Abstract:
Polyalkylphenoxyaminoalkanes having formula (I), wherein R is a polyalkyl group having an average molecular weight in the range of about 600 to 5,000; R1 and R2 are independently hydrogen or lower alkyl having 1 to 6 carbon atoms; and A is amino, N-alkyl amino having about 1 to about 20 carbon atoms in the alkyl group, N,N-dialkyl amino having about 1 to about 20 carbon atoms in each alkyl group, or a polyamine moiety having about 2 to about 12 amine nitrogen atoms and about 2 to about 40 carbon atoms. The compounds of formula (I) are useful as fuel additives for the prevention and control of engine deposits.
Abstract:
Aromatic esters of polyalkylphenoxyalkanols having formula (I), or a fuel soluble salt thereof, wherein R is hydroxy, nitro or -(CH2)x-NR5R6, wherein R5 and R6 are independently hydrogen or lower alkyl having 1 to 6 carbon atoms and x is 0 or 1; R1 is hydrogen, hydroxy, nitro or -NR7R8, wherein R7 and R8 are independently hydrogen or lower alkyl having 1 to 6 carbon atoms; R2 and R3 are independently hydrogen or lower alkyl having 1 to 6 carbon atoms; and R4 is a polyalkyl group having an average molecular weight in the range of about 450 to 5,000. The compounds of formula (I) are useful as fuel additives for the prevention and control of engine deposits.
Abstract translation:具有式(I)的聚烷基苯氧基烷醇或其燃料可溶性盐的芳族酯,其中R是羟基,硝基或 - (CH 2)x -NR 5 R 6,其中R 5和R 6独立地是氢或具有1至6个碳原子的低级烷基,x 是0或1; R 1是氢,羟基,硝基或-NR 7 R 8,其中R 7和R 8独立地是氢或具有1至6个碳原子的低级烷基; R2和R3独立地是氢或具有1-6个碳原子的低级烷基; 并且R 4是平均分子量在约450至5,000范围内的聚烷基。 式(I)化合物可用作预防和控制发动机沉积物的燃料添加剂。
Abstract:
Disclosed is a catalyst system for the homopolymerization of alpha-olefins having 2-8 carbon atoms, said catalyst system comprising a mixed-valent dimeric Group 6b metal compound catalyst precursor wherein one atom of said Group 6b metal is a cyclopentadienyl Group 6b metal hydrocarbyl complex in which the Group 6b metal has an oxidation state +3 and wherein one atom of said Group 6b metal is a cyclopentadienyl alkaryl complex in which the Group 6b metal has an oxidation state +1, said dimeric Group 6b metal compound being supported on an inorganic support. The catalyst system can contain, in addition, a Group 2 or Group 3 metal-alkyl compound.
Abstract:
An improved oxygen scavenging system is provided. The system involves an oxygen scavenging phase containing at least one oxygen-scavenger and a second phase comprising at least one catalyst effective in catalyzing a scavenging reaction. The oxygen scavenging phase is substantially devoid of any catalyst of the scavenging reaction and the second phase is effectively separate from the oxygen scavenging phase. Nevertheless, the oxygen scavenging system provides excellent scavenging capabilities while avoiding many of the prior art problems, such as undesired oxidation during high temperature processing when the system is incorporated into a multi-layer film.
Abstract:
Ionomer compositions which have improved optical properties are disclosed. These compositions comprise ionomers which can be represented as the polymerization product of alpha-olefins having from two to eight carbon atoms, esters of alpha, beta-ethylenically-unsaturated carboxylic acids, metal salts of acrylic and methacrylic acid, and optional alpha, beta-ethylenically-unsaturated comonomers which impart some desired polymer property or properties, such as acidity and/or solvent resistivity. Also disclosed are methods of making these ionomer compositions in a reactive extruder and treating the compositions with acid to impart acidity to the compositions or to only the surface of the compositions.
Abstract:
Provided is a process for catalytically reforming a hydrocarbon feedstock using a highly sulfur sensivite catalyst. The process comprises contacting the hydrocarbon in a reaction zone, with the hydrocarbon feed and catalyst flowing in opposite directions. Once the catalyst has passed through the reaction zone, it is then passed to a regeneration zone for regeneration. The process eliminates the need of passing the hydrocarbon feed through a sulfur sorber prior to entry into the reaction zone, as the spent catalyst which is leaving the reaction zone for regeneration acts as a sulfur sorber and removes the sulfur from the feed entering the reaction zone.
Abstract:
Ionomer compositions which have improved optical properties are disclosed. These compositions comprise ionomers which can be represented as the polymerization product of alpha-olefins having from two to eight carbon atoms, esters of alpha, beta-ethylenically-unsaturated carboxylic acids, metal salts of acrylic and methacrylic acid, and optional alpha, beta-ethylenically-unsaturated comonomers which impart some desired polymer property or properties, such as acidity and/or solvent resistivity. Also disclosed are methods of making these ionomer compositions in a reactive extruder and treating the compositions with acid to impart acidity to the compositions or to only the surface of the compositions.
Abstract:
Provided is a system useful for oxygen scavenging which comprises at least two components, i.e., an oxygen scavenging material which forms at least one by-product upon reaction thereof with oxygen, and an effective amount of a neutralizing material capable of neutralizing at least a portion of theses by-products. In a preferred application, a multi-layer structure that can be employed in producing packages and in particular food packages, comprises a first layer including an oxygen scavenging material and a second layer which includes a material that is capable of neutralizing at least a portion of the by-products produced by the oxidation of the oxygen scavenging material within the first layer. These two layers are arranged such that, upon formation of the package, the second layer is interior to the first layer. Furthermore, the multi-layer film can include one or more of an oxygen barrier layer, a polymeric selective barrier layer, and a heat-sealable layer.
Abstract:
Disclosed is a catalyst system for the homopolymerization of alpha-olefins having 2-8 carbon atoms, said catalyst system comprising a Group 6b metal-alkali metal compound wherein said Group 6b metal is a cyclopentadienyl Group 6b metal trialkaryl complex anion in which the Group 6b metal has an oxidation state +3 and wherein said complex anion is balanced by an alkali metal cation such as lithium and wherein the alkali metal cation is, optionally, coordinately linked to a neutral hydrocarbyl based ligand containing a heteroatom such as oxygen, nitrogen, phosphorus or sulphur, said Group 6b metal-alkali metal compound being supported on an inorganic support. The catalyst system can contain, in addition, a Group 2 or Group 3 metal-alkyl compound.
Abstract:
Benzene is alkylated with C20-C24alpha olefins in the presence of a solid, aciditic tin-containing or zirconia-containing catalyst, such as ZrO2-H2SO4, ZrO2-WO3, or SnO2-H2SO4. The catalyst is activated prior to use and the activated catalyst is used without exposure to atmospheric water.