公开(公告)号：WO2016153803A1

公开(公告)日：2016-09-29

申请号：PCT/US2016/021756

申请日：2016-03-10

申请人： EXXONMOBIL RESEARCH AND ENGINEERING COMPANY

发明人： UMANSKY, Benjamin, S. ,  HOO, Tech-Mui ,  DEMMIN, Richard, A. ,  CHEN, Fengrong ,  GLEESON, James, W. ,  DOU, Suisheng, M. ,  MELLI, Tomas, R. ,  CLARK, Michael, C.

IPC分类号： C10G65/12 ,  C10G47/14 ,  C10G47/16

CPC分类号： C10G67/02 ,  C10G47/14 ,  C10G47/16 ,  C10G65/12 ,  C10G2300/301 ,  C10G2300/302 ,  C10G2300/304 ,  C10G2400/10 ,  C10M101/02

摘要： A process for producing high yields of higher quality (API Group II, Group ΙΙI`) lubricating oil basestock fractions which allows the production of two or more types of high quality lubes in continuous mode (no blocked operation mode) without transition times and feed or intermediate product tankage segregation. Two consecutive hydroprocessing steps are used: the first step processes a wide cut feed at a severity needed to match heavy oil lube properties. The second step hvdroprocesses a light oil after fractionation of the liquid product from the first step at a severity higher than for the heavy oil fraction. The two hydroprocessing steps will normally be carried out in separate reactors but they may be combined in a single reactor which allows for the two fractions to be processed with different degrees of severity.

摘要翻译： 生产高产量的高质量（API Group II，Group IIII）润滑油基础油馏分的方法，其允许以连续模式（无阻塞操作模式）生产两种或更多种类型的高质量润滑剂，而不需要过渡时间和进料或 中间产品油罐分离。 使用两个连续的加氢处理步骤：第一步按照重油润滑油性能所需的严重程度处理宽切削进料。 第二步，以比重油馏分高的浓度从第一步骤中分离液体产物之后进行轻油处理。 两个加氢处理步骤通常在单独的反应器中进行，但是它们可以在单个反应器中组合，这允许以不同的严重程度处理两个馏分。

公开(公告)号：WO2014025668A1

公开(公告)日：2014-02-13

申请号：PCT/US2013/053575

申请日：2013-08-05

申请人： EXXONMOBIL RESEARCH AND ENGINEERING COMPANY

发明人： RAMOS, Antonio, O. ,  KORSTEN, Hans, G. ,  HUANG, Yi, En ,  NADARAJAH, Chithranjan ,  UMANSKY, Benjamin, S.

IPC分类号： B01J8/00

CPC分类号： B01J8/0015 ,  B01J8/002 ,  B01J8/003 ,  B01J2208/00752

摘要： Methods, devices and processes for effectively loading catalysts into reactor vessels. In particular methods, devices and processes for effectively loading catalysts into fixed bed reactors utilizing inducted vibrational energy to improve catalyst loading performance, thereby resulting in improved flow distribution through the catalyst beds at designed operating conditions. The methods herein are particularly effectively for improving the performance of new or existing catalyst bed configurations of vertically-oriented two-phase hydroprocessing fixed bed reactors.

摘要翻译： 有效地将催化剂装载到反应堆容器中的方法，装置和方法。 特别是使用引入的振动能量有效地将催化剂加载到固定床反应器中以改善催化剂装载性能的方法，装置和方法，从而在设计的操作条件下导致通过催化剂床的流量分布改善。 本文的方法特别有效地改善了垂直取向的两相加氢固定床反应器的新的或现有的催化剂床构型的性能。

公开(公告)号：WO2021230985A1

公开(公告)日：2021-11-18

申请号：PCT/US2021/024550

申请日：2021-03-29

申请人： EXXONMOBIL RESEARCH AND ENGINEERING COMPANY

发明人： GLEESON, James, W. ,  UMANSKY, Benjamin, S. ,  FRUCHEY, Kendall, S.

IPC分类号： B01D71/02 ,  C10G31/09

摘要： Provided herein are molecular sieve membranes (100) for separating hydrocarbons of a lube feed stock into a permeate and a retentate based on molecular shape. The molecular sieve membranes comprise one or more layers of size-selective catalyst and a porous support comprising a plurality of diffusing gaps. Each layer of size-selective catalyst has a plurality of perpendicular membrane channels (12) and a plurality of opening pores (14). The porous support is in fluidic communication with the plurality of opening pores to provide a fluidic pathway between the perpendicular membrane channels and the diffusing gaps. Also provided are processes for separating n-paraffins from other hydrocarbons in a lube feed stock using the present molecular sieve membranes.

