公开(公告)号：WO2010030550A3

公开(公告)日：2010-06-03

申请号：PCT/US2009055824

申请日：2009-09-03

申请人： GUARDIAN INDUSTRIES ,  SHARMA PRAMOD K

发明人： SHARMA PRAMOD K

IPC分类号： B05D5/00 ,  B01J21/06 ,  C01G23/047

CPC分类号： A01N59/16 ,  B01J21/063 ,  B01J35/004 ,  B01J37/0215 ,  B01J37/08 ,  C01G23/053 ,  C01P2002/84 ,  C03C17/256 ,  C03C2217/212 ,  C03C2218/113 ,  C09C1/3607 ,  A01N25/04 ,  A01N25/34

摘要： Methods for forming titanium dioxide coatings having crystals comprising reduced crystallite size are disclosed. Sol-gel compositions are prepared, formed on a substrate, and the coated substrate is heated at a temperature sufficient to form a titanium dioxide coating with crystals having a reduced crystallite size. Titanium dioxide coatings having crystals comprising reduced crystallite size and having at least one of improved antimicrobial properties, self-cleaning properties, and/or hydrophilicity are also disclosed. Substrates comprising such coatings are also disclosed.

摘要翻译： 公开了形成具有包含减小的微晶尺寸的晶体的二氧化钛涂层的方法。 制备溶胶 - 凝胶组合物，在基材上形成，并将涂覆的基材在足以形成具有减小的微晶尺寸的晶体的二氧化钛涂层的温度下加热。 还公开了具有包含减小的微晶尺寸并具有改善的抗微生物性质，自清洁性质和/或亲水性中的至少一种的晶体的二氧化钛涂层。 还公开了包含这种涂层的基材。

公开(公告)号：WO2010030550A2

公开(公告)日：2010-03-18

申请号：PCT/US2009/055824

申请日：2009-09-03

申请人： GUARDIAN INDUSTRIES CORP. ,  SHARMA, Pramod, K.

发明人： SHARMA, Pramod, K.

IPC分类号： B05D5/00 ,  B05D3/00 ,  C09D5/00 ,  B05D7/00

CPC分类号： A01N59/16 ,  B01J21/063 ,  B01J35/004 ,  B01J37/0215 ,  B01J37/08 ,  C01G23/053 ,  C01P2002/84 ,  C03C17/256 ,  C03C2217/212 ,  C03C2218/113 ,  C09C1/3607 ,  A01N25/04 ,  A01N25/34

摘要： Methods for forming titanium dioxide coatings having crystals comprising reduced crystallite size are disclosed. Sol-gel compositions are prepared, formed on a substrate, and the coated substrate is heated at a temperature sufficient to form a titanium dioxide coating with crystals having a reduced crystallite size. Titanium dioxide coatings having crystals comprising reduced crystallite size and having at least one of improved antimicrobial properties, self-cleaning properties, and/or hydrophilicity are also disclosed. Substrates comprising such coatings are also disclosed.

摘要翻译： 公开了形成具有减小的微晶尺寸的晶体的二氧化钛涂层的方法。 在基材上制备溶胶 - 凝胶组合物，并将涂覆的基材在足以形成具有减小的微晶尺寸的晶体形成二氧化钛涂层的温度下加热。 还公开了具有包含减小的微晶尺寸和具有改进的抗微生物性质，自清洁性能和/或亲水性中的至少一种的晶体的二氧化钛涂层。 还公开了包含这种涂层的基材。

公开(公告)号：WO2008153617A3

公开(公告)日：2009-09-24

申请号：PCT/US2008004706

申请日：2008-04-11

申请人： GUARDIAN INDUSTRIES ,  SHARMA PRAMOD K ,  TAYLOR THOMAS J

发明人： SHARMA PRAMOD K ,  TAYLOR THOMAS J

IPC分类号： H01L31/0216 ,  H01L31/048 ,  H01L31/18

CPC分类号： H01L31/02168 ,  C03C17/3417 ,  C03C2217/732 ,  C03C2218/113 ,  Y02E10/50 ,  Y10T428/12493

摘要： A method of making a photovoltaic device including an antireflective coating, including: forming a coating solution by mixing a mono-metal oxide, a bi-metal oxide, a silane, or a siloxane with a solvent, such that the coating solution may be used as a barrier between the antireflective coating and a glass substrate that inhibits sodium ion migration in the glass substrate after exposure to environmental factors including humidity and temperature. A photovoltaic device including a photovoltaic film, a glass substrate, and a barrier layer provided on the glass substrate; an anti- reflection coating provided on the glass substrate and on the barrier layer; wherein the barrier layer comprises one or more of the following: a mono-metal oxide, a bi-metal oxide, a silane, or a siloxane.

