公开(公告)号：WO2012054633A3

公开(公告)日：2013-10-17

申请号：PCT/US2011056926

申请日：2011-10-19

Applicant: BIOFORMIX INC ,  CHEN YANGBIN ,  MALOFSKY ADAM ,  SULLIVAN JEFFREY M ,  WOJCIAK STANLEY C ,  DEY TANMOY ,  MALOFSKY BERNARD ,  COCKREM MICHAEL C M

Inventor： CHEN YANGBIN ,  MALOFSKY ADAM ,  SULLIVAN JEFFREY M ,  WOJCIAK STANLEY C ,  DEY TANMOY ,  MALOFSKY BERNARD ,  COCKREM MICHAEL C M

IPC: C07C69/74

CPC classification number: C07C69/602 ,  C07C67/343 ,  C07C69/593 ,  C08F122/14 ,  C08F136/20 ,  C08G63/00 ,  C08L35/02 ,  C08L47/00 ,  C09D167/00 ,  Y02P20/127 ,  Y10T428/249921

Abstract: The present invention provides a method of making a methylene malonate monomer that includes the steps of reacting a malonic acid ester with a source of formaldehyde. The reaction is optionally performed in the presence of or contacted with an energy transfer means such as a heat transfer agent, a heat transfer surface, a source of radiation or a laser such that reaction complex is substantially vaporized to produce a vapor phase comprising methylene malonate monomer which may be isolated. The present invention further provides methylene malonate monomers prepared by the method of the invention, as well as compositions and products formed from the methylene malonate monomers, including monomer-based products and polymer-based products.

Abstract translation: 本发明提供一种制备亚甲基丙二酸单体的方法，其包括使丙二酸酯与甲醛源反应的步骤。 该反应任选地在诸如传热剂，传热表面，辐射源或激光的能量转移装置的存在或接触的情况下进行，使得反应配合物基本上蒸发以产生包含亚甲基丙二酸酯的气相 可以分离的单体。 本发明还提供了通过本发明的方法制备的亚甲基丙二酸酯单体，以及由亚甲基丙二酸酯单体形成的组合物和产品，包括基于单体的产品和基于聚合物的产品。

公开(公告)号：WO1997006044A1

公开(公告)日：1997-02-20

申请号：PCT/US1996011557

申请日：1996-07-12

Applicant: MALOFSKY, Adam, G. ,  MALOFSKY, Bernard, M. ,  GLASSBERG, Paul, R.

IPC: B62B07/06

CPC classification number: B62B7/00 ,  B62B2501/065

Abstract: A rollable child carrier structure (100) comprising a rollable base (5) and a multiside enclosing frame (3), wherein said frame comprises tubing sections made of lightweight, high modulus fiber-reinforced plastic matrix tubing.

Abstract translation: 一种可滚动的儿童托架结构（100），包括可卷绕的底座（5）和多边框包围框架（3），其中所述框架包括由轻质的高模量纤维增强塑料基质管制成的管段。

公开(公告)号：WO2012054616A3

公开(公告)日：2012-04-26

申请号：PCT/US2011/056903

申请日：2011-10-19

Applicant: BIOFORMIX INC. ,  MALOFSKY, Bernard ,  MALOFSKY, Adam ,  DEY, Tanmoy ,  SULLIVAN, Jeffrey, M. ,  CHEN, Yangbin ,  WOJCIAK, Stanley, C.

Inventor： MALOFSKY, Bernard ,  MALOFSKY, Adam ,  DEY, Tanmoy ,  SULLIVAN, Jeffrey, M. ,  CHEN, Yangbin ,  WOJCIAK, Stanley, C.

IPC: C07C69/74

Abstract: The present invention provides improved methods for the chemical synthesis of methylene malonates using the Knovenagel synthesis reaction. The method of the invention provides for improved methylene malonates by significantly reducing or eliminating the formation of alternative and/or deleterious side products, significantly reducing or eliminating unwanted consumption of methylene malonates, and significantly reducing or eliminating the degradation of methylene malonates. These advantages result in methylene malonates, which upon recovery, are of higher quality, greater purity, improved yield and possess overall improved performance characteristics (e.g., improved cure speed, retention of cure speed, improved shelf-life and/or stability).