公开(公告)号：WO2011133829A1

公开(公告)日：2011-10-27

申请号：PCT/US2011/033514

申请日：2011-04-22

申请人： EXXONMOBIL RESEARCH AND ENGINEERING COMPANY ,  UMANSKY, Benjamin, S. ,  KALYANARAMAN, Mohan ,  HILBERT, Timothy, L. ,  LOPEZ, Carlos, N. ,  ZHANG, Lei

发明人： UMANSKY, Benjamin, S. ,  KALYANARAMAN, Mohan ,  HILBERT, Timothy, L. ,  LOPEZ, Carlos, N. ,  ZHANG, Lei

IPC分类号： C10G65/04 ,  C10G45/58

CPC分类号： C10G45/02 ,  B01D3/141 ,  C10G45/58 ,  C10G45/64 ,  C10G65/043 ,  C10G2300/202 ,  C10G2300/304 ,  C10G2300/4018 ,  C10G2400/04 ,  C10L1/08

摘要： A diesel fuel product with beneficial cold flow properties can be produced. A suitable feedstock for forming a diesel boiling range product can be hydrotreated to have a sulfur content of at least about 100 wppm and then dewaxed. This two stage process can allow for production of an arctic or winter diesel without use of high pressures. Optionally, a divided wall column fractionator can be used to allow a single separation stage to handle the effluent from both the hydroprocessing and the dewaxing stages.

摘要翻译： 可以生产具有有益冷流特性的柴油燃料产品。 用于形成柴油沸点产物的合适原料可以被加氢处理以具有至少约100wppm的硫含量，然后脱蜡。 这两个阶段的过程可以允许生产北极或冬季柴油而不使用高压。 任选地，可以使用分开的塔柱分馏器来使单个分离阶段处理来自加氢处理和脱蜡阶段的流出物。

公开(公告)号：WO2010104581A2

公开(公告)日：2010-09-16

申请号：PCT/US2010/000731

申请日：2010-03-11

申请人： EXXONMOBIL RESEARCH AND ENGINEERING COMPANY ,  CLARK, Michael, C. ,  UMANSKY, Benjamin, S. ,  NYE, Elizabeth, A. ,  REICHENSPERGER, Mark, J. ,  LEWIS, William, C.

发明人： CLARK, Michael, C. ,  UMANSKY, Benjamin, S. ,  NYE, Elizabeth, A. ,  REICHENSPERGER, Mark, J. ,  LEWIS, William, C.

IPC分类号： C10G35/06

CPC分类号： C10G35/065 ,  B01J29/7038 ,  C07C2/66 ,  C07C2529/70 ,  C10G29/205 ,  C10G2300/1092 ,  C10G2300/1096 ,  C10G2300/301 ,  C10G2300/305 ,  C10G2300/4018 ,  C10G2400/02 ,  Y02P20/52 ,  C07C15/085

摘要： A process for the alkylation of a benzene-containing refinery stream such as reformate with light refinery olefins which is capable of achieving high benzene conversion levels operates in a fixed bed of an MWW zeolite catalyst, preferably MCM- 22, in single pass mode in the liquid phase at a relatively low to moderate temperatures with pressure maintained at a value adequate to ensure subcritical operation. High levels of benzene conversion with conversions of at least 90% and higher, e.g. 92% or 95% or even higher are achievable. A high octane product is produced, comprising mono-, di- and tri-alkylbenzenes with lesser levels of the tetra-substituted products. By operating with staged olefin injection, the end point of the alkylation product can be maintained at a low value while, at the same time, achieving high levels of benzene and olefin conversion.

摘要翻译： 使用能够实现高苯转化水平的轻炼油烯烃的含苯精炼料流如重整油的烷基化方法在MWW沸石催化剂（优选MCM-22）的固定床中以单程模式在 液相在相对低至中等温度下，压力保持在足以确保亚临界操作的值。 高转化率的苯转化率至少为90％以上，例如。 可达到92％或95％甚至更高。 产生高辛烷值的产物，其包含具有较少含量的四取代产物的单烷基苯，二烷基苯和三烷基苯。 通过使用分段烯烃注入操作，烷基化产物的终点可以保持在低值，同时实现高水平的苯和烯烃转化。

公开(公告)号：WO2018005141A1

公开(公告)日：2018-01-04

申请号：PCT/US2017/038077

申请日：2017-06-19

申请人： EXXONMOBIL RESEARCH AND ENGINEERING COMPANY

发明人： UMANSKY, Benjamin, S. ,  GUPTA, Himanshu ,  NELSON, John, D. ,  HUGHART, Cindy, J. ,  CHENG, Jane, C. ,  LEVINE, Steven, W. ,  BROWN, Stephen, H. ,  MARUT, Todd, P. ,  DANKWORTH, David, C. ,  SOLED, Stuart, L. ,  DEGNAN, Thomas, F. ,  FALKINER, Robert, J. ,  HARANDI, Mohsen, N. ,  HENAO, Juan, D. ,  ZHANG, Lei ,  BAI, Chuansheng ,  DOUGHERTY, Richard, C.

