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    METHOD TO OBTAIN METHYLENE MALONATE VIA BIS(HYDROXYMETHYL) MALONATE PATHWAY
    3.
    发明申请
    METHOD TO OBTAIN METHYLENE MALONATE VIA BIS(HYDROXYMETHYL) MALONATE PATHWAY 审中-公开
    通过双（羟甲基）马来酸酐途径获得亚甲基马来酸盐的方法

    公开(公告)号：WO2014110388A1

    公开(公告)日：2014-07-17

    申请号：PCT/US2014/011068

    申请日：2014-01-10

    Applicant: BIOFORMIX INC.

    Inventor： MALOFSKY, Bernard, Miles ,  MALOFSKY, Adam, Gregg ,  SULLIVAN, Jeffrey, M. ,  KISANGA, Philip, B. ,  ANDERSON, John, Joseph ,  COCKREM, Michael Charles, Milner ,  CARLBERG, Philip, Jay

    IPC: C07C69/07 ,  C07C61/00

    CPC classification number: B01J19/245 ,  B01J8/067 ,  B01J29/40 ,  B01J2208/00168 ,  B01J2208/065 ,  B01J2219/00033 ,  B01J2219/0004 ,  B01J2219/00087 ,  B01J2219/00177 ,  B01J2219/24 ,  C07C67/31 ,  C07C67/327 ,  C07C67/333 ,  C07C67/56 ,  C07C69/593 ,  C08F222/14 ,  C09D4/00 ,  C09J4/00

    Abstract: Method to obtain methylene malonate and related monomers following a bis(hydroxymethyl) malonate pathway. A bis(hydroxymethyl) malonate intermediary is subsequently reacted (i.e., subjected to thermolysis) to provide a methylene malonate monomer species. A source of formaldehyde (e.g., formalin) is provided in the presence of a basic catalyst (e.g., calcium hydroxide), to which a malonate (e.g., diethyl malonate) is added under suitable reaction conditions to obtain the desired intermediary (e.g., dialkyl bis(hydroxymethyl) malonate). The intermediary is reacted (i.e., subjected to thermolysis) under suitable conditions in the presence of a suitable catalyst (e.g., a zeolite) to obtain a methylene malonate monomer. In an exemplary embodiment, the thermolysis reaction includes the addition of the bis(hydroxymethyl) malonate intermediary onto a heated catalyst. The reaction product is collected and purified. The disclosed methods may be performed in a continuous operation. Discrete steps may be performed by using modular units within a plant.

    Abstract translation: 获得二（羟甲基）丙二酸酯途径后亚甲基丙二酸酯和相关单体的方法。 随后将双（羟甲基）丙二酸酯中间体反应（即进行热解）以提供亚甲基丙二酸酯单体种类。 在碱性催化剂（如氢氧化钙）的存在下提供甲醛源（如福尔马林），在合适的反应条件下加入丙二酸酯（如丙二酸二乙酯）以获得所需的中间体（如二烷基 双（羟甲基）丙二酸酯）。 中间体在合适的条件下，在合适的催化剂（如沸石）存在下反应（即进行热解），得到亚甲基丙二酸单体。 在一个示例性实施方案中，热解反应包括在加热的催化剂上加入双（羟甲基）丙二酸酯中间体。 收集并纯化反应产物。 所公开的方法可以在连续操作中执行。 离散步骤可以通过使用工厂内的模块化单元来执行。

    METHODS FOR ACTIVATING POLYMERIZABLE COMPOSITIONS, POLYMERIZABLE SYSTEMS, AND PRODUCTS FORMED THEREBY
    4.
    发明申请
    METHODS FOR ACTIVATING POLYMERIZABLE COMPOSITIONS, POLYMERIZABLE SYSTEMS, AND PRODUCTS FORMED THEREBY 审中-公开
    活化可聚合组合物的方法，可聚合体系和形成的产物

    公开(公告)号：WO2013149165A1

    公开(公告)日：2013-10-03

    申请号：PCT/US2013/034636

    申请日：2013-03-29

    Applicant: BIOFORMIX INC.

    Inventor： MALOFSKY, Bernard, Miles ,  MALOFSKY, Adam, Gregg ,  ELLISON, Matthew, McBrayer ,  WOJCIAK, Stanley, C.

    IPC: C08F2/38

    CPC classification number: C08F22/14 ,  C08F2/38

    Abstract: The exemplary embodiments disclosed herein relate to activating methods for initiation polymerization of methylene malonates and other polymerizable compositions. The polymerization may be activated by anionic or free radical mechanisms. Because the polymerization may occur very quickly upon contact between the activating agent and the polymerizable composition, methods are provide herein for separating or otherwise rendering the activating agent ineffective to initiate polymerization, until such a reaction is desired. The separation may be physical (separate packaging, separate application steps, encapsulation) or it may be based on latent- activation methods (activation precursors, UV activation). Products formed from the methods disclosed herein may include inks, adhesives, coatings, sealants, reactive moldings, fibers, films, sheets, medical polymers, composites, laminates and the like. Exemplary polymerizable compositions and products formed therefrom are environmentally sustainable, environmentally benign and/or biologically benign.

