公开(公告)号：WO2010112641A1

公开(公告)日：2010-10-07

申请号：PCT/ES2010/000141

申请日：2010-03-27

Applicant: UNIVERSIDAD DE MALAGA ,  MAIRELES TORRES, Pedro Jésus ,  SANTAMARÍA GONZÁLEZ, JOSE ,  MORENO TOST, Ramon ,  RUBIO CABELLERO, Juan Miguel ,  MERIDA ROBLES, Josefa María ,  RODRIGUEZ CASTELLON, Enriique ,  JIMENEZ LOPEZ, Antonio

Inventor： MAIRELES TORRES, Pedro Jésus ,  SANTAMARÍA GONZÁLEZ, JOSE ,  MORENO TOST, Ramon ,  RUBIO CABELLERO, Juan Miguel ,  MERIDA ROBLES, Josefa María ,  RODRIGUEZ CASTELLON, Enriique ,  JIMENEZ LOPEZ, Antonio

IPC: C07C67/02 ,  C07C67/03 ,  C12G3/00 ,  B01J37/08

CPC classification number: B01J23/06 ,  B01J35/002 ,  C07C67/03 ,  C10L1/026 ,  C11C3/003 ,  C11C3/10 ,  Y02E50/13 ,  Y02P30/20 ,  C07C69/52 ,  C07C69/24

Abstract: La presente invención describe el empleo de catalizadores sólidos, obtenidos por calcinación de un cincato de un metal alcalinotérreo o de un metal de transición divalente, para la producción de biocarburantes (biodiésel) mediante transesterifícación en condiciones suaves de temperatura y presión atmosférica, de aceites o grasas vegetales o animales, con alcoholes de bajo peso molecular. Ventajas, además de las propias de la catálisis heterogénea: - Simplicidad, reproducibilidad y fácil escalado de la síntesis. - El precursor del catalizador activo es estable en aire. - La temperatura de descomposición o activación del catalizador es inferior a la de otros catalizadores sólidos básicos. - La cinética de la reacción es similar a la descrita en reacciones de catálisis homogénea, y significativamente más rápida que en el caso de otros catalizadores sólidos.

Abstract translation: 本发明涉及通过煅烧碱土金属或二价过渡金属的锌酸盐而获得的固体催化剂用于通过植物或动物油或脂肪与低分子量的酯交换生产生物燃料（生物柴油）的用途 - 在温和的温度和大气压条件下进行。 除了多相催化本身的优点之外，本发明还提供了以下优点：简单，重现性和易于缩合合成; 活性催化剂的前体在空气中稳定; 催化剂分解或活化的温度低于其他碱性固体催化剂; 反应的动力学类似于均相催化反应中所述的动力学，并且显着快于其它固体催化剂的情况。

公开(公告)号：WO2004035200A8

公开(公告)日：2004-12-02

申请号：PCT/EP0314857

申请日：2003-10-15

Applicant: CENTRE NAT RECH SCIENT ,  UNIV MONTPELLIER II ,  TREJO-MENAYO JOSE-MANUEL ,  SNAM PROGETTI ,  CONSORZIO INTERUNIVERSITARIO N ,  REPSOL YPF SA ,  ROZIERE JACQUES ,  JONES DEBORAH ,  JACQUIN MELANIE ,  ROSSINI STEFANO ,  CATANI ROBERTO ,  VACCARI ANGELO ,  LENARDA MAURIZIO ,  BUSCA GUIDO ,  JIMENEZ-LOPEZ ANTONIO ,  RODRIGUEZ-CASTELLON ENRIQUE ,  MAIRELES-TORRES PEDRO

Inventor： TREJO-MENAYO JOSE-MANUEL ,  ROZIERE JACQUES ,  JONES DEBORAH ,  JACQUIN MELANIE ,  ROSSINI STEFANO ,  CATANI ROBERTO ,  VACCARI ANGELO ,  LENARDA MAURIZIO ,  BUSCA GUIDO ,  JIMENEZ-LOPEZ ANTONIO ,  RODRIGUEZ-CASTELLON ENRIQUE ,  MAIRELES-TORRES PEDRO

