公开(公告)号：WO2022074562A1

公开(公告)日：2022-04-14

申请号：PCT/IB2021/059130

申请日：2021-10-05

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： LIN, Sung-Tso ,  LIU, Ching-Yi ,  LU, Ying-Yuh ,  SU, Wei-Cheng

IPC: C09J133/06 ,  C09J133/08 ,  C09J7/38 ,  C08L33/24

Abstract: The present application is a composition including a base resin comprising between about 4% and about 15% acrylic acid monomer and an oligomer additive comprising (a) one of an acrylamide or meth(acrylamide) copolymer and (b) a high glass transition temperature monomer. The oligomer additive has a molecular weight range of between about 20,000 and about 1,000,000 and a glass transition temperature of between about 70°C and about 115°C. The composition has a blending ratio of base resin to oligomer additive of between about 7 to about 30 parts per hundred of resin.

公开(公告)号：WO2009085740A3

公开(公告)日：2009-07-09

申请号：PCT/US2008/086951

申请日：2008-12-16

Applicant: 3M INNOVATIVE PROPERTIES COMPANY ,  KUMAR, Ramesh, C. ,  MCKENZIE, Taun, L. ,  LU, Ying-Yuh

Inventor： KUMAR, Ramesh, C. ,  MCKENZIE, Taun, L. ,  LU, Ying-Yuh

IPC: C08F292/00 ,  C08J5/02 ,  C08L33/04 ,  C08L57/00

Abstract: A copolymer comprises the reaction product of (a) (meth)acrylate functionalized nanoparticles, (b) vinyl monomer, and (c) mercapto-functional silicone. The (meth)acrylate functionalize nanoparticles are selected from the group consisting of silica nanoparticles, zirconia nanoparticles, titania nanoparticles, and combinations thereof.

公开(公告)号：WO2009079582A1

公开(公告)日：2009-06-25

申请号：PCT/US2008/087232

申请日：2008-12-17

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： LU, Ying-Yuh ,  ANDERSON, Kelly, S.

IPC: C09J191/00

CPC classification number: C09J133/08 ,  C08F2220/1858 ,  C08G2170/40 ,  Y10T428/28 ,  Y10T428/2804 ,  Y10T428/2839 ,  Y10T428/2861 ,  Y10T442/2754 ,  C08F2220/281 ,  C08F2220/286 ,  C08F226/08

Abstract: The present invention provides an adhesive made from a reaction product of: (a) a polymerizable monomer derived at least in part from non-petroleum resources; (b) an initiator; (c) a polymeric stabilizer, wherein the reaction occurs in water to yield a microsphere adhesive. The microsphere adhesive can be formulated into a pressure sensitive adhesive composition that can be applied to various substrates such as paper and polymeric film to produce repositionable adhesive coated articles such as tapes, notes, flags, easels and the like.

Abstract translation: 本发明提供一种由以下反应产物制成的粘合剂：（a）至少部分来自非石油资源的可聚合单体; （b）引发剂; （c）聚合物稳定剂，其中反应发生在水中以产生微球粘合剂。 可以将微球粘合剂配制成压敏粘合剂组合物，其可以施加到各种基材如纸和聚合物膜上以产生可重新定位的粘合剂涂覆的制品，例如带，笔记，旗帜，画架等。

公开(公告)号：WO2007102977A1

公开(公告)日：2007-09-13

申请号：PCT/US2007/004026

申请日：2007-02-16

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： LEWANDOWSKI, Kevin, M. ,  FILIATRAULT, Timothy, B. ,  ANDERSON, Kelly, S. ,  GADDAM, Babu, N. ,  JOSEPH, Eugene, G. ,  LU, Ying-Yuh

IPC: C09J133/10

CPC classification number: C09J133/08 ,  C09J2201/606

Abstract: An adhesive composition comprising an emulsion polymer which comprises a (meth)acrylate copolymer and silica nanoparticles is described. The addition of the nanoparticles results in a significant increase in the overlap shear properties of the adhesive while maintaining the peel adhesion.

Abstract translation: 描述了包含包含（甲基）丙烯酸酯共聚物和二氧化硅纳米颗粒的乳液聚合物的粘合剂组合物。 纳米颗粒的添加导致粘合剂的重叠剪切性能显着增加，同时保持剥离粘合力。

公开(公告)号：WO2004094549A1

公开(公告)日：2004-11-04

申请号：PCT/US2004/007945

申请日：2004-03-12

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： XIA, Jianhui ,  LU, Ying-Yuh ,  ZHOU, Zhiming

IPC: C09J7/00

CPC classification number: B32B27/08 ,  B32B7/12 ,  B32B27/308 ,  B32B27/365 ,  B32B2307/7246 ,  B32B2551/00 ,  C08L2666/04 ,  C09J7/10 ,  C09J7/35 ,  C09J133/06 ,  C09J201/02 ,  C09J2433/00 ,  Y10T428/2804 ,  Y10T428/2848 ,  Y10T428/2891 ,  Y10T428/31507 ,  Y10T428/31855 ,  Y10T428/31909 ,  Y10T428/31938

Abstract: Described are adhesive compositions containing a mixture of a pressure sensitive adhesive, a high Tg polymer, and a crosslinker to form a compatibilized blend that is optically clear. Methods of using the adhesive compositions, and multilayer assemblies such as optical elements prepared using the adhesives, are also provided.