摘要翻译： 一种制造包括抗反射涂层的光伏器件的方法，包括：通过将单金属氧化物，双金属氧化物，硅烷或硅氧烷与溶剂混合形成涂布溶液，使得可以使用涂布溶液 作为在暴露于包括湿度和温度的环境因素之后，在玻璃基板中抑制钠离子迁移的抗反射涂层和玻璃基板之间的屏障。 一种光电器件，包括设置在所述玻璃基板上的光伏膜，玻璃基板和阻挡层; 设置在玻璃基板上和阻挡层上的抗反射涂层; 其中所述阻挡层包含一种或多种以下物质：单金属氧化物，双金属氧化物，硅烷或硅氧烷。

公开(公告)号：WO2008136894A3

公开(公告)日：2008-11-13

申请号：PCT/US2008/004385

申请日：2008-04-04

申请人： GUARDIAN INDUSTRIES CORP. ,  SHARMA, Pramod, K.

发明人： SHARMA, Pramod, K.

IPC分类号： H01L31/0216 ,  C03C17/25 ,  C03C17/00

摘要： A method of making an anti-reflection coating using a sol-gel process, for use in a photovoltaic device or the like. The method may include the following steps in certain example embodiments: forming a polymeric component of silica by mixing silane(s) with one or more of a first solvent, a catalyst, and water; forming a silica sol gel by mixing the polymeric component with a colloidal silica, and optionally a second solvent; forming a combined sol by mixing siloxane(s) with the silica sol; casting the mixture by spin coating or the like to form a silica and siloxane containing layer on a substrate; and curing and/or heat treating the layer. This layer may make up all or only part of an anti-reflection coating which may be used in a photovoltaic device or the like.

公开(公告)号：WO2009075705A1

公开(公告)日：2009-06-18

申请号：PCT/US2008/011218

申请日：2008-09-26

申请人： CENTRE LUXEMBOURGEOIS DE RECHERCHES POUR LE VERRE ET LA CERAMIQUE S.A. (C.R.V.C.) ,  GUARDIAN INDUSTRIES CORP. ,  DISTELDORF, Bernd ,  SHARMA, Pramod, K. ,  MELLOTT, Nathan, P.

发明人： DISTELDORF, Bernd ,  SHARMA, Pramod, K. ,  MELLOTT, Nathan, P.

IPC分类号： C03C17/00 ,  C03C17/34 ,  G02B1/11 ,  H01L31/0216 ,  C23C16/40

CPC分类号： G02B1/113 ,  C03C17/002 ,  C03C17/3417 ,  C03C17/3458 ,  C03C2217/732 ,  C03C2218/15 ,  H01L31/02167 ,  H01L31/18

摘要： This invention relates to a method' of making glass. In certain example embodiments, a major surface (s) of the glass is treated with aluminum chloride (e.g., A1C13). This treating, or application of an aluminum chloride based layer on the glass substrate, may be performed using combustion deposition. The combustion deposition may be performed at or just prior to the annealing lehr in certain example embodiments, or at any other suitable location. The aluminum chloride barrier layer, applied at a desirable glass temperature, helps to reduce sodium leaching or diffusion from the glass during conditions such as high heat and/or humidity, thereby improving the durability and/or stability of the resulting product. At least some of the aluminium oxide (AL203) during the coating process.