IPC分类号： C10G67/14 ,  B01J27/185 ,  B01J35/10 ,  C10G31/09 ,  C10G45/16

摘要： Systems and methods are provided for hydroconversion of a heavy oil feed under slurry hydroprocessing conditions and/or solvent assisted hydroprocessing conditions. The systems and methods for slurry hydroconversion can include the use of a configuration that can allow for improved separation of catalyst particles from the slurry hydroprocessing effluent. In addition to allowing for improved catalyst recycle, an amount of fines in the slurry hydroconversion effluent can be reduced or minimized. This can facilitate further processing or handling of any "pitch" generated during the slurry hydroconversion. The systems and methods for solvent assisted hydroprocessing can include processing of a heavy oil feed in conjunction with a high solvency dispersive power crude.

摘要翻译： 提供了用于在淤浆加氢处理条件和/或溶剂辅助加氢处理条件下加氢转化重油进料的系统和方法。 用于淤浆加氢转化的系统和方法可以包括使用可以允许催化剂颗粒从淤浆加氢处理流出物中改善分离的构型。 除了允许改进的催化剂再循环之外，浆料加氢转化流出物中的细粒的量可以减少或最小化。 这可以便于进一步处理或处理任何“音调” 在浆液加氢转化过程中产生。 用于溶剂辅助加氢处理的系统和方法可以包括与高溶解力分散能力原油一起处理重油进料。

公开(公告)号：WO2017205200A1

公开(公告)日：2017-11-30

申请号：PCT/US2017/033505

申请日：2017-05-19

申请人： EXXONMOBIL RESEARCH AND ENGINEERING COMPANY

发明人： UMANSKY, Benjamin, S. ,  ALDOUS, Keith, K. ,  GLEESON, James, W. ,  BLOK, Edward, J. ,  DEMMIN, Richard, A.

IPC分类号： C10G67/04

摘要： Systems and methods are provided for producing upgraded raffinate and extract products from lubricant boiling range feeds and/or other feeds having a boiling range of 400°F (204°C) to 1500°F (816°C) or more. The upgraded raffinate and/or extract products can have a reduced or minimized concentration of sulfur, nitrogen, metals, or a combination thereof. The reduced or minimized concentration of sulfur, nitrogen, and/or metals can be achieved by hydrotreating a suitable feed under hydrotreatment conditions corresponding to relatively low levels of feed conversion. Optionally, the feed can also dewaxed, such as by catalytic dewaxing or by solvent dewaxing. Because excessive aromatic saturation is not desired, the pressure for hydrotreatment (and optional dewaxing) can be 500 psig (∼3.4 MPa) to 1200 psig (∼8.2 MPa).

摘要翻译： 提供了系统和方法，用于从沸程为400°F（204℃）至1500°F（816℃）的润滑剂沸程进料和/或其它进料生产提质提余液和提取产物。 C）或更多。 升级后的残液和/或提取物产品可具有降低的或最小化的硫，氮，金属或其组合的浓度。 硫，氮和/或金属的浓度降低或最小化可以通过在对应于相对低水平的进料转化的加氢处理条件下加氢处理合适的进料来实现。 任选地，进料也可以脱蜡，例如通过催化脱蜡或通过溶剂脱蜡。 因为不需要过度的芳族饱和度，加氢处理（和任选的脱蜡）的压力可以是500psig（〜3.4MPa）至1200psig（〜8.2MPa）。

公开(公告)号：WO2012125888A1

公开(公告)日：2012-09-20

申请号：PCT/US2012/029350

申请日：2012-03-16

申请人： EXXONMOBIL RESEARCH AND ENGINEERING COMPANY ,  RAMOS, Antonio, O. ,  UMANSKY, Benjamin, S. ,  TRACY, William, J., III ,  GANDHI, Ramesh, X. ,  KORSTEN, Hans, G. ,  WYATT, John, T., Jr. ,  NOVAK, William, J.