Abstract translation: 描述了含有压敏粘合剂，高Tg聚合物和交联剂的混合物的粘合剂组合物，以形成光学透明的相容的共混物。 还提供了使用粘合剂组合物的方法和使用粘合剂制备的多层组件如光学元件。

公开(公告)号：WO2011119326A3

公开(公告)日：2011-09-29

申请号：PCT/US2011/027552

申请日：2011-03-08

Applicant: 3M INNOVATIVE PROPERTIES COMPANY ,  AUSEN, Ronald, W. ,  KOPECKY, William, J. ,  CASTIGLIONE, Stephanie, B. ,  LU, Ying-Yuh

Inventor： AUSEN, Ronald, W. ,  KOPECKY, William, J. ,  CASTIGLIONE, Stephanie, B. ,  LU, Ying-Yuh

IPC: B32B3/22 ,  G02B5/00 ,  B29C47/30 ,  C08J5/18 ,  B42F7/00

Abstract: Composite layer comprising a plurality of longitudinal, generally parallel first zones comprised of a first polymeric material each encapsulated in a second polymeric material. There are at least 10 longitudinal first zones per cm.

公开(公告)号：WO2010075387A2

公开(公告)日：2010-07-01

申请号：PCT/US2009/069200

申请日：2009-12-22

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： LU, Ying-Yuh ,  ANDERSON, Kelly S.

IPC: C09J133/04 ,  C09J7/00 ,  C09J11/06

CPC classification number: C09J133/08 ,  C09J4/06 ,  C09J7/385 ,  C09J133/066 ,  C09J139/06 ,  C09J2201/606 ,  Y10T428/2804 ,  Y10T428/2848 ,  Y10T428/2891 ,  Y10T442/2754

Abstract: The present disclosure provides an adhesive made from a reaction product of: (a) one or more polymerizable monomer selected from the group consisting of n-C 6 to n-C 14 (meth)acrylates derived at least in part from non-petroleum resources; (b) an initiator; (c) a polymeric stabilizer, wherein the reaction occurs in water to yield a microsphere adhesive. The microsphere adhesive can be formulated into a pressure sensitive adhesive composition that can be applied to various substrates such as paper and polymeric film to produce repositionable adhesive coated articles such as tapes, notes, flags, easels, and the like.

Abstract translation: 本公开内容提供了由以下反应产物制成的粘合剂：（a）至少部分由非石油资源衍生的一种或多种选自由n-C 6至n-C 14（甲基）丙烯酸酯组成的组的可聚合单体; （b）引发剂; （c）聚合物稳定剂，其中反应发生在水中以产生微球粘合剂。 微球粘合剂可以配制成压敏粘合剂组合物，其可以施加到诸如纸和聚合物膜的各种基材上以产生可重新定位的粘合剂涂覆的制品，例如带，笔记，旗帜，画架等。

公开(公告)号：WO2007094979A1

公开(公告)日：2007-08-23

申请号：PCT/US2007/002950

申请日：2007-02-02

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： DUNCAN, John E. ,  O'KEEFE, Michael W. ,  AUERBACH, Roy A. ,  OLOFSON, Peter M. ,  BOYER, Christopher R. ,  LU, Ying-Yuh ,  XIA, Jianhui

IPC: C08J5/12 ,  G02B5/00 ,  G02B6/00

CPC classification number: G02B27/283 ,  C08F265/04 ,  C08F289/00 ,  C08F290/06 ,  G02B1/04 ,  C08L51/08

Abstract: A curable composition is provided comprising an oligomer having a plurality of pendent and/or terminal ethylenically unsaturated, free-radically polymerizable functional groups, a free-radically polymerizable crosslinking agent, and/or a diluent monomer, and a photoinitiator. The composition, when cured, is non-yellowing, exhibits low shrinkage and low birefringence making it suitable for many optical applications such as optical lenses, optical fibers, prisms, light guides, optical adhesives, and optical films.

