公开(公告)号：WO2010067379A3

公开(公告)日：2011-03-24

申请号：PCT/IN2009000708

申请日：2009-12-08

Applicant: RELIANCE IND LTD ,  MANDAL SUKUMAR ,  DAS ASIT KUMAR ,  YADAV ASHWANI ,  YADAV MANOJ ,  BHATNAGAR AKHILESH ,  DONGARA RAJESHWAR ,  KATRAVULAPALLI VEERA VENKATA SATYA BHASKARA SITA R

Inventor： MANDAL SUKUMAR ,  DAS ASIT KUMAR ,  YADAV ASHWANI ,  YADAV MANOJ ,  BHATNAGAR AKHILESH ,  DONGARA RAJESHWAR ,  KATRAVULAPALLI VEERA VENKATA SATYA BHASKARA SITA R

IPC: C10G11/05

CPC classification number: C10G11/18 ,  C10G11/05 ,  C10G2400/20

Abstract: A fluid catalytic cracking (FCC) process for manufacturing propylene and ethylene in increased yield. The process comprises cracking an olefinic naphtha stream and main hydrocarbon stock in combination with an olefinic C4 hydrocarbon stream in different zones of one or more risers of an FCC unit. Each FCC riser comprises an acceleration zone at the lower portion thereof, a lift stream feed nozzle at the bottom of the acceleration zone, a main hydrocarbon stock feed nozzle above the acceleration zone and an olefinic naphtha feed nozzle at a location along the acceleration zone between the lift stream feed nozzle and main hydrocarbon stock feed nozzle. The cracking is carried out on a mixed FCC catalyst comprising atleast 2 percent by weight pentasil zeolite and at least 10 percent by weight Y- zeolite. The catalyst is injected at the bottom of each FCC riser, the olefinic naptha is injected through the olefinic feed nozzle, the main hydrocarbon stock is injected through the main hydrocarbon stock feed nozzle and the lift stream is injected through the lift stream feed nozzle at the bottom of the acceleration zone. The lift stream comprises the olefinic C4 hydrocarbon stream with or without steam and/or a fuel gas. The olefinic C4 hydrcarbon steam is cracked in the acceleration zone at 600 to 8000°C and pressure of 0.8 to 5 kg/cm up 2 (gauge) and weight hourly space velocity (WHSV) of 0.2 to 100 hr up 1 and vapour residence time of 0.2 to 5 seconds.

Abstract translation: 用于以增加的产率制造丙烯和乙烯的流化催化裂化（FCC）方法。 该方法包括在FCC单元的一个或多个立管的不同区域中与烯属烃石脑油流和主要烃类物料一起裂化。 每个FCC提升管包括其下部的加速区，加速区底部的升力流进料喷嘴，加速区上方的主烃储料供给喷嘴和沿加速区的位置处的烯烃石脑油进料喷嘴， 升降机进料喷嘴和主油料进料喷嘴。 裂化在含至少2重量百分比的pentasil沸石和至少10重量％Y-沸石的混合FCC催化剂上进行。 在每个FCC提升管的底部注入催化剂，通过烯烃进料喷嘴注入烯烃萘，主要烃类原料通过主要烃类原料进料喷嘴注入，提升流通过提升料流进料喷嘴注入 底部的加速区。 提升流包括具有或不具有蒸汽和/或燃料气体的烯烃C4烃流。 烯烃C4碳氢化合物蒸汽在加速区600〜8000℃，压力0.8〜5kg / cm 2（表压），重时空速（WHSV）为0.2〜100小时-1，蒸汽停留时间 为0.2〜5秒。

公开(公告)号：WO2010067379A2

公开(公告)日：2010-06-17

申请号：PCT/IN2009/000708

申请日：2009-12-08

Applicant: RELIANCE INDUSTRIES LIMITED ,  MANDAL, Sukumar ,  DAS, Asit, Kumar ,  YADAV, Ashwani ,  YADAV, Manoj

