公开(公告)号：WO2012174561A3

公开(公告)日：2013-06-20

申请号：PCT/US2012043004

申请日：2012-06-18

Applicant: UNIV CALIFORNIA ,  BAZAN GUILLERMO C ,  YING LEI ,  HSU BEN B Y ,  WEN WEN ,  TSENG HSIN-RONG

Inventor： BAZAN GUILLERMO C ,  YING LEI ,  HSU BEN B Y ,  WEN WEN ,  TSENG HSIN-RONG ,  WELCH GREGORY C

IPC: C08G61/12 ,  C08G73/06 ,  H01L31/00

CPC classification number: H01L51/0036 ,  C08G61/122 ,  C08G61/123 ,  C08G61/126 ,  C08G2261/124 ,  C08G2261/1412 ,  C08G2261/148 ,  C08G2261/1646 ,  C08G2261/212 ,  C08G2261/3241 ,  C08G2261/3246 ,  C08G2261/344 ,  C08G2261/414 ,  C08G2261/91 ,  C08G2261/92 ,  H01L51/0043 ,  H01L51/0094 ,  H01L51/0533 ,  H01L51/0545 ,  Y02E10/549

Abstract: A method of regioselectively preparing a pyridine-containing compound is provided. In particular embodiments, the method includes reacting halogen-functionalized pyridal[2,1,3]thiadiazole with organotin-functionalized cyclopenta[2,1-b:3,4-b'] 'dithiophene or organotin-functionalized indaceno[1,2-b:5,6-b']dithiophene. Also provided is a method of preparing a polymer. The method includes regioselectively preparing a monomer that includes a pyridal[2,1,3]thiadiazole unit; and reacting the monomer to produce a polymer that includes a regioregular conjugated backbone section, wherein the section includes a repeat unit containing the pyridal[2,1,3]thiadiazole unit. A polymer that includes a regioregular conjugated backbone section, and electronic devices that include the polymer, are also provided.

Abstract translation: 提供了一种区域选择性制备含吡啶化合物的方法。 在具体实施方案中，该方法包括使卤素官能化的吡啶并[2,1,3]噻二唑与有机锡官能化的环戊二烯并[2,1-b：3,4-b']二噻吩或有机锡官能化的茚并不是[1,2 -b：5,6-b']二。 还提供了制备聚合物的方法。 该方法包括区域选择性制备包含吡啶并[2,1,3]噻二唑单元的单体; 并使所述单体反应以制备包含区域结构共轭主链部分的聚合物，其中所述部分包括含有所述吡啶并[2,1,3]噻二唑单元的重复单元。 还提供了包括区域性共轭主链部分的聚合物和包括聚合物的电子器件。

公开(公告)号：WO2014039847A2

公开(公告)日：2014-03-13

申请号：PCT/US2013058546

申请日：2013-09-06

Applicant: UNIV CALIFORNIA ,  TSENG HSIN-RONG ,  YING LEI ,  HSU BEN B Y ,  TAKACS CHRISTOPHER J ,  BAZAN GUILLERMO C ,  HEEGER ALAN J

Inventor： TSENG HSIN-RONG ,  YING LEI ,  HSU BEN B Y ,  TAKACS CHRISTOPHER J ,  BAZAN GUILLERMO C ,  HEEGER ALAN J

IPC: H01L51/30

CPC classification number: H01L51/0036 ,  H01L51/0012 ,  H01L51/0035 ,  H01L51/0043 ,  H01L51/0566 ,  Y10T428/2913

Abstract: Embodiments of the invention include methods and materials for preparing organic semiconducting layers, for example one used in an organic semiconductor device including a substrate with a nanostructured surface and an organic semiconductor film overlying the nanostructured surface. The semiconductor film is typically formed from macroscopically ordered polymer fibers made from selected conjugate polymer compounds. Such polymer fibers synthesized from selected conjugated polymer compounds and directionally aligned in organic semiconductor devices can provide these devices improved functional properties, including for example, unexpectedly high field effect saturation mobilities.

Abstract translation: 本发明的实施例包括用于制备有机半导体层的方法和材料，例如在包括具有纳米结构表面的衬底和覆盖纳米结构表面的有机半导体膜的有机半导体器件中使用的方法和材料。 半导体膜通常由选择的共轭聚合物化合物制成的宏观有序聚合物纤维形成。 由选择的共轭聚合物化合物合成并在有机半导体器件中定向排列的这种聚合物纤维可以提供这些器件改进的功能特性，包括例如意外高的场效应饱和迁移率。

公开(公告)号：WO2012174561A2

公开(公告)日：2012-12-20

申请号：PCT/US2012/043004

申请日：2012-06-18

Applicant: THE REGENTS OF THE UNIVERSITY OF CALIFORNIA ,  BAZAN, Guillermo, C. ,  YING, Lei ,  HSU, Ben, B., Y. ,  WEN, Wen ,  TSENG, Hsin-Rong

Inventor： BAZAN, Guillermo, C. ,  YING, Lei ,  HSU, Ben, B., Y. ,  WEN, Wen ,  TSENG, Hsin-Rong ,  WELCH, Gregory, C.

CPC classification number: H01L51/0036 ,  C08G61/122 ,  C08G61/123 ,  C08G61/126 ,  C08G2261/124 ,  C08G2261/1412 ,  C08G2261/148 ,  C08G2261/1646 ,  C08G2261/212 ,  C08G2261/3241 ,  C08G2261/3246 ,  C08G2261/344 ,  C08G2261/414 ,  C08G2261/91 ,  C08G2261/92 ,  H01L51/0043 ,  H01L51/0094 ,  H01L51/0533 ,  H01L51/0545 ,  Y02E10/549

Abstract: A method of regioselectively preparing a pyridine-containing compound is provided. In particular embodiments, the method includes reacting halogen-functionalized pyridal[2,1,3]thiadiazole with organotin-functionalized cyclopenta[2,1- b :3,4- b '] 'dithiophene or organotin-functionalized indaceno[1,2-b:5,6-b']dithiophene. Also provided is a method of preparing a polymer. The method includes regioselectively preparing a monomer that includes a pyridal[2,1,3]thiadiazole unit; and reacting the monomer to produce a polymer that includes a regioregular conjugated backbone section, wherein the section includes a repeat unit containing the pyridal[2,1,3]thiadiazole unit. A polymer that includes a regioregular conjugated backbone section, and electronic devices that include the polymer, are also provided.

Abstract translation: 提供了一种区域选择性制备含吡啶化合物的方法。 在具体实施方案中，该方法包括使卤素官能化的吡啶并[2,1,3]噻二唑与有机锡官能化的环戊二烯并[2,1-b：3,4-b']二噻吩或有机锡官能化的茚并不是[1,2 -b：5,6-b']二。 还提供了制备聚合物的方法。 该方法包括区域选择性制备包含吡啶并[2,1,3]噻二唑单元的单体; 并使所述单体反应以制备包含区域结构共轭主链部分的聚合物，其中所述部分包括含有所述吡啶并[2,1,3]噻二唑单元的重复单元。 还提供了包括区域性共轭主链部分的聚合物和包括聚合物的电子器件。