公开(公告)号：WO2009100224A1

公开(公告)日：2009-08-13

申请号：PCT/US2009/033228

申请日：2009-02-05

Applicant: SHELL OIL COMPANY ,  SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. ,  BARNES, Julian, Richard ,  RANEY, Kirk, Herbert ,  SEMPLE, Thomas, Carl ,  SHPAKOFF, Paul, Gregory ,  SMIT, Johan, Paul ,  SMIT, Jasper, Roelf

Inventor： BARNES, Julian, Richard ,  RANEY, Kirk, Herbert ,  SEMPLE, Thomas, Carl ,  SHPAKOFF, Paul, Gregory ,  SMIT, Johan, Paul ,  SMIT, Jasper, Roelf

IPC: C09K8/584 ,  B01F17/00

CPC classification number: C09K8/584

Abstract: The present invention provides a method of treating a hydrocarbon containing formation comprising (a) providing a hydrocarbon recovery composition to at least a portion of the hydrocarbon containing formation, wherein the composition comprises one or more internal olefin sulfonates having 17 or more carbon atoms, (b) adding water and/or brine from the hydrocarbon formation to the composition, (c) adding a solubilizer which comprises an ethoxylated alcohol wherein the alcohol before ethoxylation had an average molecular weight of at least 220 and (d) allowing the composition to interact with hydrocarbons in the hydrocarbon containing formation. The solubilizer may comprise less than 0.1 wt%, preferably from 0.02 to 0.05 wt%, of the total composition and it may have from 5 to 9 moles of ethylene oxide per mole of alcohol.

Abstract translation: 本发明提供了一种处理含烃地层的方法，包括（a）向含烃地层的至少一部分提供烃回收组合物，其中所述组合物包含一种或多种具有17个或更多个碳原子的内烯烃磺酸盐（ b）从组合物中加入水和/或盐水，（c）加入包含乙氧基化醇的增溶剂，其中乙氧基化前的醇的平均分子量至少为220，（d）允许组合物相互作用 含烃类地层中的烃类。 增溶剂可以占总组合物的小于0.1重量％，优选0.02至0.05重量％，并且每摩尔醇可具有5至9摩尔环氧乙烷。

公开(公告)号：WO2007030437A1

公开(公告)日：2007-03-15

申请号：PCT/US2006/034513

申请日：2006-09-06

Applicant: SHELL OIL COMPANY ,  RANEY, Kirk, Herbert ,  SHPAKOFF, Paul, Gregory

Inventor： RANEY, Kirk, Herbert ,  SHPAKOFF, Paul, Gregory

IPC: C11D1/83 ,  C11D3/20 ,  C11D3/30

CPC classification number: C11D1/83 ,  C11D1/29 ,  C11D1/72 ,  C11D3/2044 ,  C11D3/30 ,  C11D3/43

Abstract: A liquid surface active composition which is comprised of an alcohol ethoxysulfate, an alcohol ethoxylate, c) an additive which is triethanolamine or a diol comprised of carbon, oxygen, and hydrogen atoms and which has a molecular weight of 75 to 225, and water.

Abstract translation: 由醇乙氧基硫酸盐，醇乙氧基化物，c）作为三乙醇胺或由碳，氧和氢原子组成的二醇，分子量为75〜225的添加剂和水组成的液面活性组合物。

公开(公告)号：WO2005023750A3

公开(公告)日：2005-05-19

申请号：PCT/US2004027737

申请日：2004-08-26

Applicant: SHELL OIL CO ,  DE BOER-WILDSCHUT MARIJKE ,  RANEY KIRK HERBERT ,  VAN ZON ARIE

Inventor： DE BOER-WILDSCHUT MARIJKE ,  RANEY KIRK HERBERT ,  VAN ZON ARIE

IPC: A61K8/37 ,  A61Q15/00 ,  A61Q17/04 ,  A61Q19/00 ,  C07C69/02 ,  C07C69/24 ,  C07C69/52 ,  C07C69/612 ,  C07C69/616 ,  A61K7/48

CPC classification number: A61Q19/00 ,  A61K8/37 ,  A61Q15/00 ,  A61Q17/04 ,  C07C69/24

Abstract: A branched ester composition obtainable by the reaction of a carboxylic acid with a branched alcohol composition under esterification reaction conditions wherein the branched alcohol composition has from 8 to 36 carbon atoms and an average number of branches per molecule of from 0.7 to 3.0, said branching comprising methyl and ethyl branches. The present invention further relates to personal care compositions for topical application to the skin or hair comprising said branched ester composition. The branched ester composition of the invention provides improved formulation flexibility.

