METHOD FOR POLYMERIZING CYCLIC OLEFIN HAVING POLAR FUNCTIONAL GROUP, OLEFIN POLYMER PRODUCED THEREBY, OPTICAL ANTISOTROPIC FILM COMPRISING THE SAME, AND CATALYST COMPOSITION FOR POLYMERIZING THE CYCLIC OLEFIN
    7.
    发明申请
    METHOD FOR POLYMERIZING CYCLIC OLEFIN HAVING POLAR FUNCTIONAL GROUP, OLEFIN POLYMER PRODUCED THEREBY, OPTICAL ANTISOTROPIC FILM COMPRISING THE SAME, AND CATALYST COMPOSITION FOR POLYMERIZING THE CYCLIC OLEFIN 审中-公开
    聚合具有极性官能团的环烯烃的方法,生产的烯烃聚合物,包含它们的光学抗反射膜和用于聚合环烯烃的催化剂组合物

    公开(公告)号:WO2007145478A1

    公开(公告)日:2007-12-21

    申请号:PCT/KR2007/002896

    申请日:2007-06-15

    CPC classification number: C08F32/00

    Abstract: Disclosed is a method of producing a cyclic olefin polymer having a polar functional group, an olefin polymer produced by using the method, an optical anisotropic film including the olefin polymer, and a catalyst composition for producing the cyclic olefin polymer. In the olefin polymerization method and the catalyst composition for polymerization, since deactivation of the catalyst due to polar functional groups of monomers is capable of being suppressed, it is possible to produce polyolefins having a high molecular weight at high polymerization yield during polyolefin polymerization. Furthermore, the cyclic olefin having the polar functional groups has excellent polymerization reactivity and the activity of the catalyst composition including the same is maintained under a variable polymerization condition. Accordingly, the present invention is very useful for a mass-production process.

    Abstract translation: 公开了一种制备具有极性官能团的环烯烃聚合物,使用该方法制备的烯烃聚合物,包含烯烃聚合物的光学各向异性膜和用于制备环烯烃聚合物的催化剂组合物的方法。 在烯烃聚合方法和聚合用催化剂组合物中,由于能够抑制由于单体的极性官能团导致的催化剂的失活,因此可以在聚烯烃聚合期间以高聚合率产生高分子量聚烯烃。 此外,具有极性官能团的环状烯烃具有优异的聚合反应性,并且包含其的催化剂组合物的活性在可变的聚合条件下保持。 因此,本发明对于批量生产方法是非常有用的。

    POLYMERIZATION METHODS USING THE CATALYSTS
    10.
    发明申请
    POLYMERIZATION METHODS USING THE CATALYSTS 审中-公开
    使用催化剂的聚合方法

    公开(公告)号:WO2007046611A1

    公开(公告)日:2007-04-26

    申请号:PCT/KR2006/004199

    申请日:2006-10-17

    CPC classification number: C08F4/70 C08F32/08

    Abstract: Provided is a method of preparing a cyclic olefin polymer by addition polymerization of a cyclic olefin monomer, the method including contacting a metal catalyst complex represented by Formula 1 below with a cyclic olefin monomer. [M(L1)x(Ll2)y(L3)z]a[Ani]b wherein M is a Group X metal; [M(Li)χ(L'2)y(L3)z] is a cationic complex; Li is an anionic hydrocarbyl-containing ligand; U2 is a neutral ligand; L3 is an N-heterocyclic carbene ligand; [Ani] is an anion capable of weakly coordinating with the metal M; x is 1 or 2; y is 0 to 4; z is 1 or 2;2≤x+y+z≤6; a and b are respectively the number of cations and the number of anions capable of weakly coordinating with the metal M and are each a number of 1-10 which is used to satisfy the net charge balance of the metal catalyst complex, and wherein for each of L1, L2, and L3, when a plurality of ligands are present in a molecule of the metal catalyst complex, the ligands may be the same or different. According to the method of the present invention, a high molecular weight cyclic olefin addition polymer can be produced in a high yield even when using a polar functional group-containing cyclic olefin monomer. A polymer produced using the method shows good thermal stability.

    Abstract translation: 提供通过环状烯烃单体的加成聚合制备环状烯烃聚合物的方法,该方法包括使由下述通式1表示的金属催化剂络合物与环状烯烃单体接触。 [式1] [M(L1)x(Ll2)y(L3)z] a [Ani] b其中M是第X族金属; [M(Li)2(L'2)y(L3)z]是阳离子络合物; Li是含阴离子烃基的配体; U2是中性配体; L3是N-杂环卡宾配体; [Ani]是能够与金属M弱配位的阴离子; x为1或2; y为0〜4; z为1或2; 2 = x + y + z = 6; a和b分别是能够与金属M弱配位的阳离子数和阴离子数,并且各自为1-10,其用于满足金属催化剂络合物的净电荷平衡,并且其中对于每个 的L1,L2和L3,当多个配体存在于金属催化剂络合物的分子中时,配体可以相同或不同。 根据本发明的方法,即使使用含极性官能团的环状烯烃单体,也可以高产率地制造高分子量环状烯烃加成聚合物。 使用该方法制备的聚合物显示出良好的热稳定性。

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