公开(公告)号：WO2005042546A2

公开(公告)日：2005-05-12

申请号：PCT/US2004/025420

申请日：2004-08-06

Applicant: WISCONSIN ALUMNI RESEARCH FOUNDATION ,  LANDIS, Clark R. ,  JIN, Wiechang ,  OWEN, Jonathan S. ,  CLARK, Thomas P. ,  NELSON, Ryan C.

Inventor： LANDIS, Clark R. ,  JIN, Wiechang ,  OWEN, Jonathan S. ,  CLARK, Thomas P. ,  NELSON, Ryan C.

IPC: C07F

CPC classification number: C07F9/6584 ,  B01J31/1658 ,  B01J31/2295 ,  B01J31/2466 ,  B01J31/2476 ,  B01J2231/321 ,  B01J2231/4261 ,  B01J2231/44 ,  B01J2231/645 ,  B01J2531/0205 ,  B01J2531/822 ,  B01J2531/824 ,  B01J2531/828 ,  B01J2540/10 ,  B01J2540/442 ,  B01J2540/66 ,  C07F15/0066 ,  C07F15/008 ,  C07F15/0093

Abstract: Diazaphosphacycles comprising compounds having the formula XI : and salts of the compound are provided, wherein the variables W, T, R1, R14, and R15 are as described herein. Transition metal catalysts incorporating such diazaphosphacycles and methods of use thereof are also disclosed. There are further provided compositions comprising diazaphosphacycles covalently attached to a solid support and methods of use thereof.

Abstract translation: 提供了包含具有式XI的化合物的二亚磷酰胆碱：和化合物的盐，其中变量W，T，R1，R14和R15如本文所述。 还公开了结合了这种二氮磷脂的过渡金属催化剂及其使用方法。 还提供了组合物，其包含共价连接到固体支持物上的重氮磷酸循环及其使用方法。

公开(公告)号：WO2005042546A3

公开(公告)日：2005-09-01

申请号：PCT/US2004025420

申请日：2004-08-06

Applicant: WISCONSIN ALUMNI RES FOUND ,  LANDIS CLARK R ,  JIN WIECHANG ,  OWEN JONATHAN S ,  CLARK THOMAS P ,  NELSON RYAN C

Inventor： LANDIS CLARK R ,  JIN WIECHANG ,  OWEN JONATHAN S ,  CLARK THOMAS P ,  NELSON RYAN C

IPC: C07F20060101 ,  C07F1/08 ,  C07F9/02 ,  C07F9/94

CPC classification number: C07F9/6584 ,  B01J31/1658 ,  B01J31/2295 ,  B01J31/2466 ,  B01J31/2476 ,  B01J2231/321 ,  B01J2231/4261 ,  B01J2231/44 ,  B01J2231/645 ,  B01J2531/0205 ,  B01J2531/822 ,  B01J2531/824 ,  B01J2531/828 ,  B01J2540/10 ,  B01J2540/442 ,  B01J2540/66 ,  C07F15/0066 ,  C07F15/008 ,  C07F15/0093

Abstract: Diazaphosphacycles comprising compounds having the formula XI : and salts of the compound are provided, wherein the variables W, T, R1, R14, and R15 are as described herein. Transition metal catalysts incorporating such diazaphosphacycles and methods of use thereof are also disclosed. There are further provided compositions comprising diazaphosphacycles covalently attached to a solid support and methods of use thereof.

Abstract translation: 提供了包含具有式XI的化合物的二氮杂磷杂环化合物和该化合物的盐，其中变量W，T，R1，R14和R15如本文所述。 还公开了掺入这种二氮杂磷杂环化合物的过渡金属催化剂及其使用方法。 还提供了包含共价连接到固体载体上的二氮杂磷杂环化合物的组合物及其使用方法。

公开(公告)号：WO2006026489A1

公开(公告)日：2006-03-09

申请号：PCT/US2005/030519

申请日：2005-08-25

Applicant: THE DOW CHEMICAL COMPANY ,  WISCONSIN ALUMNI RESEARCH FOUNDATION ,  LANDIS, Clark, R. ,  CLARK, Thomas, P. ,  KLOSIN, Jerzy

Inventor： LANDIS, Clark, R. ,  CLARK, Thomas, P. ,  KLOSIN, Jerzy

IPC: C07C67/303 ,  C07F9/6584 ,  C07C253/10 ,  C07C231/18

CPC classification number: C07C45/505 ,  C07B2200/07 ,  C07C51/235 ,  C07C67/293 ,  C07C231/18 ,  C07C253/30 ,  C07F9/6584 ,  C07F17/02 ,  C07C47/228 ,  C07C69/003 ,  C07C255/17 ,  C07C69/14

Abstract: This invention relates to a asymmetric hydroformylation processes in which a prochiral or chiral olefin is reacted with carbon monoxide and hydrogen in the presence of an optically active metal-ligand complex catalyst to produce an optically active aldehyde or a product derived from an optically active aldehyde.

Abstract translation: 本发明涉及不对称加氢甲酰化方法，其中前旋手性或手性烯烃在光学活性金属 - 配体配合物催化剂存在下与一氧化碳和氢气反应以产生光学活性醛或衍生自光学活性醛的产物。