Inventor： MANDAL, Sukumar ,  DAS, Asit, Kumar ,  YADAV, Ashwani ,  YADAV, Manoj

CPC classification number: C10G11/18 ,  C10G11/05 ,  C10G2400/20

Abstract: A fluid catalytic cracking (FCC) process for manufacturing propylene and ethylene in increased yield. The process comprises cracking an olefinic naphtha stream and main hydrocarbon stock in combination with an olefinic C 4 hydrocarbon stream in different zones of one or more risers of an FCC unit. Each FCC riser comprises an acceleration zone at the lower portion thereof, a lift stream feed nozzle at the bottom of the acceleration zone, a main hydrocarbon stock feed nozzle above the acceleration zone and an olefinic naphtha feed nozzle at a location along the acceleration zone between the lift stream feed nozzle and main hydrocarbon stock feed nozzle. The cracking is carried out on a mixed FCC catalyst comprising atleast 2 percent by weight pentasil zeolite and at least 10 percent by weight Y- zeolite. The catalyst is injected at the bottom of each FCC riser, the olefinic naptha is injected through the olefinic feed nozzle, the main hydrocarbon stock is injected through the main hydrocarbon stock feed nozzle and the lift stream is injected through the lift stream feed nozzle at the bottom of the acceleration zone. The lift stream comprises the olefinic C 4 hydrocarbon stream with or without steam and/or a fuel gas. The olefinic C 4 hydrcarbon steam is cracked in the acceleration zone at 600 to 8000°C and pressure of 0.8 to 5 kg/cm up 2 (gauge) and weight hourly space velocity (WHSV) of 0.2 to 100 hr up 1 and vapour residence time of 0.2 to 5 seconds.

Abstract translation: 用于以增加的产率制造丙烯和乙烯的流化催化裂化（FCC）方法。 该方法包括在FCC单元的一个或多个提升管的不同区域中裂化烯烃石脑油流和主烃流与烯烃C 4烃流的组合。 每个FCC提升管在其下部包括加速区，加速区底部的提升流进料喷嘴，加速区上方的主烃原料进料喷嘴和位于加速区之间的加速区的位置处的烯烃石脑油进料喷嘴 提升流进料喷嘴和主碳氢化合物原料进料喷嘴。 裂化在包含至少2重量％pentasil沸石和至少10重量％Y-沸石的混合FCC催化剂上进行。 催化剂在每个FCC提升管的底部注入，烯烃石蜡通过烯烃进料喷嘴注入，主烃原料通过主烃原料进料喷嘴注入，提升物流通过提升料流进料喷嘴注入 加速区底部。 提升物流包含具有或不具有蒸汽和/或燃料气体的烯烃C 4烃物流。 烯烃C 4烃蒸汽在加速区在600-8000℃和0.8-5kg / cm 2（表压）和0.2-5的重时空速（WHSV）的压力下裂化。 100小时上升1和蒸气停留时间0.2至5秒。

公开(公告)号：WO2012121764A1

公开(公告)日：2012-09-13

申请号：PCT/US2011/062031

申请日：2011-11-23

Applicant: RATIOPHARM GMBH ,  TEVA PHARMACEUTICALS USA, INC. ,  GIDWANI, Ramesh, Matioram ,  HIREMATH, Channaveerayya ,  YADAV, Manoj, Dalsingar ,  ALBRECHT, Wolfgang ,  FISCHER, Dirk

Inventor： GIDWANI, Ramesh, Matioram ,  HIREMATH, Channaveerayya ,  YADAV, Manoj, Dalsingar ,  ALBRECHT, Wolfgang ,  FISCHER, Dirk

IPC: C07D405/12 ,  A61K31/517 ,  A61P35/00

CPC classification number: C07D405/12

Abstract: Afatinib salts and crystalline forms thereof are described in the present application and processes for their preparation. Crystalline forms of Afatinib are also described in the present application and processes for their preparation. The present invention also includes pharmaceutical compositions of such Afatinib salts and crystalline forms thereof or crystalline forms of Afatinib, methods of their preparation and the use thereof in the treatment of a patient in need thereof.

