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公开(公告)号:WO2009130233A1
公开(公告)日:2009-10-29
申请号:PCT/EP2009/054785
申请日:2009-04-22
Applicant: BASF SE , HÖLZL, Werner , BRAUN, Holger , WALLQUIST, Olof
Inventor: HÖLZL, Werner , BRAUN, Holger , WALLQUIST, Olof
IPC: C08J7/16
CPC classification number: C08J7/16 , C08F293/005 , C08F2438/01 , C08J2327/06
Abstract: Disclosed is a method of preparing a modified halogenated polymer surface, comprising the steps of (a) activating the surface by modification with a polymerisation initiator by (a 1 ) reacting the halogenated polymer surface with sodium azide and subsequent (a 2 ) 1,3 dipolar cycloaddition with an alkine-functionalized initiator; or (a 3 ) reacting the halogenated polymer surface with mercapto-functionalized initiators; and (b) reacting the activated surface obtained in steps (a 1 )/(a 2 ) or (a 3 ) with polymerizable monomeric units A and/or B. The modified halogenated polymer substrates according to the invention exhibit outstanding properties.
Abstract translation: 公开了一种制备改性卤化聚合物表面的方法,其包括以下步骤:(a)通过(a1)使卤化聚合物表面与叠氮化钠和随后的(a2)1,3偶极环加成反应,通过用聚合引发剂进行改性来活化表面 用烷基官能化引发剂; 或(a3)使卤代聚合物表面与巯基官能化的引发剂反应; 和(b)使步骤(a1)/(a2)或(a3)中获得的活化表面与可聚合单体单元A和/或B反应。本发明的改性卤化聚合物基材具有突出的性能。
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公开(公告)号:WO2010054979A1
公开(公告)日:2010-05-20
申请号:PCT/EP2009/064695
申请日:2009-11-05
Applicant: BASF SE , HÖLZL, Werner , BRAUN, Holger
Inventor: HÖLZL, Werner , BRAUN, Holger
CPC classification number: G03F7/012 , C08F293/005 , C08F2438/01 , G03F7/265 , Y10T428/24479
Abstract: Disclosed is a method of preparing a modified halogenated polymer surface, comprising the steps of (a) activating the surface by modification with a polymerisation initiator by (a 1 ) reacting the halogenated polymer surface with sodium azide, subsequent (a 2 ) patterning the azidated surface via photolithographic patterning methods, and subsequent (a 3 ) 1, 3 dipolar cycloaddition with an alkine-functionalized initiator; and (b) reacting the activated surface obtained in steps (a 1 )-(a 3 ) with polymerizable monomeric units A and/or B.
Abstract translation: 公开了一种制备改性卤化聚合物表面的方法,其包括以下步骤:(a)通过(a1)使卤化聚合物表面与叠氮化钠反应,通过用聚合引发剂进行改性来活化表面,随后(a2)将叠氮化表面经过 光刻图案化方法,以及随后(a3)1,3与亚烷基官能化引发剂的偶极环加成反应; 和(b)使步骤(a1) - (a3)中获得的活化表面与可聚合单体单元A和/或B反应。
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公开(公告)号:WO2006015959A2
公开(公告)日:2006-02-16
申请号:PCT/EP2005/053780
申请日:2005-08-03
Applicant: CIBA SPECIALTY CHEMICALS HOLDING INC. , HÖLZL, Werner , PREUSS, Andrea , WALLQUIST, Olof
Inventor: HÖLZL, Werner , PREUSS, Andrea , WALLQUIST, Olof
IPC: A61K8/49
CPC classification number: A61K8/41 , A01N61/00 , A61K8/40 , A61K8/46 , A61K8/466 , A61K8/49 , A61K8/4926 , A61K8/494 , A61K8/4966 , A61K8/498 , A61Q11/00 , A61Q11/02 , C11D3/42 , C11D3/48 , D21H21/36
Abstract: Use of fluorescent whitening agents for whitening and the antimicrobial treatment of surfaces, and preservation of cosmetics, household products, personal care products, textiles, paper and starting materials of paper, plastics and disinfectants.
