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公开(公告)号：WO2019191068A1
公开(公告)日：2019-10-03
申请号：PCT/US2019/024034
申请日：2019-03-26
发明人： KEATON, Richard J. , HUACUJA, Rafael , WILSON, David R. , KLOSIN, Jerzy , PEARSON, David M. , SENECAL, Todd D. , MUKHOPADHYAY, Sukrit , WOODWARD, William H. H.
IPC分类号： B01J31/02 , C08F110/14 , C08F210/16 , C08F4/659
摘要： Embodiments of this disclosure include processes of polymerizing olefins, the process comprising contacting ethylene and a (C 3 -C 40 )alpha-olefin comonomer in the presence of a catalyst system, the catalyst system comprising a Group IV metal-ligand complex and an ionic metallic activator complex, the ionic metallic activator complex comprising an anion and a countercation, the anion having a structure according to formula (I):formula (I)
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公开(公告)号：WO2019190925A1
公开(公告)日：2019-10-03
申请号：PCT/US2019/023643
申请日：2019-03-22
发明人： KEATON, Richard J. , HUACUJA, Rafel , WILSON, David R. , KLOSIN, Jerzy , PEARSON, David M. , SENECAL, Todd D. , MUKHOPADHYAY, Sukrit , WOODWARD, William H.H.
IPC分类号： C08F210/16 , C08F4/642
摘要： Embodiments of the disclosure include processes of polymerizing olefins. The process includes contacting ethylene and a (C 3 −C 40 )alpha-olefin comonomer in the presences of a catalyst system. The catalyst system comprises a procatalyst and a bimetallic activator complex. The bimetallic activator complex comprises an anion and a countercation, and the anion has a structure according to formula (I).
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3.发明申请
公开(公告)号：WO2019067274A8
公开(公告)日：2019-04-04
申请号：PCT/US2018/051638
申请日：2018-09-19
发明人： KRASOVSKIY, Arkady L. , WILSON, David R. , STUBBERT, Bryan D. , VAIDYA, Tulaza , KLOSIN, Jerzy , CARNAHAN, Edmund M. , FONTAINE, Philip P. , ROSEN, Mari S.
IPC分类号： C08F4/659 , C08F210/16 , C08F4/64
摘要： Embodiments are directed to a catalyst system comprising metal ligand complexes and processes for polyolefin polymerization using the metal ligand complex having the following structure: where each X is selected from the group consisting of -(CH 2 )SiR X 3 .
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公开(公告)号：WO2019055742A1
公开(公告)日：2019-03-21
申请号：PCT/US2018/051004
申请日：2018-09-14
发明人： RAGHURAMAN, Arjun , HEATH, William H. , HOOK, Bruce D. , YU, Wanglin , MUKHOPADHYAY, Sukrit , SPINNEY, Heather A. , WILSON, David R.
摘要： A method of producing an alcohol ethoxylate surfactant or lubricant, the method including reacting a low molecular weight initiator with ethylene oxide in the presence of a polymerization catalyst, the low molecular weight initiator having a nominal hydroxyl functionality at least 1, and the polymerization catalyst being a Lewis acid catalyst having the general formula M(R 1 ) I (R 2 ) I (R 3 ) I (R 4 ) 0 or 1 , whereas M is boron, aluminum, indium, bismuth or erbium, R 1 , R 2 , R 3 , and R 4 are each independent, R 1 includes a first fluoroalkyl-substituted phenyl group, R 2 includes a second fluoroalkyl-substituted phenyl group or a first fluoro/chloro- substituted phenyl group, R 3 includes a third fluoroalkyl-substituted phenyl group or a second fluoro/chloro-substituted phenyl group, and optional R 4 includes a functional group or functional polymer group, R 1 being different from at least one of R 2 and R 3 . The method further including forming an alcohol ethoxylate surfactant or lubricant having a number average molecular weight of greater than the number average molecular weight of the low molecular weight initiator in the presence of the Lewis acid catalyst.
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公开(公告)号：WO2016149025A2
公开(公告)日：2016-09-22
申请号：PCT/US2016/021702
申请日：2016-03-10
发明人： KLOSIN, Jerzy , MILBRANDT, Kara A. , BOELTER, Scott D. , WILSON, David R. , ROSEN, Mari S. , WELSH, Dean M. , MARGL, Peter M. , KOH, Kyoung Moo , PEARSON, David M. , HUACUJA, Rafael
IPC分类号： B01J31/24
CPC分类号： B01J31/2433 , B01J31/143 , B01J31/188 , B01J31/2208 , B01J31/2438 , B01J31/2457 , B01J31/2476 , B01J31/2495 , B01J2231/20 , B01J2531/62 , B01J2540/10 , B01J2540/22 , B01J2540/225 , B01J2540/30 , B01J2540/34 , B01J2540/444 , C07C2/36 , C07C2531/14 , C07C2531/18 , C07C2531/24 , C07F9/6568 , C07F9/65683 , C07F9/65685 , C07F9/6571 , C07F9/657154 , C07F9/65842 , C07F9/65844 , C07F9/65846 , C07F9/65848 , C07F11/005 , C07F17/02 , C07C11/02 , C07C11/107
摘要： The invention relates to oligomerization of olefins, such as ethylene, to higher olefins, such as a mixture of 1-hexene and 1-octene, using a catalyst system that comprises a) a source of chromium b) one or more activators and c) a phosphacycle-containing ligating compound. Addtionally, the invention relates to a phosphacycle-containing ligating compound and a process for making said compound.