IPC: B01J21/12 ,  B01J23/40 ,  B01J23/42 ,  B01J23/46 ,  B01J23/755 ,  B01J29/03 ,  B01J29/04 ,  B01J29/85 ,  B01J29/86 ,  B01J35/00 ,  C10G50/00

CPC classification number: B01J29/043 ,  B01J21/12 ,  B01J23/40 ,  B01J23/464 ,  B01J23/755 ,  B01J29/0308 ,  B01J29/041 ,  B01J29/044 ,  B01J35/002 ,  C10G50/00

Abstract: The present invention relates to the use of a silicon-based porous catalytic system for oligomerising light olefins said porous silicon-based catalytic system having an average pore diameter of between about 1 nm and about 5 nm and an acidity level of between about 150 µmol/g and about 650 µmol/g, and prepared from at least one hydrolysable silicon-based compound, or other source of silicon, and at least one non-ionic surface active agent.The invention also relates to a process for oligomerising light olefins using said silicon-based porous catalytic system, and to certain silicon-based porous catalytic systems.

Abstract translation: 本发明涉及硅基多孔催化体系用于低聚轻链烯烃的用途，所述多孔硅基催化体系的平均孔径为约1nm至约5nm，酸度为约150μmol/ g和约650μmol/ g，并且由至少一种可水解的硅基化合物或其它硅源生成，以及至少一种非离子表面活性剂。本发明还涉及使用所述 硅基多孔催化体系，以及某些硅基多孔催化体系。

公开(公告)号：WO2004035200A3

公开(公告)日：2004-10-07

申请号：PCT/EP0314857

申请日：2003-10-15

Applicant: CENTRE NAT RECH SCIENT ,  UNIV MONTPELLIER II ,  TREJO-MENAYO JOSE-MANUEL ,  SNAM PROGETTI ,  CONSORZIO INTERUNIVERSITARIO N ,  REPSOL YPF SA ,  ROZIERE JACQUES ,  JONES DEBORAH ,  JACQUIN MELANIE ,  ROSSINI STEFANO ,  CATANI ROBERTO ,  VACCARI ANGELO ,  LENARDA MAURIZIO ,  BUSCA GUIDO ,  JIMENEZ-LOPEZ ANTONIO ,  RODRIGUEZ-CASTELLON ENRIQUE ,  MAIRELES-TORRES PEDRO

Inventor： TREJO-MENAYO JOSE-MANUEL ,  ROZIERE JACQUES ,  JONES DEBORAH ,  JACQUIN MELANIE ,  ROSSINI STEFANO ,  CATANI ROBERTO ,  VACCARI ANGELO ,  LENARDA MAURIZIO ,  BUSCA GUIDO ,  JIMENEZ-LOPEZ ANTONIO ,  RODRIGUEZ-CASTELLON ENRIQUE ,  MAIRELES-TORRES PEDRO

IPC: B01J21/12 ,  B01J23/40 ,  B01J23/42 ,  B01J23/46 ,  B01J23/755 ,  B01J29/03 ,  B01J29/04 ,  B01J29/85 ,  B01J29/86 ,  B01J35/00 ,  C10G50/00 ,  B01J29/02

CPC classification number: B01J29/043 ,  B01J21/12 ,  B01J23/40 ,  B01J23/464 ,  B01J23/755 ,  B01J29/0308 ,  B01J29/041 ,  B01J29/044 ,  B01J35/002 ,  C10G50/00

Abstract: The present invention relates to the use of a silicon-based porous catalytic system for oligomerising light olefins said porous silicon-based catalytic system having an average pore diameter of between about 1 nm and about 5 nm and an acidity level of between about 150 µmol/g and about 650 µmol/g, and prepared from at least one hydrolysable silicon-based compound, or other source of silicon, and at least one non-ionic surface active agent.The invention also relates to a process for oligomerising light olefins using said silicon-based porous catalytic system, and to certain silicon-based porous catalytic systems.