Abstract translation: 使用荧光增白剂进行美白和表面的抗微生物处理,以及化妆品,家用产品,个人护理产品,纺织品,纸张和纸张,塑料和消毒剂原料的保存。
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公开(公告)号:WO2011023573A1
公开(公告)日:2011-03-03
申请号:PCT/EP2010/061804
申请日:2010-08-13
Applicant: BASF SE , HÖLZL, Werner , PURSCHWITZ, Janina
Inventor: HÖLZL, Werner , PURSCHWITZ, Janina
IPC: A61K31/167 , A61P31/00 , A61K8/44 , A61Q5/02 , A61Q11/02 , A61Q15/00 , A61Q19/00 , A61Q17/00 , C11D3/00 , C11D3/32
CPC classification number: C11D3/48 , A61K8/42 , A61Q5/02 , A61Q11/02 , A61Q15/00 , A61Q17/005 , C11D3/32
Abstract: Disclosed is a novel method for achieving an antimicrobial, preservative and/or microorganism adhesion inhibiting effect, for the protection within an article and/or material or on the surface of an article and/or material. The novel method comprises application of a salicylic compound of the formula (I) wherein one of A and A is a residue of the formula (I'): -NH-CO-R 1 while the other is hydrogen; R 1 is C 1 -C 22 alkyl, C 3 -C 12 cycloalkyl, C 3 -C 12 cycloalkyl interrupted by O and/or NR 5 , C 4 -C 12 aryl, C 5 -C 18 arylalkyl; R 2 is OR 3 or NHR 4 ; R 3 and R 4 are selected from H, C 1 -C 22 alkyl, C 3 -C 12 cycloalkyl, C 3 -C 12 cycloalkyl interrupted by O and/or NR 5 , C 4 -C 12 aryl, C 5 -C 18 arylalkyl; R 5 is H or C 1 -C 8 alkyl; wherein each aryl moiety is unsubstituted or substituted by C 1 -C 4 alkyl, C 1 -C 4 alkoxy, C 1 -C 4 acyl, C 1 -C 4 acyloxy, C 1 -C 4 acylamino, CF 3 , OH, amino, halogen; or an adduct or salt thereof; to said article and/or material.
Abstract translation: 公开了一种用于实现在制品和/或材料内或制品和/或材料的表面上的保护的抗微生物,防腐和/或微生物粘附抑制作用的新方法。 该新方法包括施用式(I)的水杨酸化合物,其中A和A之一是式(I')的残基:-NH-CO-R 1,而另一个是氢; R1是C1-C22烷基,C3-C12环烷基,被O和/或NR5,C4-C12芳基,C5-C18芳烷基中断的C3-C12环烷基; R2是OR3或NHR4; R 3和R 4选自H,C 1 -C 22烷基,C 3 -C 12环烷基,被O和/或NR 5,C 4 -C 12芳基,C 5 -C 18芳烷基间隔的C 3 -C 12环烷基; R5是H或C1-C8烷基; 其中每个芳基部分是未取代的或被C 1 -C 4烷基,C 1 -C 4烷氧基,C 1 -C 4酰基,C 1 -C 4酰氧基,C 1 -C 4酰氨基,CF 3,OH,氨基,卤素取代。 或其加合物或其盐; 对所述物品和/或材料。
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5.
公开(公告)号:WO2009138341A2
公开(公告)日:2009-11-19
申请号:PCT/EP2009/055453
申请日:2009-05-06
Applicant: BASF SE , ELDER, Stewart, Todd , KHAWAM, Fadi , HUANG, Xinyu , HÖLZL, Werner
Inventor: ELDER, Stewart, Todd , KHAWAM, Fadi , HUANG, Xinyu , HÖLZL, Werner
CPC classification number: A01N37/36 , A01N37/44 , C07C229/12
Abstract: Anti-microbial compositions are provided which comprise as an antimicrobial agent at least one compound derived from a select polyol containing at least 3 hydroxy groups wherein one or more, and often two or more, of the hydroxyls are derivitized to form certain ether, ester, carbonate or carbamate groups which groups may bear additional functionality. Novel antimicrobial compounds of this class are also provided. The compositions are effective against a variety of pathogens including fungi, Gram positive bacteria and Gram negative bacteria and are expected to have low human toxicity. Applications for the polyglycerol antimicrobial agents and compositions include those involving human and plant contact, such as cosmetics, hair care products, textiles and plant protections, as well as in applications with much less human contact, such as plastics, coatings, wood, paper and other materials of construction.