公开(公告)号：WO2012012362A2

公开(公告)日：2012-01-26

申请号：PCT/US2011044430

申请日：2011-07-19

Applicant: URASEAL INC ,  OFS FITEL LLC ,  MALOFSKY BERNARD M ,  MALOFSKY ADAM G ,  BRADLEY JOSEPH E ,  MANN WILLIAM H ,  TABLE ROBERT C ,  MORANDO VICTOR J ,  SELLERS JAMES M ,  WINTERS NATHAN E ,  DEPIANO JOHN ,  DICKINSON PAUL R ,  HENDRICKSON DANIEL

Inventor： MALOFSKY BERNARD M ,  MALOFSKY ADAM G ,  BRADLEY JOSEPH E ,  MANN WILLIAM H ,  TABLE ROBERT C ,  MORANDO VICTOR J ,  SELLERS JAMES M ,  WINTERS NATHAN E ,  DEPIANO JOHN ,  DICKINSON PAUL R ,  HENDRICKSON DANIEL

IPC: B32B37/14

CPC classification number: G02B6/4466 ,  B65H49/205 ,  B65H51/10 ,  B65H57/26 ,  B65H2701/32 ,  G02B6/4457 ,  G02B6/4463 ,  G02B6/46 ,  H02G3/305 ,  Y10T428/2938

Abstract: Among other things, a communication line is attached along a target surface of a building by laying out the line from a tool. An outer surface of the line is in a temporarily tacky condition as the line is laid out along the surface. The line is in the temporarily tacky condition based at least in part on an adhesive component having been pre-applied to the outer surface of the line. The line becomes non-tacky after it has been attached.

Abstract translation: 除此之外，通过从工具布置线来沿着建筑物的目标表面附接通信线。 由于线沿着表面布置，线的外表面处于临时发粘状态。 该线至少部分基于预先施加到线的外表面的粘合剂组分而处于临时发粘状态。 连线后，线条变得无粘性。

公开(公告)号：WO2012054633A2

公开(公告)日：2012-04-26

申请号：PCT/US2011/056926

申请日：2011-10-19

Applicant: BIOFORMIX, LLC ,  CHEN, Yangbin ,  MALOFSKY, Adam ,  SULLIVAN, Jeffrey, M. ,  WOJCIAK, Stanley, C. ,  DEY, Tanmoy ,  MALOFSKY, Bernard ,  COCKREM, Michael, C.m.

Inventor： CHEN, Yangbin ,  MALOFSKY, Adam ,  SULLIVAN, Jeffrey, M. ,  WOJCIAK, Stanley, C. ,  DEY, Tanmoy ,  MALOFSKY, Bernard ,  COCKREM, Michael, C.m.

IPC: C07C69/38

CPC classification number: C07C69/602 ,  C07C67/343 ,  C07C69/593 ,  C08F122/14 ,  C08F136/20 ,  C08G63/00 ,  C08L35/02 ,  C08L47/00 ,  C09D167/00 ,  Y02P20/127 ,  Y10T428/249921

Abstract: The present invention provides a method of making a methylene malonate monomer that includes the steps of reacting a malonic acid ester with a source of formaldehyde optionally in the presence of an acidic or basic catalyst and optionally in the presence of an acidic or non-acidic solvent to form reaction complex. The reaction is optionally performed in the presence of or contacted with an energy transfer means such as a heat transfer agent, a heat transfer surface, a source of radiation or a laser such that reaction complex is substantially vaporized to produce a vapor phase comprising methylene malonate monomer which may be isolated. The present invention further provides methylene malonate monomers prepared by the method of the invention, as well as compositions and products formed from the methylene malonate monomers, including monomer-based products (e.g., inks, adhesives, coatings, sealants or reactive molding) and polymer-based products (e.g., fibers, films, sheets, medical polymers, composite polymers and surfactants).