摘要翻译： 本发明涉及一种制造玻璃的方法。 在某些示例性实施方案中，玻璃的主要表面用氯化铝（例如，A1C13）处理。 可以使用燃烧沉积来在玻璃基板上处理或施加氯化铝基层。 燃烧沉积可以在某些示例性实施例中或在任何其它适当位置处在退火退火炉之前或之前进行。 以期望的玻璃温度施加的氯化铝阻挡层有助于在诸如高热和/或湿度的条件期间减少钠浸出或扩散玻璃，从而提高所得产品的耐久性和/或稳定性。 在涂覆过程中至少有一些氧化铝（AL203）。

公开(公告)号：WO2009025694A1

公开(公告)日：2009-02-26

申请号：PCT/US2008/007489

申请日：2008-06-16

申请人： GUARDIAN INDUSTRIES CORP. ,  SHARMA, Pramod, K.

发明人： SHARMA, Pramod, K.

IPC分类号： C03C17/30 ,  C03C17/25

CPC分类号： C03C17/30 ,  C03C17/25 ,  C03C2217/213 ,  C03C2218/113 ,  Y10T428/24372 ,  Y10T428/249974 ,  Y10T428/2991 ,  Y10T428/2995 ,  Y10T428/31663

摘要： There is provided a forming a solution by mixing at least a polymeric silane, a solvent, acetone, acetic acid, and a rheological enhancer, wherein the rheological enhancer may comprise an acrylic latex; and agitating the solution. Also provided are methods of using the same in coated articles, and coated articles themselves.

摘要翻译： 提供通过混合至少聚合硅烷，溶剂，丙酮，乙酸和流变增强剂形成溶液，其中流变增强剂可以包含丙烯酸胶乳; 并搅动溶液。 还提供了在涂覆制品中使用它们的方法，以及涂覆物品本身。

公开(公告)号：WO2009002377A1

公开(公告)日：2008-12-31

申请号：PCT/US2008/005265

申请日：2008-04-24

申请人： GUARDIAN INDUSTRIES CORP. ,  SHARMA, Pramod, K.

发明人： SHARMA, Pramod, K.

IPC分类号： C01B33/141 ,  C01B33/145 ,  C09D1/00 ,  C03C1/00 ,  C03C17/00

CPC分类号： C09D7/61 ,  C01B33/1485 ,  C03C17/02 ,  C03C17/3411 ,  C03C2217/74 ,  C03C2218/113 ,  C08K3/36 ,  C09D7/67 ,  Y10T428/31612

摘要： There is provided a method of making a stabilized colloidal silica solution, the method including forming a solution by mixing a colloidal silica, a solvent, and a stabilizing agent, wherein the stabilizing agent is selected from the group consisting of siloxane-based stabilizers, polysorbate-based stabilizers, non-ionic surfactant based stabilizers, and acrylic polymer-based flow-enhancing stabilizers; and agitating the solution. There is also provided methods of using the same in coated articles, and coated articles themselves.

摘要翻译： 提供一种制备稳定的胶体二氧化硅溶液的方法，该方法包括通过混合胶体二氧化硅，溶剂和稳定剂形成溶液，其中稳定剂选自硅氧烷基稳定剂，聚山梨酯 基于稳定剂，非离子表面活性剂基稳定剂和基于丙烯酸聚合物的流动增强稳定剂; 并搅动溶液。 还提供了在涂布制品中使用它们的方法以及涂覆物品本身。

公开(公告)号：WO2008112047A2

公开(公告)日：2008-09-18

申请号：PCT/US2008/001368

申请日：2008-02-01

申请人： GUARDIAN INDUSTRIES CORP. ,  SHARMA, Pramod, K.

发明人： SHARMA, Pramod, K.

IPC分类号： H01L31/0216

CPC分类号： G02B1/113 ,  C03C3/078 ,  C03C17/25 ,  C03C17/3417 ,  C03C2217/213 ,  C03C2217/214 ,  C03C2217/22 ,  C03C2217/23 ,  C03C2217/732 ,  C03C2217/78 ,  C03C2218/113 ,  C03C2218/365 ,  C08K3/36 ,  C09D183/06 ,  G02B1/105 ,  G02B1/14 ,  H01L31/02168 ,  H01L31/03921 ,  Y02E10/50 ,  Y10T428/31663

摘要： A method of making an anti -reflection coating using a sol-gel process, for use in a photovoltaic device or the like. The method may include the following steps in certain example embodiments: forming a polymeric component of silica by mixing silane(s) with one or more of a first solvent, a catalyst, and water; forming a silica sol gel by mixing the polymeric component with a colloidal silica, and optionally a second solvent; forming a metal oxide sol by mixing silane(s) with a metal oxide, a second catalyst, and a third solvent; forming a combined sol by mixing the metal oxide sol with the silica sol; casting the mixture by spin coating or the like to form a silica and metal oxide containing layer on a substrate; and curing and/or heat treating the layer. This layer may make up all or only part of an anti-reflection coating which may be used in a photovoltaic device or the like.