Abstract translation: 提供了抗微生物组合物,其包含至少一种衍生自含有至少3个羟基的选择多元醇的化合物作为抗微生物剂,其中一个或多个,并且通常两个或更多个羟基被衍生以形成某些醚,酯, 碳酸酯或氨基甲酸酯基,这些基团可以具有附加的功能。 还提供了这一类的新型抗菌化合物。 该组合物对各种病原体有效,包括真菌,革兰氏阳性菌和革兰氏阴性细菌,预计人体毒性低。 聚甘油抗微生物剂和组合物的应用包括涉及人和植物接触的那些,例如化妆品,护发产品,纺织品和植物保护,以及在人类接触少得多的应用中,例如塑料,涂料,木材,纸和 其他施工材料。
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公开(公告)号:WO2007009879A1
公开(公告)日:2007-01-25
申请号:PCT/EP2006/063896
申请日:2006-07-05
Applicant: CIBA SPECIALTY CHEMICALS HOLDING INC. , HÖLZL, Werner , PREUSS, Andrea
Inventor: HÖLZL, Werner , PREUSS, Andrea
CPC classification number: A61Q17/005 , A61K8/347 , A61K2800/524
Abstract: The present invention relates to the use of compounds of the formula (1 ) wherein all substitutents have the meanings as defined in Claim 1 as preservatives in personal care, pharmaceutical and household; the preservatives can also be used as in-can preservatives.
Abstract translation: 本发明涉及式(1)化合物的用途,其中所有取代基具有权利要求1中定义的含义作为个人护理,制药和家庭中的防腐剂; 防腐剂也可以作为罐内防腐剂使用。
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公开(公告)号:WO2005079744A1
公开(公告)日:2005-09-01
申请号:PCT/EP2005/050605
申请日:2005-02-11
Applicant: CIBA SPECIALTY CHEMICALS HOLDING INC. , HÖLZL, Werner , PREUSS, Andrea
Inventor: HÖLZL, Werner , PREUSS, Andrea
IPC: A61K7/48
CPC classification number: A61K8/368 , A61K8/39 , A61Q11/00 , A61Q15/00 , A61Q17/005
Abstract: Use of compounds of formula (I) wherein R 1 is substituted or unsubstituted C 8 -C 30 alkyl or substituted or unsubstituted C 3 -C 7 cyclo- alkyl, and R 2 is H, COOH or substituted or unsubstituted O-C 1 -C 30 alkyl, in the antimicrobial treatment of surfaces, in the preservation of cosmetics, household products, textiles and plastics, and for use in disinfectants.
Abstract translation: 在表面的抗微生物处理中,其中R 1为取代或未取代的C 8 -C 30烷基或取代或未取代的C 3 -C 7环烷基,R 2为H,COOH或取代或未取代的O-C 1 -C 30烷基的式(I) 在化妆品,家用产品,纺织品和塑料的保存和用于消毒剂。
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公开(公告)号:WO2003078367A2
公开(公告)日:2003-09-25
申请号:PCT/EP2003/002618
申请日:2003-03-13
Applicant: CIBA SPECIALTY CHEMICALS HOLDING INC. , HÖLZL, Werner , KOPPOLD, Jürgen , MARQUAIS-BIENEWALD, Sophie , PREUSS, Andrea
Inventor: HÖLZL, Werner , KOPPOLD, Jürgen , MARQUAIS-BIENEWALD, Sophie , PREUSS, Andrea
IPC: C07C43/23
CPC classification number: A61Q17/005 , A01N31/14 , A01N31/16 , A01N55/00 , A61K8/34 , A61Q5/00 , A61Q11/00 , A61Q15/00 , C07C43/23 , C07C43/253 , C07F7/0818
Abstract: The use of benzyl alcohol derivatives of the formula CH2OH in which R,, R2, R3, n and m have the meanings given in claim 1, as microbicidal active substances is described. The compounds exhibit a marked effect against pathogenic Gram-positive and Gramnegative bacteria. They are therefore suitable for the antimicrobial treatment, in particular preservation and disinfection, of surfaces.
Abstract translation: 描述了其中R 1,R 2,R 3,n和m具有权利要求1中给出的含义的式CH 2 OH的苄醇衍生物作为杀微生物活性物质。 该化合物对致病革兰氏阳性和革兰氏阴性细菌表现出显着的作用。 因此,它们适用于表面的抗菌处理,特别是保存和消毒。
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公开(公告)号:WO2007099042A1
公开(公告)日:2007-09-07
申请号:PCT/EP2007/051548
申请日:2007-02-19
Applicant: CIBA SPECIALTY CHEMICALS HOLDING INC. , HÖLZL, Werner , PREUSS, Andrea , GERSTER, Michèle
Inventor: HÖLZL, Werner , PREUSS, Andrea , GERSTER, Michèle
IPC: A01N33/12 , C08G77/04 , C08G77/26 , C08G77/388
CPC classification number: A01N33/12 , A01N55/00 , C07F7/0854 , C08G77/045 , C08G77/388
Abstract: The invention relates to cationic siloxane derivatives for use especially as fungicides and/or antiadhesives. The cationic siloxane derivatives have the formula (I), wherein R1, R2, R3, R4, R 4 ', R5 and n are as defined in the description.