Abstract translation: 本发明涉及基于硅的多孔催化体系用于低聚轻烯烃的用途，所述多孔硅基催化体系的平均孔径为约1nm至约5nm，酸度水平为约150μmol/ g至约650μmol/ g，并且由至少一种可水解的硅基化合物或其他硅来源以及至少一种非离子表面活性剂制备。本发明还涉及使用所述的所述低聚烯烃低聚烯烃的方法 硅基多孔催化体系，以及某些硅基多孔催化体系。

公开(公告)号：WO2004035200A2

公开(公告)日：2004-04-29

申请号：PCT/EP2003/014857

申请日：2003-10-15

Applicant: CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (C.N.R.S) ,  UNIVERSITE DE MONTPELLIER II ,  SNAMPROGETTI S.P.A. ,  CONSORZIO INTERUNIVERSITARIO NAZIONALE PER LA SCIENZA E TECHNOLOGIA DEI MATERIALI ,  REPSOL YPF S.A. ,  TREJO-MENAYO, José-Manuel ,  ROZIERE, Jacques ,  JONES, Deborah ,  JACQUIN, Mélanie ,  ROSSINI, Stefano ,  CATANI, Roberto ,  VACCARI, Angelo ,  LENARDA, Maurizio ,  BUSCA, Guido ,  JIMENEZ-LOPEZ, Antonio ,  RODRIGUEZ-CASTELLON, Enrique ,  MAIRELES-TORRES, Pedro

Inventor： TREJO-MENAYO, José-Manuel ,  ROZIERE, Jacques ,  JONES, Deborah ,  JACQUIN, Mélanie ,  ROSSINI, Stefano ,  CATANI, Roberto ,  VACCARI, Angelo ,  LENARDA, Maurizio ,  BUSCA, Guido ,  JIMENEZ-LOPEZ, Antonio ,  RODRIGUEZ-CASTELLON, Enrique ,  MAIRELES-TORRES, Pedro

IPC: B01J21/00

CPC classification number: B01J29/043 ,  B01J21/12 ,  B01J23/40 ,  B01J23/464 ,  B01J23/755 ,  B01J29/0308 ,  B01J29/041 ,  B01J29/044 ,  B01J35/002 ,  C10G50/00

Abstract: The present invention relates to the use of a silicon-based porous catalytic system for oligomerising light olefins said porous silicon-based catalytic system having an average pore diameter of between about 1 nm and about 5 nm and an acidity level of between about 150 µmol/g and about 650 µmol/g, and prepared from at least one hydrolysable silicon-based compound, or other source of silicon, and at least one non-ionic surface active agent.The invention also relates to a process for oligomerising light olefins using said silicon-based porous catalytic system, and to certain silicon-based porous catalytic systems.

Abstract translation: 本发明涉及硅基多孔催化体系用于低聚轻链烯烃的用途，所述多孔硅基催化体系的平均孔径为约1nm至约5nm，酸度为约150μmol/ g和约650μmol/ g，并且由至少一种可水解的硅基化合物或其它硅源生成，以及至少一种非离子表面活性剂。本发明还涉及使用所述 硅基多孔催化体系，以及某些硅基多孔催化体系。

公开(公告)号：WO2003064031A3

公开(公告)日：2003-08-07

申请号：PCT/IB2003/000318

申请日：2003-01-31

Applicant: CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (C.N.R.S.) ,  UNIVERSITE DE MONTPELLIER II ,  UNIVERSIDAD MALAGA ,  REPSOL YPF S.A. ,  CONSORZIO INTERUNIVERSITARIO NAZIONALE PER LA SCIENZA E TECNOLOGIA DEI MATERIALI ,  ROZIERE, Jacques ,  JONES, Deborah ,  JACQUIN, Mélanie ,  JIMENEZ-LOPEZ, Antonio ,  RODRIGUEZ-CASTELLON, Enrique ,  MAIRELES-TORRES, Pedro ,  TREJO-MENAYO, José-Manuel ,  VACCCARI, Angelo ,  LENARDA, Maurizio ,  BUSCA, Guido

