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    HETEROPHASIC POLYOLEFIN COMPOSITION HAVING IMPROVED FLOWABILITY AND IMPACT STRENGTH
    3.
    发明申请
    HETEROPHASIC POLYOLEFIN COMPOSITION HAVING IMPROVED FLOWABILITY AND IMPACT STRENGTH 审中-公开
    具有改善流动性和冲击强度的异种聚烯烃组合物

    公开(公告)号：WO2012116718A1

    公开(公告)日：2012-09-07

    申请号：PCT/EP2011/005656

    申请日：2011-11-10

    Applicant: BOREALIS AG ,  KOCK, Cornelia ,  GREIN, Christelle ,  POTTER, Elisabeth

    Inventor： KOCK, Cornelia ,  GREIN, Christelle ,  POTTER, Elisabeth

    IPC: C08L23/10

    CPC classification number: C08L23/10 ,  C08L23/0815 ,  C08L23/16 ,  C08L2666/06

    Abstract: The invention relates to a heterophasic polyolefin composition having improved flowability and impact strength but also an excellent impact/stiffness balance and a low amount of a hexane extractable fraction, to a process for the preparation of such a heterophasic polyolefin composition, to articles made therefrom and uses of the heterophasic polyolefin composition. The heterophasic polyolefin composition, comprises a matrix comprising a heterophasic propylene base polymer, comprising a matrix comprising a propylene homo- and/or copolymer, an elastomeric ethylene/ alpha-olefin phase dispersed in the matrix, and an ethylene polymer component having an MFR (2.16 kg/ 190 °C) of 15 to 300 g/10 min. and a density of 0.915 g/cm3 or more, wherein the heterophasic polyolefin composition comprising monomer units derived from an oligomeric diene compound, and having a hexane extractable fraction in an amount of not more than 6 wt.%, measured from extruded cast films of 100μm thickness at 50 °C and 2 h extraction time and an MFR (2.16 kg, 230 °C, ISO 1133) of 8 to 80 g/10 min. The heterophasic propylene polymer composition may be used for extrusion, injection moulding, blow moulding, injection stretch blow moulding, cast film extrusion or thermoforming.

    Abstract translation: 本发明涉及具有改进的流动性和冲击强度的异相聚烯烃组合物，而且具有优异的冲击/刚度平衡和少量的己烷可萃取部分，用于制备这种多相聚烯烃组合物的方法制备的制品和 多相聚烯烃组合物的用途。 多相聚烯烃组合物包含包含多相丙烯基聚合物的基质，其包含基体，其包含丙烯均聚物和/或共聚物，分散在基质中的弹性体乙烯/α-烯烃相和具有MFR（ 2.16kg / 190℃）为15-300g / 10min。 并且密度为0.915g / cm 3以上，其中所述多相聚烯烃组合物包含衍生自低聚二烯化合物的单体单元，并且具有不超过6重量％的己烷可萃取组分，其量由 在50℃下的100μm厚度和2小时提取时间和8至80g / 10min的MFR（2.16kg，230℃，ISO 1133）。 异相丙烯聚合物组合物可用于挤出，注射成型，吹塑，注射拉伸吹塑，流延膜挤出或热成型。

    STIFF POLYPROPYLENE COMPOSITION WITH EXCELLENT ELONGATION AT BREAK
    5.
    发明申请
    STIFF POLYPROPYLENE COMPOSITION WITH EXCELLENT ELONGATION AT BREAK 审中-公开
    高分子聚丙烯组合物

    公开(公告)号：WO2012025584A1

    公开(公告)日：2012-03-01

    申请号：PCT/EP2011/064619

    申请日：2011-08-25

    Applicant: Borealis AG ,  KOCK, Cornelia ,  GREIN, Christelle ,  SCHEDENIG, Tonja

    Inventor： KOCK, Cornelia ,  GREIN, Christelle ,  SCHEDENIG, Tonja

    IPC: C08L23/14

    CPC classification number: C08L23/14 ,  C08K3/346 ,  C08K5/0083 ,  C08L23/06 ,  C08L23/0815 ,  C08L23/12 ,  C08L23/142 ,  C08L23/16 ,  C08L2205/035 ,  C08L2205/22 ,  C08L2207/02 ,  C08L2666/04 ,  C08F210/06 ,  C08F210/16 ,  C08F2500/11 ,  C08F2500/12 ,  C08F2500/15 ,  C08F2500/17 ,  C08F10/06 ,  C08F2/001

    Abstract: Polypropylene composition comprising (a) a high melt strength polypropylene having a melt flow rate MFR2 (230 °C) of equal or below 15 g/lOmin and a branching index g' of below 1.0, (b) a first heterophasic propylene copolymer comprising a polypropylene having a melt flow rate MFR2 (230 °C) in the range of 50 to 500 g/lOmin and an elastomeric propylene copolymer having a propylene content in the range of 50 to 80 wt.-% and an intrinsic viscosity (IV) of equal or more than 2.5 dl/g, (c) a second heterophasic propylene copolymer comprising a random propylene copolymer having a melt flow rate MFR2 (230 °C) in the range of 1 to 40 g/lOmin, a branching index g' of 1.0, and a comonomer content of more than 0.5 wt.-%,and an elastomeric propylene copolymer having a propylene content in the range of 50 to 80 wt.-%, and an intrinsic viscosity (IV) of equal or below 2.4 dl/g, (d) a polyethylene plastomer having an ethylene content of at least 50 wt.-%, and (e) a mineral filler (F).