Abstract translation: 一种支链酯组合物，其通过羧酸与支链醇组合物在酯化反应条件下反应得到，其中支链醇组合物具有8至36个碳原子，每分子平均支链数为0.7至3.0，所述支化包括 甲基和乙基支链。 本发明还涉及用于局部施用于包含所述支链酯组合物的皮肤或头发的个人护理组合物。 本发明的支链酯组合物提供改进的制剂柔性。

公开(公告)号：WO2004081342A2

公开(公告)日：2004-09-23

申请号：PCT/US2004/007251

申请日：2004-03-10

Applicant: SHELL OIL COMPANY ,  SHPAKOFF, Paul, Gregory ,  RANEY, Kirk, Herbert

Inventor： SHPAKOFF, Paul, Gregory ,  RANEY, Kirk, Herbert

IPC: E21B43/22

CPC classification number: C09K8/584

Abstract: A method of treating a hydrocarbon containing formation is described. The method may include providing a hydrocarbon recovery composition to the hydrocarbon containing formation. Hydrocarbons in the hydrocarbon containing formation may interact with the hydrocarbon recovery composition. The hydrocarbon recovery composition may include an aliphatic anionic surfactant and an aliphatic nonionic additive. In some embodiments, an aliphatic anionic surfactant may be branched. In other embodiments, an aliphatic nonionic additive may be branched.

Abstract translation: 描述了处理含烃地层的方法。 该方法可以包括向含烃地层提供烃回收组合物。 烃类地层中的碳氢化合物可与烃回收组合物相互作用。 烃回收组合物可以包括脂族阴离子表面活性剂和脂族非离子添加剂。 在一些实施方案中，脂族阴离子表面活性剂可以是支链的。 在其它实施方案中，脂族非离子添加剂可以是支链的。

公开(公告)号：WO2004022013A1

公开(公告)日：2004-03-18

申请号：PCT/US2003/027127

申请日：2003-08-29

Applicant: SHELL OIL COMPANY ,  RANEY, Kirk, Herbert ,  BURNLEY, Carolyn, Ann

Inventor： RANEY, Kirk, Herbert ,  BURNLEY, Carolyn, Ann

IPC: A61K7/06

CPC classification number: A61Q17/04 ,  A61K8/342 ,  A61Q5/00 ,  A61Q19/00

Abstract: A personal care composition for topical application to the skin or hair comprising (i) a branched primary alcohol component, having from 8 to 36 carbon atoms per molecule and an average number of branches per molecule of at least 0.7, preferably from 0.7 to 3.0, said branching preferably comprising methyl and/or ethyl branches, and said branched primary alcohol component optionally comprising up to 3 moles of alkylene oxide per mole of alcohol, or said branched primary alcohol component optionally comprising a product made by reacting alkylene oxide with branched primary alcohol in a ratio of up to 3 moles of alkylene oxide per mole of alcohol; and (ii) a cosmetically-acceptable vehicle. The personal care compositions of the invention provide excellent stability, viscosity and rheology characteristics, together with emolliency, application and skin feel benefits.

Abstract translation: 其用于局部施用于皮肤或头发的个人护理组合物，其包含（i）每分子具有8至36个碳原子的分支伯醇组分和每分子平均分支数为至少0.7，优选0.7至3.0， 所述分支优选包含甲基和/或乙基支链，并且所述支化伯醇组分任选地包含每摩尔醇最多3摩尔环氧烷烃，或所述支化伯醇组分，任选地包含通过使环氧烷与支化伯醇反应制得的产物 以每摩尔醇高达3摩尔环氧烷烃的比例; 和（ii）美容上可接受的载体。 本发明的个人护理组合物提供优异的稳定性，粘度和流变特性，以及润肤性，使用性和皮肤感觉益处。

公开(公告)号：WO2012163852A1

公开(公告)日：2012-12-06

申请号：PCT/EP2012/059891

申请日：2012-05-25

Applicant: SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. ,  RANEY, Kirk, Herbert ,  NAVARRETE, Reinaldo, Conrado ,  DIRKZWAGER, Hendrik ,  BARNES, Julian, Richard ,  MOENE, Robert

Inventor： RANEY, Kirk, Herbert ,  NAVARRETE, Reinaldo, Conrado ,  DIRKZWAGER, Hendrik ,  BARNES, Julian, Richard ,  MOENE, Robert

IPC: C09K8/584

CPC classification number: C09K8/584 ,  C09K8/588 ,  E21B43/16

Abstract: The invention relates to a hydrocarbon recovery composition comprising an anionic surfactant, wherein said composition is in the solid state, and to a shaped article comprising said composition. Preferably, said composition is in the form of a powder. Further, the invention relates to a process for treating a hydrocarbon containing formation comprising the steps of a) transporting said composition or shaped article to the location of the hydrocarbon containing formation; b) dissolving said composition or shaped article in water thereby forming an aqueous fluid containing the hydrocarbon recovery composition; c) providing the aqueous fluid containing the hydrocarbon recovery composition to at least a portion of the hydrocarbon containing formation; and d) allowing the hydrocarbon recovery composition to interact with the hydrocarbons in the hydrocarbon containing formation.