Inventor： ROZIERE, Jacques ,  JONES, Deborah ,  JACQUIN, Mélanie ,  JIMENEZ-LOPEZ, Antonio ,  RODRIGUEZ-CASTELLON, Enrique ,  MAIRELES-TORRES, Pedro ,  TREJO-MENAYO, José-Manuel ,  VACCCARI, Angelo ,  LENARDA, Maurizio ,  BUSCA, Guido

IPC: B01J21/08

Abstract: Process of preparation of silicon-based multifunctional catalytic systems synthesised together with one or more surface active agents, 2) multifunctional silicon-based porous catalytic system comprising at least one porous catalytic support structurally comprising silica and at least one other metal or non-metal oxide chosen from aluminium, zirconium, and boron, said catalytic support being synthesised together with one or more surface active agents, and at least one or more catalyst chosen from among metallic elements of groups 6-10 of the periodic table of the elements, 3) the catalytic systems are useful in hydrogenation and/or decyclisation reactions of (poly)aromatic compounds, especially for improving the quality of diesel fuels and increasing their cetane number.

公开(公告)号：WO03064031A2

公开(公告)日：2003-08-07

申请号：PCT/IB0300318

申请日：2003-01-31

Applicant: CENTRE NAT RECH SCIENT ,  UNIV MONTPELLIER II ,  UNIV MALAGA ,  REPSOL PETROLEO ,  CONSORZIO INTERUNIVERSITARIO N ,  ROZIERE JACQUES ,  JONES DEBORAH ,  JACQUIN MELANIE ,  JIMENEZ-LOPEZ ANTONIO ,  RODRIGUEZ-CASTELLON ENRIQUE ,  MAIRELES-TORRES PEDRO ,  TREJO-MENAYO JOSE-MANUEL ,  VACCCARI ANGELO ,  LENARDA MAURIZIO ,  BUSCA GUIDO

Inventor： ROZIERE JACQUES ,  JONES DEBORAH ,  JACQUIN MELANIE ,  JIMENEZ-LOPEZ ANTONIO ,  RODRIGUEZ-CASTELLON ENRIQUE ,  MAIRELES-TORRES PEDRO ,  TREJO-MENAYO JOSE-MANUEL ,  VACCCARI ANGELO ,  LENARDA MAURIZIO ,  BUSCA GUIDO

IPC: B01J21/08 ,  B01J29/04 ,  B01J37/03 ,  C10G45/48 ,  C10G45/52

CPC classification number: B01J29/042 ,  B01J21/08 ,  B01J29/0316 ,  B01J29/043 ,  B01J37/033 ,  B01J37/036 ,  C10G2400/04

Abstract: Process of preparation of silicon-based multifunctional catalytic systems synthesised together with one or more surface active agents, 2) multifunctional silicon-based porous catalytic system comprising at least one porous catalytic support structurally comprising silica and at least one other metal or non-metal oxide chosen from aluminium, zirconium, and boron, said catalytic support being synthesised together with one or more surface active agents, and at least one or more catalyst chosen from among metallic elements of groups 6-10 of the periodic table of the elements, 3) the catalytic systems are useful in hydrogenation and/or decyclisation reactions of (poly)aromatic compounds, especially for improving the quality of diesel fuels and increasing their cetane number.

Abstract translation: 制备与一种或多种表面活性剂一起合成的硅基多官能催化体系的方法，2）多功能硅基多孔催化体系，其包含至少一种结构上包含二氧化硅和至少一种其它金属或非金属氧化物的多孔催化剂载体 选自铝，锆和硼，所述催化载体与一种或多种表面活性剂一起合成，以及选自元素周期表6-10族的金属元素中的至少一种或多种催化剂，3） 催化体系可用于（多）芳族化合物的氢化和/或二环化反应，特别是用于改善柴油燃料的质量和增加其十六烷值。