NEW POLYPROPYLENE COMPOSITION WITH BROAD MWD
    3.
    发明申请
    NEW POLYPROPYLENE COMPOSITION WITH BROAD MWD 审中-公开
    具有广泛MWD的新型聚丙烯组合物

    公开(公告)号:WO1996011216A1

    公开(公告)日:1996-04-18

    申请号:PCT/FI1995000558

    申请日:1995-10-10

    Inventor: BOREALIS A/S

    Abstract: The invention relates to a copolymer composition prepared from copolymers of propene and alpha -olefin having 2 to 12 carbon atoms, having high molecular weight, a broad molecular weight distribution and an improved comonomer distribution. The invention relates also to a process for producing the composition and the use of the composition in pipes, fittings, profiles, films and foams. The composition is a so-called reactor mixture of copolymers of said monomers comprising a first copolymer having a higher molecular weight, an alpha -olefin content of 3 to 10 wt.% and a melt flow rate MFR2 of 0,005 to 0,8, and a second copolymer having a lower molecular weight, thus the final composition has a comonomer content of 2 to 10 wt.%, a melt flow rate MFR2 of 0,05 to 2,5 wt.%, a melt flow ratio MFR10/MFR2 of 6 to 15, and the split of the copolymers in the composition between the higher molecular weight copolymer and the lower molecular weight copolymer is from 40/60 to 70/30.

    Abstract translation: 本发明涉及由具有2至12个碳原子的丙烯和α-烯烃的共聚物制备的共聚物组合物,具有高分子量,宽分子量分布和改进的共聚单体分布。 本发明还涉及一种生产该组合物的方法和该组合物在管道,配件,型材,膜和泡沫中的用途。 所述组合物是所述单体的共聚物的所谓反应混合物,其包含具有较高分子量,3-10重量%的α-烯烃含量和0.005至0.8的熔体流动速率MFR 2的第一共聚物,以及 具有较低分子量的第二共聚物,因此最终组合物的共聚单体含量为2至10重量%,熔体流动速率MFR 2为0.05至2.5重量%,熔体流动比MFR 10 / MFR 2为 6〜15,高分子量共聚物和低分子量共聚物的组成中的共聚物的分裂为40/60〜70/30。

    STEREOSPECIFIC CATALYST SYSTEM FOR POLYMERIZATION OF OLEFINS
    6.
    发明申请
    STEREOSPECIFIC CATALYST SYSTEM FOR POLYMERIZATION OF OLEFINS 审中-公开
    用于烯烃聚合的立体催化剂体系

    公开(公告)号:WO1995032994A1

    公开(公告)日:1995-12-07

    申请号:PCT/FI1995000298

    申请日:1995-05-30

    CPC classification number: C08F10/00 C08F4/6465 C08F4/6494

    Abstract: Olefins or mixtures of olefins, particularly propene or mixtures of propene advantageously with ethene, can be polymerized using a Ziegler-Natta catalyst system containing, besides a transition-metal-based procatalyst and cocatalyst which is an organometallic compound, a compound particularly suited for controlling the stereospecificity of the produced polymer. Such a compound called an external donor may also have other effects. By using an acetal derivative of an aldehyde that has two ether groups for this purpose, advantageously selected from the group of dialkoxyphenylalkanes, e.g., dimethoxyphenylpropane, a good stereospecificity of the product is attained combined with the high hydrogen sensitivity of the catalyst system, whereby the use of hydrogen as the chain transfer agent offers an easy control method of the molecular weight of the product by means of adjusting the amount of hydrogen available in the polymerization reaction. If with the acetal derivative donor is used a clearly less hydrogen sensitive donor, e.g. alkoxysilanes, much broader MWD's of the product are achieved.

    Abstract translation: 烯烃或烯烃的混合物,特别是丙烯或丙烯与丙烯的混合物有利地与乙烯可以使用齐格勒 - 纳塔催化剂体系进行聚合,除了基于过渡金属的前催化剂和作为有机金属化合物的助催化剂之外,还特别适用于控制 产生的聚合物的立体定向性。 称为外部供体的这种化合物也可以具有其它作用。 通过使用具有两个醚基团的醛的缩醛衍生物用于此目的,有利地选自二烷氧基苯基烷烃例如二甲氧基苯基丙烷,产物的良好立体定向性与催化剂体系的高氢敏感性相结合,由此 使用氢作为链转移剂通过调节聚合反应中可用的氢的量提供了产物分子量的容易控制方法。 如果使用缩醛衍生物供体,则使用明显较少的氢敏供体,例如。 烷氧基硅烷,更广泛的MWD的产品实现。

Patent Agency Ranking