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1.
公开(公告)号:WO2003033441A1
公开(公告)日:2003-04-24
申请号:PCT/US2002/031046
申请日:2002-09-30
Applicant: EXXONMOBIL CHEMICAL PATENTS INC. , CHENG, Minquan , PHILLIPS, Jeffrey, J. , NICOLETTI, Michael, P. , LUMGAIR, David, R., Jr. , SHUTT, John, R. , KABIN, Jeffrey, A. , BORGMANN, Wilried , KUNKEL, Josef , FRITZ, Helmut , WALZL, Roland , LAUERMANN, Gerhard , MULLER, Klaus
Inventor: CHENG, Minquan , PHILLIPS, Jeffrey, J. , NICOLETTI, Michael, P. , LUMGAIR, David, R., Jr. , SHUTT, John, R. , KABIN, Jeffrey, A. , BORGMANN, Wilried , KUNKEL, Josef , FRITZ, Helmut , WALZL, Roland , LAUERMANN, Gerhard , MULLER, Klaus
IPC: C07C7/04
Abstract: This invention is directed to a method of removing dimethyl ether from an olefin stream. The method includes distilling the olefin stream so that the dimethyl ether is separated out of the olefin stream with propane. The olefin stream can then be further distilled to provide a polymer grade ethylene stream and a polymer grade propylene stream, with each stream containing not greater than about 10 wppm dimethyl ether.
Abstract translation: 本发明涉及一种从烯烃流中除去二甲醚的方法。 该方法包括蒸馏烯烃流,使得二甲醚与丙烷分离出烯烃料流。 然后可以进一步蒸馏烯烃物流以提供聚合物级乙烯料流和聚合物级丙烯料流,每个料流含有不大于约10wppm二甲醚。
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公开(公告)号:WO03033439A2
公开(公告)日:2003-04-24
申请号:PCT/EP0211408
申请日:2002-10-11
Applicant: EXXONMOBIL CHEM PATENTS INC , BORGMANN WILFRIED , KUNKEL JOSEF , FRITZ HELMUT , LAUERMANN GERHARD , WALZL ROLAND , MUELLER KLAUS
Inventor: BORGMANN WILFRIED , KUNKEL JOSEF , FRITZ HELMUT , LAUERMANN GERHARD , WALZL ROLAND , MUELLER KLAUS
Abstract: A method is described for producing olefins from methanol in a reactor, wherein liquid methanol is evaporated and introduced into the reactor as gaseous methanol for olefin synthesis, while hot olefin-containing reactor exit gas is removed from the reactor. For better utilization of heat, it is proposed to send at least a part of the liquid methanol (1) with the reactor exit gas (15) into a heat exchanger (9), where the liquid methanol (1) is evaporated and the reactor exit gas (15) is simultaneously cooled. The methanol evaporated in the way (14) can be impute to the reactor directly or after addition to another stream (3).
Abstract translation: 描述了一种用于在反应器中从甲醇生产烯烃的方法,其中将液体甲醇蒸发并作为用于烯烃合成的气态甲醇引入反应器,同时从反应器中除去含热烯烃的反应器出口气体。 为了更好地利用热量,建议将至少一部分液体甲醇(1)与反应器出口气体(15)一起送入热交换器(9),其中液体甲醇(1)蒸发,反应器 出口气体(15)同时被冷却。 以(14)的方式蒸发的甲醇可以直接或者在添加到另一个流(3)之后直接归因于反应器。
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3.