Abstract translation: 本发明提供一种制备亚甲基丙二酸单体的方法，其包括以下步骤：使丙二酸酯与甲醛源任选地在酸性或碱性催化剂存在下反应，并任选在酸性或非酸性溶剂存在下反应 形成反应复合物。 该反应任选地在诸如传热剂，传热表面，辐射源或激光的能量转移装置的存在或接触的情况下进行，使得反应配合物基本上蒸发以产生包含亚甲基丙二酸酯的气相 可以分离的单体。 本发明还提供了通过本发明方法制备的亚甲基丙二酸单体，以及由亚甲基丙二酸酯单体形成的组合物和产品，包括基于单体的产品（例如油墨，粘合剂，涂料，密封剂或反应性模塑）和聚合物 （如纤维，薄膜，薄片，医用聚合物，复合聚合物和表面活性剂）。

公开(公告)号：WO2012012357A1

公开(公告)日：2012-01-26

申请号：PCT/US2011/044419

申请日：2011-07-19

Applicant: OFS FITEL, LLC ,  BUREK, Denis, E. ,  HENDRICKSON, Daniel ,  GEORGE, John ,  WHITE, Willard, C. ,  DICKINSON, Paul, R. ,  MANN, William, H. ,  BRADLEY, Joseph, E. ,  MALOFSKY, Adam, Gregg ,  MALOFSKY, Bernard, Miles

Inventor： BUREK, Denis, E. ,  HENDRICKSON, Daniel ,  GEORGE, John ,  WHITE, Willard, C. ,  DICKINSON, Paul, R. ,  MANN, William, H. ,  BRADLEY, Joseph, E. ,  MALOFSKY, Adam, Gregg ,  MALOFSKY, Bernard, Miles

IPC: G02B6/00

CPC classification number: G02B6/4457 ,  G02B6/4441 ,  G02B6/4453 ,  G02B6/4463 ,  Y10T156/18

Abstract: An optical fiber is permanently routed easily, quickly, and unobtrusively at a customer premises using an inventive hand tool, without staples or other fasteners. The fiber has an adhesive outer coating that is activated as the fiber is applied by the tool on an exposed surface such as a wall, ceiling, molding, groove, or corner at the premises. When the activated coating hardens, the fiber is bonded to the surface on which it was applied, and the hardened coating also provides physical protection for the fiber. In the disclosed embodiment, the coated fiber is supplied on a spool that mounts on the tool, and the coating is activated by guiding the fiber as it unwinds from the spool through a chamber containing an activating substance. The fiber with the activated coating is then guided to an applicator wheel on the tool which applies the fiber to the surface.

Abstract translation: 光纤在使用本发明的手工工具的情况下，不需要订书钉或其他紧固件就能在使用者住处方便地，快速地和不引人注目地永久地路由。 纤维具有粘合剂外涂层，当纤维通过工具施加在暴露的表面上，例如墙壁，天花板，模制品，凹槽或在该处所的拐角处时，其被激活。 当活化的涂层变硬时，纤维被粘合到其所施加的表面上，并且硬化的涂层也为纤维提供物理保护。 在所公开的实施例中，涂覆的纤维被供应在安装在工具上的卷轴上，并且当纤维通过包含活化物质的室从卷轴展开时引导纤维来激活涂层。 然后将具有活化涂层的纤维引导到将纤维施加到表面上的工具上的涂抹器轮上。

公开(公告)号：WO2012054616A2

公开(公告)日：2012-04-26

申请号：PCT/US2011056903

申请日：2011-10-19

Applicant: BIOFORMIX LLC ,  MALOFSKY BERNARD ,  MALOFSKY ADAM ,  DEY TANMOY ,  SULLIVAN JEFFREY M ,  CHEN YANGBIN ,  WOJCIAK STANLEY C

Inventor： MALOFSKY BERNARD ,  MALOFSKY ADAM ,  DEY TANMOY ,  SULLIVAN JEFFREY M ,  CHEN YANGBIN ,  WOJCIAK STANLEY C

IPC: C08L35/02

CPC classification number: C07C69/602 ,  C07C67/343 ,  C07C69/593 ,  C08F122/14 ,  C08F136/20 ,  C08G63/00 ,  C08L35/02 ,  C08L47/00 ,  C09D167/00 ,  Y02P20/127 ,  Y10T428/249921

Abstract: The present invention provides improved methods for the chemical synthesis of methylene malonates using the Knovenagel synthesis reaction. The method of the invention provides for improved methylene malonates by significantly reducing or eliminating the formation of alternative and/or deleterious side products, significantly reducing or eliminating unwanted consumption of methylene malonates, and significantly reducing or eliminating the degradation of methylene malonates. These advantages result in methylene malonates, which upon recovery, are of higher quality, greater purity, improved yield and possess overall improved performance characteristics (e.g., improved cure speed, retention of cure speed, improved shelf-life and/or stability).

