTZ, William, J. ,  THUNHORST, Kristin, L. ,  HINE, Andrew, M. ,  NELSON, James, M.

Inventor： GOENNER, Emily, S. ,  GREGAR, Travis, Q. ,  KOLB, Brant, U. ,  SCHULTZ, William, J. ,  THUNHORST, Kristin, L. ,  HINE, Andrew, M. ,  NELSON, James, M.

IPC: C08K9/04 ,  C08K9/06 ,  C08J5/00 ,  C09C1/30 ,  C09D7/12

CPC classification number: C09C1/3081 ,  B82Y30/00 ,  C01P2004/03 ,  C01P2004/64 ,  C01P2006/22 ,  C08J5/005 ,  C08J2333/06 ,  C08K3/36 ,  C08K9/04 ,  C09C1/3063 ,  C09C1/3072 ,  C09D7/62

Abstract: End-capped, surface-modified, silica nanoparticles are described. The resulting treated, surface-modified nanoparticles, including such nanoparticles in a resin system, are also disclosed. Effects of such surface treatments on various properties of the resulting resin system, including blister-resistance, optical clarity, and rheology are included.

Abstract translation: 描述了封端的表面改性的二氧化硅纳米颗粒。 还公开了在树脂体系中包含这些纳米颗粒的经处理的表面改性纳米粒子。 包括这种表面处理对所得树脂体系的各种性能的影响，包括耐起泡性，光学透明度和流变性。