公开(公告)号:WO03033441A8
公开(公告)日:2005-04-28
申请号:PCT/US0231046
申请日:2002-09-30
Applicant: EXXONMOBIL CHEM PATENTS INC , CHENG MINQUAN , PHILLIPS JEFFREY J , NICOLETTI MICHAEL P , LUMGAIR DAVID R JR , SHUTT JOHN R , KABIN JEFFREY A , BORGMANN WILRIED , KUNKEL JOSEF , FRITZ HELMUT , WALZL ROLAND , LAUERMANN GERHARD , MULLER KLAUS
Inventor: CHENG MINQUAN , PHILLIPS JEFFREY J , NICOLETTI MICHAEL P , LUMGAIR DAVID R JR , SHUTT JOHN R , KABIN JEFFREY A , BORGMANN WILRIED , KUNKEL JOSEF , FRITZ HELMUT , WALZL ROLAND , LAUERMANN GERHARD , MULLER KLAUS
IPC: C07C7/04 , C07C11/02 , C07C11/04 , C07C11/06 , C07C11/08 , C08F110/02 , C08F110/06
Abstract: This invention is directed to a method of removing dimethyl ether from an olefin stream. The method includes distilling the olefin stream so that the dimethyl ether is separated out of the olefin stream with propane. The olefin stream can then be further distilled to provide a polymer grade ethylene stream and a polymer grade propylene stream, with each stream containing not greater than about 10 wppm dimethyl ether.
Abstract translation: 本发明涉及一种从烯烃流中除去二甲醚的方法。 该方法包括蒸馏烯烃流,使得二甲醚与丙烷分离出烯烃料流。 然后可以进一步蒸馏烯烃物流以提供聚合物级乙烯料流和聚合物级丙烯料流,每个料流含有不大于约10wppm二甲醚。
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公开(公告)号:WO2003033439A3
公开(公告)日:2003-04-24
申请号:PCT/EP2002/011408
申请日:2002-10-11
Applicant: EXXONMOBIL CHEMICAL PATENTS INC. , BORGMANN, Wilfried , KUNKEL, Josef , FRITZ, Helmut , LAUERMANN, Gerhard , WALZL, Roland , MÜLLER, Klaus
Inventor: BORGMANN, Wilfried , KUNKEL, Josef , FRITZ, Helmut , LAUERMANN, Gerhard , WALZL, Roland , MÜLLER, Klaus
IPC: C07C1/00
Abstract: A method is described for producing olefins from methanol in a reactor, wherein liquid methanol is evaporated and introduced into the reactor as gaseous methanol for olefin synthesis, while hot olefin-containing reactor exit gas is removed from the reactor. For better utilization of heat, it is proposed to send at least a part of the liquid methanol (1) with the reactor exit gas (15) into a heat exchanger (9), where the liquid methanol (1) is evaporated and the reactor exit gas (15) is simultaneously cooled. The methanol evaporated in the way (14) can be impute to the reactor directly or after addition to another stream (3).
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5.
公开(公告)号:WO2003033438A1
公开(公告)日:2003-04-24
申请号:PCT/EP2002/011407
申请日:2002-10-11
Applicant: EXXONMOBIL CHEMICAL PATENTS INC. , BORGMANN, Wilfried , KUNKEL, Joseph , FRITZ, Helmut , LAUERMANN, Gerhard , WALZL, Roland , MÜLLER, Klaus
Inventor: BORGMANN, Wilfried , KUNKEL, Joseph , FRITZ, Helmut , LAUERMANN, Gerhard , WALZL, Roland , MÜLLER, Klaus
IPC: C07C1/00
Abstract: A method is described for processing an olefin-containing product stream (1) that contains, besides ethylene and propylene, longer-chain olefins and compounds of hydrocarbons with oxygen (oxygenates). Such a product stream (I) can occur in particular in olefin synthesis from methanol. The product stream is dewatered in successive process steps, optionally compressed in several steps and dried. Then it is subjected to fractionation. For removal of the undesired oxygenates it is proposed that the oxygenates be washed out of the gaseous product stream after the compression steps and before the drying step in a column (12) with methanol.
Abstract translation: 描述了一种用于处理含烯烃的产物流(1)的方法,其除了乙烯和丙烯外含有长链烯烃和具有氧(含氧化合物)的烃的化合物。 这样的产物流(I)特别可以在甲醇的烯烃合成中发生。 产物流在连续的工艺步骤中脱水,任选在几个步骤中压缩并干燥。 然后进行分馏。 为了去除不需要的含氧化合物,提出在压缩步骤之后和在用甲醇的塔(12)中的干燥步骤之前,将含氧化合物从气态产物流中洗出。
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