Abstract translation: 本发明涉及一种烃回收组合物，其包含阴离子表面活性剂，其中所述组合物为固体状态，以及包含所述组合物的成型制品。 优选地，所述组合物为粉末形式。 此外，本发明涉及一种处理含烃地层的方法，包括以下步骤：a）将所述组合物或成型制品运输到含烃地层的位置; b）将所述组合物或成型制品溶解在水中，从而形成含有烃回收组合物的含水流体; c）将含有烃回收组合物的含水流体提供给含烃地层的至少一部分; 和d）允许烃回收组合物与含烃地层中的烃相互作用。

公开(公告)号：WO2012091880A2

公开(公告)日：2012-07-05

申请号：PCT/US2011/064083

申请日：2011-12-09

Applicant: SHELL OIL COMPANY ,  SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. ,  BARNES, Julian Richard ,  BUECHELE, James Laurel ,  ELLISON, Robert Hardy ,  RANEY, Kirk Herbert ,  SEMPLE, Thomas Carl ,  SMIT, Johan Paul

Inventor： BARNES, Julian Richard ,  BUECHELE, James Laurel ,  ELLISON, Robert Hardy ,  RANEY, Kirk Herbert ,  SEMPLE, Thomas Carl ,  SMIT, Johan Paul

IPC: C09K8/58 ,  C09K8/32 ,  E21B43/16

CPC classification number: C09K8/584

Abstract: A hydrocarbon recovery composition comprising vinylidene based alkoxylate derivatives. A method of treating a crude oil formation and a method of preparing the hydrocarbon recovery composition are also described.

Abstract translation: 包含基于亚乙烯基的烷氧基化物衍生物的烃采收组合物。 还描述了处理原油地层的方法和制备烃采收组合物的方法。

公开(公告)号：WO2009100301A1

公开(公告)日：2009-08-13

申请号：PCT/US2009/033345

申请日：2009-02-06

Applicant: SHELL OIL COMPANY ,  SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. ,  RANEY, Kirk Herbert ,  SEMPLE, Thomas Carl

Inventor： RANEY, Kirk Herbert ,  SEMPLE, Thomas Carl

IPC: C09K8/584 ,  B01F17/00

CPC classification number: C09K8/584

Abstract: A method of treating a hydrocarbon containing formation, comprising (a) providing a hydrocarbon recovery composition to at least a portion of the hydrocarbon containing formation, wherein the hydrocarbon recovery composition comprises a propoxylated composition which comprises (1) a glycerol sulfonate of a propoxylated primary alcohol having a branched aliphatic group with an average carbon number from 10 to 24 and having an average number of branches per aliphatic group of from 0.7 to 2.5 and having at least 0.5, preferably from 3 to 12, moles of propylene oxide per mole of primary alcohol and (2) polypropylene glycol; provided that the primary alcohol is propoxylated by contacting the alcohol with propylene oxide in the presence of a catalytically effective amount of one or more of the phosphate salts of lanthanum series elements or the rare earth elements, preferably a carbonate salt thereof, wherein the propoxylated composition comprising the propoxylated alcohol and from 1 to 30 wt% of polypropylene glycol is produced; and (b) allowing the composition to interact with hydrocarbons in the hydrocarbon containing formation.