Abstract translation: 在本申请中描述了阿片碱及其结晶形式及其制备方法。 在本申请中还描述了阿片碱的结晶形式及其制备方法。 本发明还包括这样的阿拉非尼盐及其结晶形式或结晶形式的阿拉金滨的药物组合物，其制备方法及其在治疗有此需要的患者中的用途。

公开(公告)号：WO2012120537A3

公开(公告)日：2012-12-06

申请号：PCT/IN2012000093

申请日：2012-02-10

Applicant: RELIANCE IND LTD ,  MARVE MAHESH ,  SALGARKAR SUYOG ,  MALVANKAR MANTHAN ,  PAREKH AMIT ,  RAYAN VINOD ,  YADAV ASHWANI ,  BISHT HARENDER ,  YADAV MANOJ ,  MANDAL SUKUMAR ,  DAS ASIT

Inventor： MARVE MAHESH ,  SALGARKAR SUYOG ,  MALVANKAR MANTHAN ,  PAREKH AMIT ,  RAYAN VINOD ,  YADAV ASHWANI ,  BISHT HARENDER ,  YADAV MANOJ ,  MANDAL SUKUMAR ,  DAS ASIT

IPC: C10G73/06 ,  C10G21/00

CPC classification number: C10G21/16 ,  C10G21/14 ,  C10G73/10 ,  C10G73/12 ,  C10G2300/1096 ,  C10G2300/44 ,  C10G2400/30

Abstract: A process for producing paraffin extracted clarified slurry oil (raffinate) with improved aromaticity from the feed stock such as clarified slurry oil (CSO) is provided. The obtained paraffin extracted clarified slurry oil with improved aromaticity is suitable for a variety of industrial applications. For example, it can be used as a valuable feedstock for producing carbon black.

Abstract translation: 提供了一种从原料如澄清浆料油（CSO）生产具有改进的芳香性的石蜡提取澄清浆料油（萃余液）的方法。 所得石蜡提取澄清浆料油具有改善的芳香度，适用于各种工业应用。 例如，它可以用作生产炭黑的有价值的原料。

公开(公告)号：WO2011001445A2

公开(公告)日：2011-01-06

申请号：PCT/IN2010/000386

申请日：2010-06-09

Applicant: RELIANCE INDUSTRIES LIMITED ,  YADAV, Manoj ,  MANDAL, Sukumar ,  DAS, Asit Kumar ,  GUPTA, Yogesh ,  MAKHANIA, Minaz ,  TULSI, Gobind ,  ARORA, Shailendra ,  JAGUSTE, Shubhangi

Inventor： YADAV, Manoj ,  MANDAL, Sukumar ,  DAS, Asit Kumar ,  GUPTA, Yogesh ,  MAKHANIA, Minaz ,  TULSI, Gobind ,  ARORA, Shailendra ,  JAGUSTE, Shubhangi

IPC: C10G53/08

CPC classification number: C10G53/08 ,  C10G5/04 ,  C10G5/06 ,  C10G7/02 ,  C10G11/18 ,  C10G31/06 ,  C10G55/06 ,  C10G70/06 ,  C10G2300/301 ,  C10G2400/20 ,  C10G2400/26 ,  C10G2400/28

Abstract: A process is disclosed for enhanced recovery of propylene and LPG from the fuel gas produced in Fluid catalytic cracking unit by contacting a heavier hydrocarbon feed with FCC catalyst. In the conventional process, the product mixture from FCC main column overhead comprising naphtha, LPG and fuel gas, are first condensed and gravity separated to produce unstabilized naphtha, which is subsequently used in the absorber to absorb propylene and LPG from fuel gas. However, the recovery of propylene beyond 97 wt% is difficult in this process since unstabilized naphtha already contains propylene of 5 mol% or above. In the present invention, C 4 and lighter components from unstabilized naphtha are first stripped off in a separate column to obtain a liquid fraction almost free from propylene (

Abstract translation: 公开了一种通过使较重烃进料与FCC催化剂接触，从流化床催化裂化装置产生的燃料气体中提高丙烯和LPG回收率的方法。 在常规方法中，首先将包含石脑油，液化石油气和燃料气体的FCC主塔架塔的产物混合物冷凝并重力分离以产生不稳定的石脑油，随后在吸收器中使用该燃料从燃料气体中吸收丙烯和LPG。 然而，在该方法中，丙烯的回收率超过97wt％是困难的，因为未稳定的石脑油已经含有5mol％或更高的丙烯。 在本发明中，C4和来自不稳定石脑油的较轻组分首先在单独的塔中汽提，得到几乎不含丙烯（<0.1mol％）和其它LPG组分的液体组分。 在吸收器中使用这种汽提的液体馏分，在冷却至20℃至30℃后，从燃料气体中吸收较高量的丙烯和LPG，导致丙烯的回收率提高。