摘要翻译： 使用溶胶 - 凝胶法制造用于光伏器件等的抗反射涂层的方法。 该方法可以在某些示例性实施方案中包括以下步骤：通过将硅烷与一种或多种第一溶剂，催化剂和水混合形成二氧化硅的聚合物组分; 通过将聚合物组分与胶体二氧化硅和任选的第二溶剂混合形成硅溶胶凝胶; 通过将硅烷与金属氧化物，第二催化剂和第三溶剂混合来形成金属氧化物溶胶; 通过将金属氧化物溶胶与二氧化硅溶胶混合形成组合溶胶; 通过旋涂等浇注混合物以在基材上形成二氧化硅和含金属氧化物的层; 并固化和/或热处理该层。 该层可以构成可用于光伏器件等的抗反射涂层的全部或仅有的一部分。

公开(公告)号：WO2007081497A1

公开(公告)日：2007-07-19

申请号：PCT/US2006/048238

申请日：2006-12-19

申请人： GUARDIAN INDUSTRIES CORP. ,  SHARMA, Pramod, K. ,  VARAPRASAD, Desaraju, V. ,  TAYLOR, Thomas, J.

发明人： SHARMA, Pramod, K. ,  VARAPRASAD, Desaraju, V. ,  TAYLOR, Thomas, J.

IPC分类号： C03C8/14 ,  C03C17/04 ,  F21V9/06 ,  G02B5/02

CPC分类号： F21V9/06 ,  C03C8/00 ,  C03C17/007 ,  C03C17/008 ,  C03C2217/452 ,  C03C2217/477 ,  C03C2218/31 ,  C03C2218/365 ,  G02B5/0221 ,  G02B5/0242 ,  G02B5/0278 ,  G02B5/0294 ,  G02B5/208

摘要： A diffuser is provided in an illumination system, where the diffuser is capable of blocking significant amounts of ultraviolet (UV) radiation. In certain example embodiments of this invention, the diffuser includes a glass substrate which supports a UV coating(s) that blocks significant amounts of UV radiation thereby reducing the amount of UV radiation which can makes its way through the diffuser. In certain example embodiments, the coating may include inorganic particulate in a frit matrix so that the coating may both diffuse visible light and perform UV blocking.

摘要翻译： 扩散器设置在照明系统中，其中扩散器能够阻挡大量的紫外（UV）辐射。 在本发明的某些示例性实施例中，漫射器包括玻璃基底，其支撑阻挡大量UV辐射的UV涂层，从而减少可以使其穿过扩散器的UV辐射的量。 在某些示例性实施例中，涂层可以包括玻璃料基质中的无机颗粒，使得涂层可以漫射可见光并进行UV阻挡。

公开(公告)号：WO2007081484A9

公开(公告)日：2007-07-19

申请号：PCT/US2006/047589

申请日：2006-12-14

申请人： GUARDIAN INDUSTRIES CORP. ,  SHARMA, Pramod, K. ,  TAYLOR, Thomas, J.

发明人： SHARMA, Pramod, K. ,  TAYLOR, Thomas, J.

IPC分类号： G02B5/02 ,  C03C17/00 ,  F21V5/00 ,  G02F1/1335

摘要： A diffuser is provided that includes a glass substrate with a diffusing coating thereon. The diffusing coating may include one or more layers. In certain example embodiments, the diffusing coating comprises inorganic pigments therein for light diffusing purposes, and the inorganic pigments are sized so as to permit a diffuser having a combination of high visible transmission and good diffusion qualities to be realized. In certain example embodiments, the diffusing coating may be of or include a frit with the inorganic pigments therein.