Abstract translation: 提供了一种可固化组合物，其包含具有多个侧链和/或末端烯键式不饱和，可自由基聚合的官能团，可自由基聚合的交联剂和/或稀释剂单体和光引发剂的低聚物。 当固化时，组合物不变黄，显示低收缩率和低双折射，使其适用于许多光学应用，例如光学透镜，光纤，棱镜，光导，光学粘合剂和光学膜。

公开(公告)号：WO2015095118A1

公开(公告)日：2015-06-25

申请号：PCT/US2014/070486

申请日：2014-12-16

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： JUNE, Stephen M. ,  MOROZOWICH, Nicole L. ,  LU, Ying-Yuh

IPC: C09J201/02 ,  C09J9/00 ,  C09J133/06

CPC classification number: C09J133/06 ,  C08F220/10 ,  C08L33/06 ,  C09J9/005 ,  C09J201/02

Abstract: A solid thermoplastic semi-crystalline friction-activated adhesive composition comprising the mixture of: (a) from about 50 to about 100 parts by weight of a semi-crystalline adhesive polymer that comprises: (1) crystalline monomer having an alkyl carbon length of at least 16 carbon atoms; (2) non-crystalline monomer having a homopolymer T g below about 80°C; (3) waxy, soft monomer having an average pendant alkyl carbon length of at least 14 carbon atoms; (4) monomer having acid or base functionality; (5) functional or non-functional macromere having a T m from about 40 to about 120°C; (b) 0 to about 50 parts by weight of tackifier; (c) 0 to about 50 parts by weight of crystalline additive; (d) 0 to about 50 parts by weight of filler; (e) 0 to about 30 parts by weight of oil; and (f) 0 to about 50 parts by weight of one surfactant. Also glue crayons and other application devices comprising such adhesive compositions.

Abstract translation: 一种固体热塑性半结晶摩擦活化粘合剂组合物，其包含以下混合物：（a）约50至约100重量份的半结晶粘合剂聚合物，其包含：（1）具有烷基碳长度为 至少16个碳原子; （2）均聚物Tg低于约80℃的非晶体单体; （3）具有至少14个碳原子的平均侧链烷基碳长度的蜡状软质单体; （4）具有酸或碱官能度的单体; （5）具有约40至约120℃的Tm的功能或非功能大分子单体; （b）0至约50重量份的增粘剂; （c）0至约50重量份的结晶添加剂; （d）0至约50重量份的填料; （e）0至约30重量份的油; 和（f）0至约50重量份的一种表面活性剂。 另外粘合蜡笔和包括这种粘合剂组合物的其它应用装置。

公开(公告)号：WO2011119324A2

公开(公告)日：2011-09-29

申请号：PCT/US2011/027546

申请日：2011-03-08

Applicant: 3M INNOVATIVE PROPERTIES COMPANY ,  AUSEN, Ronald, W. ,  KOPECKY, William, J. ,  CASTIGLIONE, Stephanie, B. ,  LU, Ying-Yuh

Inventor： AUSEN, Ronald, W. ,  KOPECKY, William, J. ,  CASTIGLIONE, Stephanie, B. ,  LU, Ying-Yuh

IPC: B32B3/12 ,  B32B7/02

CPC classification number: B32B7/02 ,  B29C47/0021 ,  B29C47/065 ,  B29C47/0828 ,  B29C47/145 ,  B29C47/16 ,  B29C47/86 ,  B29C47/862 ,  B29C47/866 ,  B29L2007/008 ,  B32B7/12 ,  B32B27/08 ,  B42F7/00 ,  B42F13/0013 ,  C08J5/18 ,  C09J7/00 ,  C09J7/40 ,  Y10T428/24612 ,  Y10T428/24802 ,  Y10T428/24826 ,  Y10T428/24942 ,  Y10T428/28 ,  Y10T428/2852

Abstract: Composite layer comprising a plurality of longitudinal first zones comprised of a first polymeric material alternating with a plurality of longitudinal second zones comprised of a second polymeric material such that one first zone is disposed between two adjacent second zones. The zones are generally parallel to one another, and at least one of each first zone or each second zone has a maximum width dimension of not greater than 2 mm. Adjacent first and second zones have an average pitch, wherein for the composite layer there is an average of said average pitches, and wherein the average pitch for any adjacent first and second zones is within 20 percent of the average pitch for adjacent first and second zones of said average of said average pitches.

Abstract translation: 复合层包括由第一聚合材料组成的多个纵向第一区域，所述第一聚合物材料与由第二聚合物材料组成的多个纵向第二区域交替，使得一个第一区域设置在两个相邻的第二区域之间。 这些区域通常彼此平行，并且每个第一区域或每个第二区域中的至少一个具有不大于2mm的最大宽度尺寸。 相邻的第一和第二区域具有平均间距，其中对于复合层，平均具有所述平均间距，并且其中相邻的第一和第二区域的平均间距在相邻的第一和第二区域的平均间距的20％以内 所述平均间距的平均值。