    Abstract translation: 本文公开的示例性实施方案涉及丙烯酸亚甲酯和其它可聚合组合物的起始聚合的活化方法。 聚合可以通过阴离子或自由基机制来活化。 因为在活化剂和可聚合组合物接触之后聚合可能非常快地发生，因此本文提供了分离或以其它方式使活化剂无效引发聚合的方法，直到需要这种反应。 分离可以是物理的（单独的包装，单独的施加步骤，包封），或者它可以基于潜在活化方法（活化前体，UV活化）。 由本文公开的方法形成的产品可以包括油墨，粘合剂，涂料，密封剂，反应性模塑品，纤维，薄膜，片材，医用聚合物，复合材料，层压材料等。 示例性的可聚合组合物和由其形成的产品是环境可持续的，环境友好的和/或生物学良性的。

    PLASTICS BONDING SYSTEMS AND METHODS
    8.
    发明申请
    PLASTICS BONDING SYSTEMS AND METHODS 审中-公开
    塑料粘结系统和方法

    公开(公告)号：WO2014078689A1

    公开(公告)日：2014-05-22

    申请号：PCT/US2013/070355

    申请日：2013-11-15

    Applicant: BIOFORMIX INC.

    Inventor： MALOFSKY, Bernard, Miles ,  MALOFSKY, Adam, Gregg ,  ELLISON, Matthew, McBrayer ,  DESOUSA, Joseph, D.

    IPC: C08J5/12

    CPC classification number: C09J4/00 ,  B32B7/10 ,  B32B7/12 ,  B32B27/06 ,  B32B27/14 ,  B32B27/26 ,  B32B37/0038 ,  B32B37/182 ,  B32B38/0012 ,  B32B2038/0016 ,  B32B2250/02 ,  B32B2605/00 ,  C09J5/00 ,  C09J5/04 ,  C09J11/06 ,  C09J2400/20 ,  C09J2400/226 ,  Y10T428/287 ,  Y10T428/2891 ,  Y10T428/31645 ,  Y10T428/31692 ,  Y10T428/31895 ,  Y10T428/31938

    Abstract: Reactive composition includes a reactive component able to form an adhesive bond between two substrates, at least one of which comprises a plastic material. The substrate may include an initiator on or near the surface thereof. The initiator may be present in the plastic material inherently, by blending in an additive package, through injection molding, or other process. The reactive component may comprise a methylene malonate, a reactive multifunctional methylene, a methylene beta ketoester, a methylene beta diketone. A carrier component for the reactive component may be selected to interact with the plastic substrate to soften and/or penetrate the surface to be bonded. The surface of the plastic may be abraded or otherwise treated to expose the initiator. The reactive component, upon contact with a suitable initiator, is able to polymerize to form an interpenetrating polymer weld.

    Abstract translation: 反应性组合物包括能够在两个基材之间形成粘合剂结合的反应性组分，其中至少一个包含塑料材料。 衬底可以在其表面上或附近包括引发剂。 引发剂可以通过在添加剂包装中，通过注射成型或其它方法共混而存在于塑料材料中。 反应性组分可以包含亚甲基丙二酸酯，反应性多官能亚甲基，亚甲基β-酮酯，亚甲基β二酮。 可以选择用于反应性组分的载体组分以与塑料基质相互作用以软化和/或渗透待结合的表面。 塑料的表面可能被磨损或以其他方式处理以暴露引发剂。 反应性组分在与合适的引发剂接触时能够聚合以形成互穿聚合物焊缝。

    OPTICAL MATERIAL AND ARTICLES FORMED THEREFROM
    9.
    发明申请
    OPTICAL MATERIAL AND ARTICLES FORMED THEREFROM 审中-公开
    光学材料及其形成的文章

    公开(公告)号：WO2013181600A2

    公开(公告)日：2013-12-05

    申请号：PCT/US2013043711

    申请日：2013-05-31

    Applicant: BIOFORMIX INC

    Inventor： ELLISON MATTHEW MCBRAYER ,  MALOFSKY BERNARD MILES ,  MALOFSKY ADAM GREGG ,  DEY TANMOY ,  SULLIVAN JEFFREY M

    IPC: C08F18/14 ,  B29D11/00

    CPC classification number: C08G63/00 ,  C07C69/38 ,  C07C69/708 ,  C08F18/14 ,  C08F222/10 ,  C09J5/00 ,  C09J167/00 ,  G02B1/04 ,  G02B6/255 ,  C08L31/06

    Abstract: Optical materials including polymerizable compositions and oligomeric and polymeric material formed therefrom. The oligomer or polymer material include structural repeat units represented by any of the formulas selected from (II), (III) and (IV). The optical material has low or substantially no absorbance of wavelengths in at least one of the spectral regions of interest. Optical components include adhesives, waveguides, spherical or non-spherical optical lenses, architectural articles, automotive components, laminated structures and composites.

    Abstract translation: 包括可聚合组合物和由其形成的低聚物和聚合材料的光学材料。 低聚物或聚合物材料包括由选自（II），（III）和（IV）的任一式表示的结构重复单元。 光学材料在感兴趣的光谱区域中的至少一个中具有低或基本上没有波长的吸光度。 光学部件包括粘合剂，波导，球形或非球面光学透镜，建筑制品，汽车部件，层压结构和复合材料。

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