公开(公告)号：WO2013121433A1

公开(公告)日：2013-08-22

申请号：PCT/IN2012/000289

申请日：2012-04-20

Applicant: RELIANCE INDUSTRIES LTD., ,  MANDAL, Sukumar ,  YADAV, Manoj ,  PAREKH, Amitkumar ,  DAS, Asit Kumar ,  JAGUSTE, Shubhangi ,  CHINTHALA, Praveen Kumar ,  RAVICHANDRAN, Gopal ,  MARVE, Mahesh ,  SAPRE, Ajit

Inventor： MANDAL, Sukumar ,  YADAV, Manoj ,  PAREKH, Amitkumar ,  DAS, Asit Kumar ,  JAGUSTE, Shubhangi ,  CHINTHALA, Praveen Kumar ,  MARVE, Mahesh ,  SAPRE, Ajit

IPC: C10G11/18 ,  B01J8/08 ,  B01J8/26 ,  C07C1/20

CPC classification number: C07C4/06 ,  B01J29/084 ,  B01J29/40 ,  B01J29/80 ,  B01J29/90 ,  B01J38/30 ,  C07C2529/06 ,  C07C2529/40 ,  C10G11/18 ,  C10G11/182 ,  C10G11/185

Abstract: A process for catalytic conversion of low value hydrocarbon streams to light olefins in comparatively higher yields is disclosed. Propylene is obtained in amounts higher than 20 wt. % and ethylene higher than 6 wt. %. The process is carried out in a preheated cracking reactor having a single riser and circulating an FCC catalyst. The riser is divided into three temperature zones in which different hydrocarbon feeds are introduced. An oxygenate feed is introduced in the operative top zone in the riser. Heat for the endothermic cracking is obtained by the exothermic reaction of converting the oxygenate feed into gas and / or from a regenerator in which the spent FCC catalyst is burnt.

Abstract translation: 公开了以较低产率将低价值烃流催化转化成轻质烯烃的方法。 获得的丙烯的量高于20wt。 ％和乙烯高于6wt。 ％。 该方法在具有单个提升管并循环FCC催化剂的预热的裂解反应器中进行。 提升管分为三个温度区，其中引入不同的烃进料。 含氧化合物进料引入提升管中的操作顶部区域。 通过将含氧化合物进料转化为气体和/或从废FCC催化剂燃烧的再生器的放热反应获得吸热裂纹的热。

公开(公告)号：WO2010067379A8

公开(公告)日：2010-09-10

申请号：PCT/IN2009000708

申请日：2009-12-08

Applicant: RELIANCE IND LTD ,  MANDAL SUKUMAR ,  DAS ASIT KUMAR ,  YADAV ASHWANI ,  YADAV MANOJ ,  BHATNAGAR AKHILESH ,  DONGARA RAJESHWAR ,  KATRAVULAPALLI VEERA VENKATA SATYA BHASKARA SITA R

Inventor： MANDAL SUKUMAR ,  DAS ASIT KUMAR ,  YADAV ASHWANI ,  YADAV MANOJ ,  BHATNAGAR AKHILESH ,  DONGARA RAJESHWAR ,  KATRAVULAPALLI VEERA VENKATA SATYA BHASKARA SITA R

CPC classification number: C10G11/18 ,  C10G11/05 ,  C10G2400/20

Abstract: A fluid catalytic cracking (FCC) process for manufacturing propylene and ethylene in increased yield. The process comprises cracking an olefinic naphtha stream and main hydrocarbon stock in combination with an olefinic C4 hydrocarbon stream in different zones of one or more risers of an FCC unit. Each FCC riser comprises an acceleration zone at the lower portion thereof, a lift stream feed nozzle at the bottom of the acceleration zone, a main hydrocarbon stock feed nozzle above the acceleration zone and an olefinic naphtha feed nozzle at a location along the acceleration zone between the lift stream feed nozzle and main hydrocarbon stock feed nozzle. The cracking is carried out on a mixed FCC catalyst comprising atleast 2 percent by weight pentasil zeolite and at least 10 percent by weight Y- zeolite. The catalyst is injected at the bottom of each FCC riser, the olefinic naptha is injected through the olefinic feed nozzle, the main hydrocarbon stock is injected through the main hydrocarbon stock feed nozzle and the lift stream is injected through the lift stream feed nozzle at the bottom of the acceleration zone. The lift stream comprises the olefinic C4 hydrocarbon stream with or without steam and/or a fuel gas. The olefinic C4 hydrcarbon steam is cracked in the acceleration zone at 600 to 8000°C and pressure of 0.8 to 5 kg/cm up 2 (gauge) and weight hourly space velocity (WHSV) of 0.2 to 100 hr up 1 and vapour residence time of 0.2 to 5 seconds.