Abstract translation: 本发明涉及特别用作杀真菌剂和/或抗粘合剂的阳离子硅氧烷衍生物。 阳离子硅氧烷衍生物具有式(I),其中R 1,R 2,R 3,R 4,R 4,R 5和n如说明书中所定义。
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10.
公开(公告)号:WO2005011758A2
公开(公告)日:2005-02-10
申请号:PCT/EP2004/051516
申请日:2004-07-16
Applicant: CIBA SPECIALTY CHEMICALS HOLDING INC. , MARQUAIS-BIENEWALD, Sophie , HÖLZL, Werner , PREUSS, Andrea , MEHLIN, Andreas
Inventor: MARQUAIS-BIENEWALD, Sophie , HÖLZL, Werner , PREUSS, Andrea , MEHLIN, Andreas
IPC: A61L2/18
CPC classification number: A61Q17/005 , A01N43/54 , A61K8/4953 , A61L2/16 , A61L2/18 , A61Q11/00 , C11D3/28 , C11D3/48 , D06M13/355 , Y10T442/2525
Abstract: The use of 2,4-bis(alkylamino)pyrimidines of formula (1) R 1 is C 1 -C 12 alkyl or C 6 -C 10 laryl; R 2 is hydrogen or C 1 -C 12 alkyl; or R 1 and R 2 together forma radical of formula (1 a) R' and R" are each independently of the other hydrogen, C 1 -C 6 alkyl or C 1 -C 6 alkoxy, R 3 and R 5 are each independently of the other hydrogen or C 1 -C 8 alkyl; R 4 is C 1 -C 20 alkyl, unsubstituted phenyl, C 6 -C 10 aryl, C 6 -C 10 aryl-C 1 -C 6 alkyl, hydroxy-C 1 -C 6 alkyl, di-C 1 -C 6 al-kylamino-C 1 -C 6 aIkyl, mono-C 1 -C 6 alkylamino-C 1 -C 6 alkyl, -(CH 2 )2-(O-(CH 2 ) 2 ) 1-4 -OH or -(CH 2 ) 2 -(O-(CH 2 ) 2 ) 1-4 -NH 2 ; R 6 is C 1 -C 20 alkyl, C 6 -C 10 aryl, C 6 -C 10 aryl-C 1 -C 6 alkyl, hydroxy-C 1 -C 6 alkyl, di-C 1 C 6 alkylamino-C 1 -C 6 alkyl, mono-C 1 -C 6 alkylamino-C 1 -C 6 alkyl, -(CH 2 ) 2 -(O-(CH 2 ) 2 ) 1-4 -OH or -(CH 2 ) 2 -(O-(CH 2 ) 2 ) 1-4 -NH 2 ; or R 3 and R 4 and/or R 5 and R 6 , together form a pyrrolidine, piperidine, hexamethyleneimine or morpholine ring; in the antimicrobial treatment of surfaces.
Abstract translation: 式(1)R 1的2,4-双(烷基氨基)嘧啶的用途是C 1 -C 12烷基或C 6 -C 10芳基; R2是氢或C1-C12烷基; 或者R 1和R 2一起形成式(1a)的基团,R'和R“各自独立地为氢,C 1 -C 6烷基或C 1 -C 6烷氧基,R 3和R 5各自独立地为氢或C 1 -C 8烷基; R 4 是C 1 -C 20烷基,未取代的苯基,C 6 -C 10芳基,C 6 -C 10芳基-C 1 -C 6烷基,羟基-C 1 -C 6烷基,二-C 1 -C 6烷基氨基-C 1 -C 6烷基,单-C 1 -C 6烷基氨基-C 1 -C 6烷基, - ( CH2)2-(O-(CH2)2)1-4-OH或 - (CH2)2-(O-(CH2)2)1-4-NH2; R6是C1-C20烷基,C6-C10芳基, C 1 -C 10芳基-C 1 -C 6烷基,羟基-C 1 -C 6烷基,二-C 1 -C 6烷基氨基-C 1 -C 6烷基,单-C 1 -C 6烷基氨基-C 1 -C 6烷基, - (CH 2)2 - (O-(CH 2)2)1-4 -OH或 - (CH2)2-(O-(CH2)2)1-4-NH2;或R3和R4和/或R5和R6一起形成吡咯烷,哌啶,六亚甲基亚胺或吗啉环;在表面的抗微生物处理中。
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