公开(公告)号：WO2015148931A1

公开(公告)日：2015-10-01

申请号：PCT/US2015/023008

申请日：2015-03-27

Applicant: DOW GLOBAL TECHNOLOGIES LLC ,  DOW AGROSCIENCES LLC

Inventor： HANLEY, Patrick S. ,  WHITEKER, Gregory T. ,  OBER, Matthias S. ,  KRUPER, Jr. ,  KRASOVSKIY, Arkady L.

IPC: C07B37/04

CPC classification number: C07C1/322 ,  C07B37/04 ,  C07C1/321 ,  C07C15/14 ,  C07C17/263 ,  C07C22/04 ,  C07C22/08 ,  C07C41/30 ,  C07C45/70 ,  C07C67/343 ,  C07C211/45 ,  C07C231/12 ,  C07C233/00 ,  C07C253/30 ,  C07C2531/22 ,  C07C2531/24 ,  C07C2531/28 ,  C07D213/127 ,  C07D213/16 ,  C07D263/54 ,  C07C233/65 ,  C07C255/50 ,  C07C43/205 ,  C07C49/784 ,  C07C69/76

Abstract: In one aspect, there is provided a method of coupling a first aromatic compound having a fluorosulfonate substituent to a second aromatic compound having a boron-containing substituent. In another aspect, there is provided a method of coupling a first aromatic compound having a hydroxyl substituent to a second aromatic compound having a boron-containing substituent in a one-pot reaction.

Abstract translation: 一方面，提供了将具有氟磺酸盐取代基的第一芳香族化合物与具有含硼取代基的第二芳香族化合物结合的方法。 在另一方面，提供了在一锅反应中将具有羟基取代基的第一芳族化合物与具有含硼取代基的第二芳族化合物偶联的方法。

公开(公告)号：WO2015138128A1

公开(公告)日：2015-09-17

申请号：PCT/US2015/017653

申请日：2015-02-26

Applicant: DOW GLOBAL TECHNOLOGIES LLC

Inventor： TULCHINSKY, Michael L. ,  KRUPER, Jr. ,  KUO, Tzu-Chi ,  MOLZAHN, David C. ,  SONNENSCHEIN, Mark F.

IPC: C07D303/04

CPC classification number: C08G59/223 ,  C07D303/04 ,  C07D303/22 ,  C08G59/68 ,  C09D163/00

Abstract: A novel byproduct compound having the following chemical formula B; wherein R is hydrogen or CH 3 ; a composition including an admixture of: (A) a product having the following chemical formula A; wherein R is hydrogen or CH 3 ; and (B) the above novel byproduct compound having the chemical formula B; and a composition including a reaction product of: (a) an aromatic epoxy resin; (b) hydrogen; (c) a catalyst; and (d) a solvent; wherein the reaction product produced is a cycloaliphatic epoxy resin admixture of the combination of (i) the above product having the chemical formula A and (ii) the novel byproduct compound having the chemical formula B; wherein the above product having the chemical formula A includes at least a cis-cis isomer, a cis-trans isomer, and a trans-trans isomer; and the novel byproduct compound having the chemical formula B includes at least a cis isomer and a trans isomer.

Abstract translation: 具有以下化学式B的新型副产物化合物; 其中R是氢或CH 3; 包含以下化合物的混合物的组合物：（A）具有以下化学式A的产物; 其中R是氢或CH 3; 和（B）上述具有化学式B的新型副产物化合物; 以及包含以下反应产物的组合物：（a）芳族环氧树脂; （b）氢; （c）催化剂; 和（d）溶剂; 其中产生的反应产物是（i）具有化学式A的上述产物和（ii）具有化学式B的新型副产物化合物的组合的脂环族环氧树脂混合物; 其中具有化学式A的上述产物至少包含顺式顺式异构体，顺式反式异构体和反式反式异构体; 具有化学式B的新型副产物化合物至少包含顺式异构体和反式异构体。

公开(公告)号：WO2012125218A1

公开(公告)日：2012-09-20

申请号：PCT/US2012/020744

申请日：2012-01-10

Applicant: DOW GLOBAL TECHNOLOGIES LLC ,  KRUPER, Jr. ,  RAND, Cynthia L. ,  MOLZAHN, David C.

Inventor： KRUPER, Jr. ,  RAND, Cynthia L. ,  MOLZAHN, David C.

IPC: C07C69/82 ,  C07C67/297 ,  C07C51/377 ,  C07C69/675 ,  C07C63/26

CPC classification number: C07C69/757 ,  C07C51/377 ,  C07C63/26 ,  C07C67/297 ,  C07C67/31 ,  C07C67/317 ,  C07C67/327 ,  C07C69/675 ,  C07C69/82 ,  C07C69/75

Abstract: The present invention generally relates to a condensed process for producing terephthalic acid and terephthalic esters from a dialkyl cyclohexane-2,5-dione-1,4-dicarboxylate; a chemoselective process for preparing a substantially bicyclic-lactone-free dialkyl cyclohexane-2,5-diol-1,4-dicarboxylate; and compositions of matter prepared thereby.

Abstract translation: 本发明一般涉及一种由环己烷-2,5-二酮-1,4-二羧酸二烷基酯制备对苯二甲酸和对苯二甲酸酯的缩合方法; 用于制备基本上不含二环内酯的二烷基环己烷-2,5-二醇-1,4-二羧酸酯的化学选择性方法; 和由此制备的物质的组成。