Abstract translation: 用于以增加的产率制造丙烯和乙烯的流化催化裂化（FCC）方法。 该方法包括在FCC单元的一个或多个立管的不同区域中与烯属烃石脑油流和主要烃类物料一起裂化。 每个FCC提升管包括其下部的加速区，加速区底部的升力流进料喷嘴，加速区上方的主烃储料供给喷嘴和沿加速区的位置处的烯烃石脑油进料喷嘴， 升降机进料喷嘴和主油料进料喷嘴。 裂化在含至少2重量百分比的pentasil沸石和至少10重量％Y-沸石的混合FCC催化剂上进行。 在每个FCC提升管的底部注入催化剂，通过烯烃进料喷嘴注入烯烃萘，主要烃类原料通过主要烃类原料进料喷嘴注入，提升流通过提升料流进料喷嘴注入 底部的加速区。 提升流包括具有或不具有蒸汽和/或燃料气体的烯烃C4烃流。 烯烃C4碳氢化合物蒸汽在加速区600〜8000℃，压力0.8〜5kg / cm 2（表压），重时空速（WHSV）0.2〜100小时-1，蒸气停留时间 为0.2〜5秒。

公开(公告)号：WO2013121433A8

公开(公告)日：2013-10-31

申请号：PCT/IN2012000289

申请日：2012-04-20

Applicant: RELIANCE IND LTD ,  MANDAL SUKUMAR ,  YADAV MANOJ ,  PAREKH AMITKUMAR ,  DAS ASIT KUMAR ,  JAGUSTE SHUBHANGI ,  CHINTHALA PRAVEEN KUMAR ,  RAVICHANDRAN GOPAL ,  MARVE MAHESH ,  SAPRE AJIT

Inventor： MANDAL SUKUMAR ,  YADAV MANOJ ,  PAREKH AMITKUMAR ,  DAS ASIT KUMAR ,  JAGUSTE SHUBHANGI ,  CHINTHALA PRAVEEN KUMAR ,  RAVICHANDRAN GOPAL ,  MARVE MAHESH ,  SAPRE AJIT

IPC: C10G11/18 ,  B01J8/08 ,  B01J8/26 ,  C07C1/20

CPC classification number: C07C4/06 ,  B01J29/084 ,  B01J29/40 ,  B01J29/80 ,  B01J29/90 ,  B01J38/30 ,  C07C2529/06 ,  C07C2529/40 ,  C10G11/18 ,  C10G11/182 ,  C10G11/185

Abstract: A process for catalytic conversion of low value hydrocarbon streams to light olefins in comparatively higher yields is disclosed. Propylene is obtained in amounts higher than 20 wt. % and ethylene higher than 6 wt. %. The process is carried out in a preheated cracking reactor having a single riser and circulating an FCC catalyst. The riser is divided into three temperature zones in which different hydrocarbon feeds are introduced. An oxygenate feed is introduced in the operative top zone in the riser. Heat for the endothermic cracking is obtained by the exothermic reaction of converting the oxygenate feed into gas and / or from a regenerator in which the spent FCC catalyst is burnt.

Abstract translation: 公开了以相对较高的产率将低价值烃流催化转化为轻质烯烃的方法。 丙烯的获得量高于20wt。 ％和乙烯高于6wt。 ％。 该方法在具有单个提升管并循环FCC催化剂的预热裂化反应器中进行。 立管分为三个温度区，其中引入不同的烃进料。 含氧化合物进料在立管的有效顶部区域引入。 用于吸热裂化的热量通过将含氧化合物进料转化成气体和/或从废催化剂催化剂在其中燃烧的再生器中的放热反应获得。