Abstract translation: 一种处理含烃地层的方法，包括（a）向所述含烃地层的至少一部分提供烃回收组合物，其中所述烃回收组合物包含丙氧基化组合物，其包含（1）丙氧基化初级的甘油磺酸盐 具有平均碳数为10至24并且每个脂族基团的平均分支数为0.7至2.5并且每摩尔初级粒子具有至少0.5，优选3至12摩尔环氧丙烷的支链脂族基团的醇的醇， 醇和（2）聚丙二醇; 条件是通过在催化有效量的一种或多种镧系元素的磷酸盐或稀土元素，优选其碳酸盐的存在下使醇与环氧丙烷接触，将伯醇丙氧基化，其中丙氧基化组合物 包括丙氧基化醇和1至30wt％的聚丙二醇; 和（b）允许组合物与含烃地层中的烃相互作用。

公开(公告)号：WO2009100228A1

公开(公告)日：2009-08-13

申请号：PCT/US2009/033232

申请日：2009-02-05

Applicant: SHELL OIL COMPANY ,  SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. ,  BARNES, Julian Richard ,  RANEY, Kirk Herbert ,  SEMPLE, Thomas Carl ,  SHPAKOFF, Paul Gregory

Inventor： BARNES, Julian Richard ,  RANEY, Kirk Herbert ,  SEMPLE, Thomas Carl ,  SHPAKOFF, Paul Gregory

IPC: C09K8/584 ,  B01F17/00

CPC classification number: C09K8/58 ,  C09K8/584

Abstract: A method of treating a hydrocarbon containing formation is described. The method includes (a) providing a hydrocarbon recovery composition to at least a portion of the hydrocarbon containing formation, wherein (i) when the salinity of the brine is from 2 wt% to 4 wt%, the composition comprises a blend of a C 20-24 internal olefin sulfonate and a C 24-28 internal olefin sulfonate wherein the weight ratio of the C 20-24 internal olefin sulfonate to the C 24-28 internal olefin sulfonate is from 90:10 to 70:30 and (ii) when the salinity of the brine is greater than 4 wt% up to 13 wt% the composition comprises a blend of a C 20-24 internal olefin sulfonate and a C 15-18 internal olefin sulfonate wherein the weight ratio of the C 20-24 internal olefin sulfonate to the C 15-18 internal olefin sulfonate is from 90:10 to 70:30; and (b) allowing the composition to interact with hydrocarbons in the hydrocarbon containing formation.

Abstract translation: 描述了处理含烃地层的方法。 该方法包括（a）向含烃地层的至少一部分提供烃回收组合物，其中（i）当盐水的盐度为2重量％至4重量％时，组合物包含C20 -24内烯烃磺酸盐和C24-28内烯烃磺酸盐，其中C20-24内烯烃磺酸盐与C24-28内烯烃磺酸盐的重量比为90:10至70:30，和（ii）当盐度为 盐水大于4重量％至13重量％，该组合物包含C20-24内烯烃磺酸盐和C15-18内烯烃磺酸盐的共混物，其中C20-24内烯烃磺酸盐与C15- 18内烯烃磺酸盐为90:10至70:30; 和（b）允许组合物与含烃地层中的烃相互作用。

公开(公告)号：WO2009015137A1

公开(公告)日：2009-01-29

申请号：PCT/US2008/070749

申请日：2008-07-22

Applicant: SHELL OIL COMPANY ,  SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. ,  RANEY, Kirk Herbert ,  SHPAKOFF, Paul Gregory ,  WHITE, Bryan Matthew

Inventor： RANEY, Kirk Herbert ,  SHPAKOFF, Paul Gregory ,  WHITE, Bryan Matthew

IPC: C07C303/24 ,  C07C305/10 ,  C11D1/29 ,  C11D11/04 ,  C11D1/94

CPC classification number: C11D1/29 ,  C07C303/24 ,  C11D11/04 ,  C07C305/10

Abstract: A process for making a useful cleaning product from an alkoxylate of a secondary alcohol which comprises: (a) partially sulfating a secondary alcohol alkoxylate with sulfur trioxide in a falling film sulfation reactor at a molar ratio of sulfur trioxide to secondary alcohol alkoxylate of less than 0.9 to produce a mixture comprising a sulfuric acid ester of the secondary alcohol alkoxylate and secondary alcohol alkoxylate which may comprise at least 50 percent by weight of the sulfuric acid ester of the secondary alcohol alkoxylate, (b) combining the mixture with a neutralizing agent in an amount sufficient to neutralize the sulfuric acid ester, and (c) optionally adding water to yield a useful cleaning product.

Abstract translation: 一种从仲醇的烷氧基化物制备有用的清洁产物的方法，其包括：（a）在降膜硫酸化反应器中以三氧化硫与仲醇烷氧基化物的摩尔比部分硫酸化仲三醇氧化物与仲醇烷氧基化物的摩尔比小于 0.9以产生包含仲醇烷氧基化物的硫酸酯和仲醇烷氧基化物的混合物，其可以包含至少50重量％的仲醇烷氧基化物的硫酸酯，（b）将混合物与中和剂混合 足以中和硫酸酯的量，和（c）任选地加入水以产生有用的清洁产品。