Abstract translation: 本发明提供使用Knovenagel合成反应化学合成丙二酸亚甲酯的改进方法。 本发明的方法通过显着减少或消除替代和/或有害副产物的形成，显着减少或消除不需要的丙二酸亚丙酯消耗，以及显着降低或消除丙二酸亚甲酯的降解来提供改进的亚甲基丙二酸酯。 这些优点导致亚甲基丙二酸酯，其在回收时具有更高的质量，更高的纯度，更高的产率并且具有总体改进的性能特征（例如，改进的固化速度，固化速度的保持，改善的保存期限和/或稳定性）。

公开(公告)号：WO2012012362A3

公开(公告)日：2012-01-26

申请号：PCT/US2011/044430

申请日：2011-07-19

Applicant: URASEAL, INC. ,  OFS FITEL, LLC ,  MALOFSKY, Bernard, M. ,  MALOFSKY, Adam, G. ,  BRADLEY, Joseph, E. ,  MANN, William, H. ,  TABLE, Robert, C. ,  MORANDO, Victor, J. ,  SELLERS, James, M. ,  WINTERS, Nathan, E. ,  DEPIANO, John ,  DICKINSON, Paul, R. ,  HENDRICKSON, Daniel

Inventor： MALOFSKY, Bernard, M. ,  MALOFSKY, Adam, G. ,  BRADLEY, Joseph, E. ,  MANN, William, H. ,  TABLE, Robert, C. ,  MORANDO, Victor, J. ,  SELLERS, James, M. ,  WINTERS, Nathan, E. ,  DEPIANO, John ,  DICKINSON, Paul, R. ,  HENDRICKSON, Daniel

IPC: H01B7/08

Abstract: Among other things, a communication line is attached along a target surface of a building by laying out the line from a tool. An outer surface of the line is in a temporarily tacky condition as the line is laid out along the surface. The line is in the temporarily tacky condition based at least in part on an adhesive component having been pre-applied to the outer surface of the line. The line becomes non-tacky after it has been attached.

公开(公告)号：WO1996008186A1

公开(公告)日：1996-03-21

申请号：PCT/US1995011636

申请日：1995-09-05

Applicant: MALOFSKY, Adam, G. ,  MALOFSKY, Bernard, M. ,  GLASSBERG, Paul, R.

IPC: A47D13/06

CPC classification number: A47D13/063 ,  Y10S5/948 ,  Y10S428/902 ,  Y10T428/1372

Abstract: Playpen and crib construction which utilizes a high modulus fiber-reinforced plastic matrix tubing (10) in the frame, said tubing (10) being made of lightweight, high modulus fiber-reinforced plastic matrix composite tubing (10) having a weight of 0.25 pounds or less per lineal foot and wherein said plastic matrix is a thermoplastic resin or thermoset plastic resin with a minimum modulus of 250,000 psi; a minimum tensil strength of 6,000 psi; and a glass transition temperature of at least 50 DEG C and wherein said high modulus fiber reinforcement is selected from the group consisting of carbon fibers, aramid fibers, glass fibers, polyolefin fibers, boron fibers and mixtures thereof.

Abstract translation: 婴儿床和婴儿床结构，其在框架中使用高模量纤维增强塑料基质管（10），所述管（10）由重量为0.25磅的轻质高模量纤维增强塑料基质复合管（10）制成 或更少，并且其中所述塑料基质是具有250,000psi的最小模量的热塑性树脂或热固性塑料树脂; 最小张力强度为6,000 psi; 玻璃化转变温度至少为50℃，其中所述高模量纤维增强材料选自碳纤维，芳族聚酰胺纤维，玻璃纤维，聚烯烃纤维，硼纤维及其混合物。