公开(公告)号：WO2012120537A2

公开(公告)日：2012-09-13

申请号：PCT/IN2012/000093

申请日：2012-02-10

Applicant: RELIANCE INDUSTRIES LTD. ,  MARVE, Mahesh ,  SALGARKAR, Suyog ,  MALVANKAR, Manthan ,  PAREKH, Amit ,  RAYAN, Vinod ,  YADAV, Ashwani ,  BISHT, Harender ,  YADAV, Manoj ,  MANDAL, Sukumar ,  DAS, Asit

Inventor： MARVE, Mahesh ,  SALGARKAR, Suyog ,  MALVANKAR, Manthan ,  PAREKH, Amit ,  RAYAN, Vinod ,  YADAV, Ashwani ,  BISHT, Harender ,  YADAV, Manoj ,  MANDAL, Sukumar ,  DAS, Asit

CPC classification number: C10G21/16 ,  C10G21/14 ,  C10G73/10 ,  C10G73/12 ,  C10G2300/1096 ,  C10G2300/44 ,  C10G2400/30

Abstract: The present disclosure provides a process for producing paraffin extracted clarified slurry oil (raffinate) with improved aromaticity from the feed stock such as clarified slurry oil(CSO). The obtained paraffin extracted clarified slurry oil with improved aromaticity is suitable for a variety of industrial applications such as it can be used as a valuable feedstock for producing carbon black.

Abstract translation: 本公开内容提供了一种从原料例如澄清的浆液油（CSO）生产具有改进的芳香度的石蜡提取的澄清浆料油（萃余液）的方法。 所得石蜡提取澄清浆料油具有改善的芳香度，适用于各种工业应用，如可用作生产炭黑的有价值的原料。

公开(公告)号：WO2011001445A3

公开(公告)日：2011-03-31

申请号：PCT/IN2010000386

申请日：2010-06-09

Applicant: RELIANCE IND LTD ,  YADAV MANOJ ,  MANDAL SUKUMAR ,  DAS ASIT KUMAR ,  GUPTA YOGESH ,  MAKHANIA MINAZ ,  TULSI GOBIND ,  ARORA SHAILENDRA ,  JAGUSTE SHUBHANGI

Inventor： YADAV MANOJ ,  MANDAL SUKUMAR ,  DAS ASIT KUMAR ,  GUPTA YOGESH ,  MAKHANIA MINAZ ,  TULSI GOBIND ,  ARORA SHAILENDRA ,  JAGUSTE SHUBHANGI

IPC: C10G53/08

CPC classification number: C10G53/08 ,  C10G5/04 ,  C10G5/06 ,  C10G7/02 ,  C10G11/18 ,  C10G31/06 ,  C10G55/06 ,  C10G70/06 ,  C10G2300/301 ,  C10G2400/20 ,  C10G2400/26 ,  C10G2400/28

Abstract: A process is disclosed for enhanced recovery of propylene and LPG from the fuel gas produced in Fluid catalytic cracking unit by contacting a heavier hydrocarbon feed with FCC catalyst. In the conventional process, the product mixture from FCC main column overhead comprising naphtha, LPG and fuel gas, are first condensed and gravity separated to produce unstabilized naphtha, which is subsequently used in the absorber to absorb propylene and LPG from fuel gas. However, the recovery of propylene beyond 97 wt% is difficult in this process since unstabilized naphtha already contains propylene of 5 mol% or above. In the present invention, C4 and lighter components from unstabilized naphtha are first stripped off in a separate column to obtain a liquid fraction almost free from propylene (

Abstract translation: 公开了一种用于通过使重烃进料与FCC催化剂接触而增强从流化床催化裂化装置中产生的燃气中回收丙烯和LPG的方法。 在常规方法中，来自FCC主塔顶馏出物（包含石脑油，LPG和燃料气）的产物混合物首先冷凝并且重力分离以产生未稳定的石脑油，其随后用于吸收器中以吸收来自燃料气体的丙烯和LPG。 然而，由于不稳定石脑油已经含有5mol％或更高的丙烯，所以在该方法中难以回收超过97wt％的丙烯。 在本发明中，来自未稳定石脑油的C4和较轻组分首先在单独的塔中汽提以获得几乎不含丙烯（<0.1mol％）和其他LPG组分的液体馏分。 在冷却到20℃至30℃之后，将这种汽提的液体馏分用于吸收器中以从燃料气体中吸收更多量的丙烯和LPG，从而改善丙烯的回收率。