    Abstract translation: 聚丙烯组合物，其包含（a）熔体流动速率MFR 2（230℃）等于或低于15g / 10min，支化指数g'低于1.0的高熔体强度聚丙烯，（b）第一多相丙烯共聚物，其包含 熔体流动速率MFR2（230℃）为50〜500g / 10min的聚丙烯和丙烯含量为50〜80重量％的弹性体丙烯共聚物，特性粘度（IV）为 等于或大于2.5dl / g，（c）第二异相丙烯共聚物，其包含熔体流动速率MFR 2（230℃）在1至40g / 10min范围内的无规丙烯共聚物，支化指数g' 1.0，共聚单体含量大于0.5重量％，丙烯含量在50-80重量％范围内的弹性体丙烯共聚物，特性粘度（IV）等于或低于2.4dl / g，（d）乙烯含量至少为50重量％的聚乙烯塑性体，和（e）矿物填料（F）。

    HETEROPHASIC PROPYLENE COPOLYMERS WITH IMPROVED STIFFNESS/IMPACT/FLOWABILITY BALANCE
    7.
    发明申请
    HETEROPHASIC PROPYLENE COPOLYMERS WITH IMPROVED STIFFNESS/IMPACT/FLOWABILITY BALANCE 审中-公开
    具有改善的强度/冲击/流动性平衡的异构丙烯共聚物

    公开(公告)号：WO2012062734A1

    公开(公告)日：2012-05-18

    申请号：PCT/EP2011/069611

    申请日：2011-11-08

    Applicant: BOREALIS AG ,  LESKINEN, Pauli ,  DOSHEV, Petar ,  KOCK, Cornelia

    Inventor： LESKINEN, Pauli ,  DOSHEV, Petar ,  KOCK, Cornelia

    IPC: C08L23/12 ,  C08F10/00 ,  C08F297/08

    CPC classification number: C08L23/14 ,  C08F110/06 ,  C08F210/06 ,  C08L23/12 ,  C08L2205/02 ,  C08L2205/025 ,  C08L2205/035 ,  C08L2207/02 ,  C08L2308/00 ,  C08L2314/02 ,  C08F10/06 ,  C08F2/001 ,  C08F2/14 ,  C08L23/16 ,  C08F4/6492 ,  C08F210/16 ,  C08F2500/12 ,  C08F2500/17 ,  C08F2500/04

    Abstract: Heterophasic propylene copolymer (HECO) comprising: (a) a polypropylene matrix comprising: (a 1 ) a first propylene homopolymer fraction (PPH1) with a melt flow rate MFR 2 (230°C) measured according to ISO 1133 in the range of > 200 to 500 g/10min, (a 2-1 ) a second propylene homopolymer fraction (PPH2) with a melt flow rate MFR 2 (230°C) measured according to ISO 1133 in the range of > 30 to ≤ 200 g/10min or, (a 2-2 ) a second propylene homopolymer fraction (PPH2) with a melt flow rate MFR 2 (230°C) measured according to ISO 1133 in the range of > 5 to ≤ 30 g/10min and, (a 3-1 ) a third propylene homopolymer fraction (PPH3) with a melt flow rate MFR 2 (230°C) measured according to ISO 1133 in the range of 0.03 to ≤ 5 g/10min, if the second propylene homopolymer fraction is fraction (a 2-1 ) or, (a 3-2 ) a third propylene homopolymer fraction (PPH3) with a melt flow rate MFR 2 (230°C) measured according to ISO 1133 in the range of > 30 to ≤ 200 g/10min, if the second propylene homopolymer fraction is fraction (a 2-2 ), wherein the polypropylene matrix has a melt flow rate MFR 2 (230°C) measured according to ISO 1133 in the range of 30 to 500 g/10min and a xylene cold soluble fraction determined at 23°C according to ISO 6427 in the range of 0.5 to 2 (230°C) measured according to ISO 1133 in the range of 25 to 200 g/10min and, (ii) the amorphous phase (AM) of the cold soluble fraction (XCS) of the heterophasic propylene copolymer has an intrinsic viscosity measured according to ISO 1628-1 (at 135°C in tetraline) of ≥ 2.0 dl/g, and a process for its preparation.

    Abstract translation: 异相丙烯共聚物（HECO），其包含：（a）聚丙烯基质，其包含：（a1）根据ISO 1133测量的熔体流动速率MFR 2（230℃）的第一丙烯均聚物部分（PPH1）的范围> 200至 500g / 10min，（a2-1）根据ISO 1133测量的熔体流动速率MFR 2（230℃）在> 30至= 200g / 10min范围内的第二丙烯均聚物部分（PPH2），或（a2 -2）根据ISO 1133在> 5至= 30g / 10min范围内测量的熔体流动速率MFR 2（230℃）的第二丙烯均聚物部分（PPH2），和（a3-1）第三丙烯均聚物 如果第二丙烯均聚物馏分为馏分（a2-1）或（a3-），则根据ISO 1133测量的馏分（PPH 3）的熔体流动速率MFR 2（230℃）为0.03至= 5g / 2）如果第二丙烯均聚物部分（如果第二丙烯均聚物部分）具有根据ISO 1133测量的熔体流动速率MFR 2（230℃）的范围> 30至= 200g / 10min的第三丙烯均聚物部分（PPH 3） 是分数（a2-2），其中聚丙烯基质的熔体流动速率MFR 2（230℃）根据ISO 1133测量的范围为30至500g / 10min，二甲苯冷可溶物级分在23℃下测定，根据 到ISO 6427，范围为0.5至<2.0wt％，（b）分散在所述基质中的弹性体丙烯共聚物，其中（i）所述多相丙烯共聚物具有根据ISO 1133测量的熔体流动速率MFR 2（230℃） 在25至200g / 10min的范围内，和（ii）多相丙烯共聚物的冷可溶级分（XCS）的无定形相（AM）具有根据ISO 1628-1测量的特性粘度（在135℃ 在四环素中）= 2.0dl / g，及其制备方法。

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