公开(公告)号：WO2010076876A1

公开(公告)日：2010-07-08

申请号：PCT/JP2009/071523

申请日：2009-12-17

申请人： DAIKIN INDUSTRIES, LTD. ,  GREENE, TWEED OF DELAWARE, INC. ,  OTA, Daisuke ,  TERADA, Junpei ,  MORIKAWA, Tatsuya ,  KOH, Meiten ,  ALEXANDER, William Brock

发明人： OTA, Daisuke ,  TERADA, Junpei ,  MORIKAWA, Tatsuya ,  KOH, Meiten ,  ALEXANDER, William Brock

IPC分类号： C08K5/00 ,  C08K5/14

CPC分类号： C08K5/0025 ,  C08K5/14 ,  C08L27/18

摘要： There is provided a crosslinked molded article obtained by crosslinking and molding a perfluoroelastomer composition which comprises no additives causing outgas or generating particles such as carbon black, zinc oxide and proton sponge and is capable of providing a crosslinked molded article having significantly improved tensile strength. The crosslinked molded article is transparent and has satisfactory mechanical properties. The crosslinked molded article is obtained by crosslinking and molding the perfluoroelastomer composition consisting of (A) a perfluoroelastomer having iodine atom and/or bromine atom and comprising 20 to 35 % by mole of a perfluoro vinyl ether unit (a) and 65 to 80 % by mole of a tetrafluoroethylene unit (b), (B) an organic peroxide, and (C) a compound having at least two double bonds in its molecule.

摘要翻译： 提供了通过交联和成型全氟弹性体组合物而获得的交联模制品，该全氟弹性体组合物不包含引起气体或产生诸如炭黑，氧化锌和质子海绵的颗粒的添加剂，并且能够提供具有显着提高的拉伸强度的交联模制品。 交联的模制品是透明的并具有令人满意的机械性能。 交联成型品通过交联和成型由（A）具有碘原子和/或溴原子的全氟弹性体组成的全氟弹性体组合物，并且包含20-35％（摩尔）全氟乙烯基醚单元（a）和65-80％ 摩尔的四氟乙烯单元（b），（B）有机过氧化物，和（C）在其分子中具有至少两个双键的化合物。

公开(公告)号：WO2010047234A1

公开(公告)日：2010-04-29

申请号：PCT/JP2009/067588

申请日：2009-10-02

申请人： DAIKIN INDUSTRIES, LTD. ,  TERADA, Junpei ,  MORIKAWA, Tatsuya ,  OTA, Daisuke ,  KOH, Meiten

发明人： TERADA, Junpei ,  MORIKAWA, Tatsuya ,  OTA, Daisuke ,  KOH, Meiten

IPC分类号： C08F214/26 ,  C08K5/00

CPC分类号： C08F214/262 ,  C08K5/0025 ,  C08L27/18

摘要： There is provided a perfluoroelastomer composition having a low glass transition temperature and excellent cold resistance and heat resistance and comprising a perfluoroelastomer comprising a tetrafluoroethylene unit (a), a perfluoro vinyl ether unit (b) and a cure site unit (c) having nitrile group, carboxyl group and/or alkoxycarbonyl group as a cure site, wherein the perfluoro vinyl ether unit (b) is contained in an amount of 8 to 23 % by mole in the perfluoroelastomer.

摘要翻译： 提供具有低玻璃化转变温度和优异的耐寒性和耐热性的全氟弹性体组合物，并且包含全氟弹性体，其包含四氟乙烯单元（a），全氟乙烯基醚单元（b）和具有腈基的固化位点单元（c） ，羧基和/或烷氧基羰基作为固化部位，其中全氟乙烯基醚单元（b）的含量在全氟弹性体中为8〜23摩尔％。

公开(公告)号：WO2008130557A1

公开(公告)日：2008-10-30

申请号：PCT/US2008/004890

申请日：2008-04-16

申请人： GREENE, TWEED OF DELAWARE, INC. ,  DAIKIN INDUSTRIES, LTD. ,  NOGUCHI, Tsuyoshi ,  LUO, Jiazhong ,  MORIKAWA, Tatsuya ,  KOMORI, Hirokazu ,  YAMATO, Takafumi ,  KOH, Meiten

发明人： NOGUCHI, Tsuyoshi ,  LUO, Jiazhong ,  MORIKAWA, Tatsuya ,  KOMORI, Hirokazu ,  YAMATO, Takafumi ,  KOH, Meiten

IPC分类号： C08F214/18

CPC分类号： C08L27/18 ,  C08K5/18 ,  C08L2205/02 ,  Y10T428/3154 ,  C08L2666/04

摘要： The present invention includes crosslinked perfluoroelastomeric compositions and molded articles formed from a cross-linkable perfluoroelastomeric composition having a first curable perfluoropolymer having a cure site monomer and a second perfluoropolymer having a cure site monomer. The molar ratio of the tetrafluoroethylene monomer to perfluoroalkylvinyl ether in one perfluoropolymer is about 0 to 100 to about 65 to 35 in the perfluoropolymer. The molar ratio of the tetrafluoroethylene monomer to the perfluoroalkylvinyl ether monomer in the second polymer is about 65:35 to about 95:5 in the second perfluoropolymer. The composition further includes a curative. One fluorine-containing elastomer composition herein, having a short crosslinking time, has perfluoroelastomers (A) having a tetrafluoroethylene unit, a perfluoralkylvinyl ether unit (a) and a monomer unit (b) having at least one kind selected from the group consisting of a nitrile group, a carboxyl group and an alkoxycarbonyl group, wherein the composition has two or more kinds of perfluoroelastomers (A) having differing contents of perfluoroalkylvinyl ether unit (a).

摘要翻译： 本发明包括交联的全氟弹性体组合物和由可交联的全氟弹性体组合物形成的模塑制品，其具有具有固化部位单体的第一可固化全氟聚合物和具有固化部位单体的第二全氟聚合物。 全氟聚合物中四氟乙烯单体与全氟烷基乙烯基醚的摩尔比在全氟聚合物中为约0至约100至约65至35。 第二聚合物中四氟乙烯单体与全氟烷基乙烯基醚单体的摩尔比在第二全氟聚合物中为约65:35至约95:5。 组合物还包括治疗剂。 具有交联时间短的一种含氟弹性体组合物具有全氟弹性体（A），其具有四氟乙烯单元，全氟烷基乙烯基醚单元（a）和单体单元（b），所述单体单元具有选自以下的至少一种： 腈基，羧基和烷氧基羰基，其中所述组合物具有两种或更多种具有不同全氟烷基乙烯基醚单元（a）含量的全氟弹性体（A）。