摘要翻译： 本发明涉及使用包括a）铬源b）一种或多种活化剂的催化剂体系将烯烃如乙烯低聚成高级烯烃，例如1-己烯和1-辛烯的混合物，和c） 含磷酸基的连接化合物。 此外，本发明涉及含有磷酸酯基的连接化合物和制备所述化合物的方法。
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6.发明申请
公开(公告)号：WO2020068494A1
公开(公告)日：2020-04-02
申请号：PCT/US2019/051572
申请日：2019-09-17
发明人： PATANKAR, Kshitish A. , RAGHURAMAN, Arjun , WILLUMSTAD, Thomas P. , SONNENSCHEIN, Mark F. , HENNING, Jody , SPINNEY, Heather A. , WILSON, David R. , MUKHOPADHYAY, Sukrit
摘要： Hydroxyl-containing copolymers of butylene oxide and ethylene oxide having a hydroxyl equivalent weight of at least 150, an average of 1.8 to 6 hydroxyl groups per molecule of which hydroxyl groups at least 70% are primary hydroxyl groups and an oxyethylene content of no greater than 10% by weight based on the weight of the copolymer, are useful for making polyurethanes. These polyols are characterized by high reactivity and fast curing times. Polyurethanes made using these polyols have excellent mechanical properties and are highly hydrophobic.
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公开(公告)号：WO2020068493A1
公开(公告)日：2020-04-02
申请号：PCT/US2019/051571
申请日：2019-09-17
发明人： PATANKAR, Kshitish A. , RAGHURAMAN, Arjun , WILLUMSTAD, Thomas P. , SONNENSCHEIN, Mark F. , HENNING, Jody , SPINNEY, Heather A. , WILSON, David R. , MUKHOPADHYAY, Sukrit , HEATH, William H.
IPC分类号： C08G18/22 , C08G18/32 , C08G18/48 , C08G18/66 , C08G18/72 , C08G18/76 , C08G18/79 , C08G65/26
摘要： Polyurethanes are made in a one-shot process from one or more polyols having a hydroxyl equivalent weight of at least 350, wherein at least 50% of the weight of iii) is a hydroxyl-containing polymer of propylene oxide, the hydroxyl-containing polymer of propylene oxide having a hydroxyl equivalent weight of at least 350, an average of 1.8 to 3 hydroxyl groups per molecule of which hydroxyl groups 40 to 70% are primary hydroxyl groups, an oxyethylene content of no greater than 10% by weight based on the weight of the polymer and a polydispersity of 1.175 or less. The polyurethanes exhibit excellent mechanical properties, are highly hygroscopic and cured rapidly.
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8.发明申请
公开(公告)号：WO2019067300A1
公开(公告)日：2019-04-04
申请号：PCT/US2018/051939
申请日：2018-09-20
发明人： STUBBERT, Bryan D. , KRASOVSKIY, Arkady L. , VAIDYA, Tulaza , KLOSIN, Jerzy , CARNAHAN, Edmund M. , FONTAINE, Philip P. , ROSEN, Mari S. , WILSON, David R.
IPC分类号： C08F210/16 , C08F4/64
摘要： Embodiments are directed to a catalyst system comprising metal-ligand complexes and processes for polyolefin polymerization using the metal-ligand complex having the following structure, Formula (I), where X is selected from the group consisting of -(CH2)SiRX3.
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公开(公告)号：WO2016149027A2
公开(公告)日：2016-09-22
申请号：PCT/US2016/021709
申请日：2016-03-10
发明人： KLOSIN, Jerzy , MILBRANDT, Kara A. , BOELTER, Scott D. , WILSON, David R. , ROSEN, Mari S. , WELSH, Dean M. , MARGL, Peter M. , KOH, Kyoung Moo , PEARSON, David M. , HUACUJA, Rafael
IPC分类号： B01J31/24
CPC分类号： B01J31/2433 , B01J31/143 , B01J31/188 , B01J31/2208 , B01J31/2438 , B01J31/2457 , B01J31/2476 , B01J31/2495 , B01J2231/20 , B01J2531/62 , B01J2540/10 , B01J2540/22 , B01J2540/225 , B01J2540/30 , B01J2540/34 , B01J2540/444 , C07C2/36 , C07C2531/14 , C07C2531/18 , C07C2531/24 , C07F9/6568 , C07F9/65683 , C07F9/65685 , C07F9/6571 , C07F9/657154 , C07F9/65842 , C07F9/65844 , C07F9/65846 , C07F9/65848 , C07F11/005 , C07F17/02 , C07C11/02 , C07C11/107
摘要： The invention relates to oligomerization of olefins, such as ethylene, to higher olefins, such as a mixture of 1-hexene and 1-octene, using a catalyst system that comprises a) a source of chromium b) one or more activators and c) a phosphacycle-containing ligating compound. Addtionally, the invention relates to a phosphacycle-containing ligating compound and a process for making said compound.
摘要翻译： 本发明涉及使用包括a）铬源b）一种或多种活化剂的催化剂体系将烯烃如乙烯低聚成高级烯烃，例如1-己烯和1-辛烯的混合物，和c） 含磷酸基的连接化合物。 此外，本发明涉及含有磷酸酯基的连接化合物和制备所述化合物的方法。
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公开(公告)号：WO2021202722A1
公开(公告)日：2021-10-07
申请号：PCT/US2021/025161
申请日：2021-03-31
发明人： NETT, Alex J. , SPINNEY, Heather A. , SENECAL, Todd D. , WILSON, David R. , FROESE, Robert D.J. , GARZA GONZALEZ, Alejandro J.
IPC分类号： C08F210/02 , C08F4/80
摘要： Processes of polymerizing olefin monomers using catalyst systems and catalysts systems that include a procatalyst having a structure according to formula (I):
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