发明人： RAMOS, Antonio, O. ,  UMANSKY, Benjamin, S. ,  TRACY, William, J., III ,  GANDHI, Ramesh, X. ,  KORSTEN, Hans, G. ,  WYATT, John, T., Jr. ,  NOVAK, William, J.

IPC分类号： B01J21/04 ,  B01J23/02

CPC分类号： B01J8/008 ,  B01J8/04 ,  B01J8/0453 ,  B01J2208/00884 ,  B01J2219/0002 ,  B01J2219/00024 ,  Y10T29/49345

摘要： A modular catalyst bed support can be used to increase the number of catalyst beds available in a reactor. The modular catalyst bed support can include a lattice with a plurality of lattice openings and modules inserted into the lattice openings. The modular catalyst bed support can rest on top of an underlying catalyst bed, which can reduce or eliminate the need for attachment of the modular catalyst bed support, to the walls of the reactor.

摘要翻译： 可以使用模块化催化剂床载体来增加反应器中可用的催化剂床数。 模块化催化剂床支撑件可以包括具有插入到格子孔中的多个格子孔和模块的格子。 模块化催化剂床支撑件可以搁置在下面的催化剂床的顶部上，这可以减少或消除将模块化催化剂床支撑件附接到反应器的壁的需要。

公开(公告)号：WO2008016636A2

公开(公告)日：2008-02-07

申请号：PCT/US2007/017173

申请日：2007-08-01

申请人： EXXONMOBIL RESEARCH AND ENGINEERING COMPANY ,  UMANSKY, Benjamin, S. ,  CLARK, Michael, C.

发明人： UMANSKY, Benjamin, S. ,  CLARK, Michael, C.

CPC分类号： C10G11/00 ,  B01J20/3408 ,  B01J29/7038 ,  C07C7/13 ,  C10G25/03 ,  C10G25/05 ,  C10G25/12 ,  C10G2300/1092 ,  C10G2300/1096 ,  C10G2400/02 ,  Y02P20/52 ,  C07C11/02

摘要： A process for the regeneration of materials used in the guard beds preceding the reactors used in an olefin conversion process which converts olefinic refinery streams to higher boiling hydrocarbon products by polymerization (oligomerization) or alkylation of aromatics including benzene. Products of the process may include olefin oligomers and alkylaromatics in the gasoline boiling range as well as alkylaromatic petrochemicals such as cumene and ethylbenzene. The process is integrated with the olefin conversion process to ensure continuous operation of the olefin conversion without sending the feedstock containing the contaminant(s) to the reactor. The process uses reaction products from the olefin conversion process to regenerate the guard bed material and so is economically attractive since it does not require the use of separate purge, regeneration feed and separation systems. A plurality of guard beds is used, each containing a material which removes catalyst poisons. The guard beds are operated on a swing system in which one or more beds is kept on stream to remove the contaminant(s) while one or more of the remaining beds is being purged or regenerated. In this way, continuity of operation is assured. The regeneration medium is a product stream from the olefin conversion process.

摘要翻译： 用于在用于烯烃转化方法的反应器之前的保护床中使用的材料的再生方法，其通过聚合（低聚）或包括苯在内的芳族化合物的烷基化将烯烃精炼料流转化成高沸点烃产物。 该方法的产物可以包括汽油沸程中的烯烃低聚物和烷基芳族化合物以及烷基芳族化学品如枯烯和乙苯。 该方法与烯烃转化方法结合以确保烯烃转化的连续操作，而不将含有污染物的原料送到反应器中。 该方法使用来自烯烃转化方法的反应产物来再生保护床材料，因此在经济上是有吸引力的，因为它不需要使用单独的吹扫，再生进料和分离系统。 使用多个保护床，每个保护床含有去除催化剂毒物的材料。 保护床在摆动系统上操作，其中一个或多个床被保持流动以除去污染物，同时一个或多个剩余的床被清除或再生。 以这种方式，确保操作的连续性。 再生介质是来自烯烃转化方法的产物流。

公开(公告)号：WO2017151326A1

公开(公告)日：2017-09-08

申请号：PCT/US2017/018263

申请日：2017-02-17

申请人： EXXONMOBIL RESEARCH AND ENGINEERING COMPANY

发明人： NOURI, Dana, W. ,  KORSTEN, Hans, G. ,  UMANSKY, Benjamin, S.

IPC分类号： B01J8/02

摘要： Systems and methods are provided for detecting abnormal temperature conditions within a fixed bed reactor. In a fixed bed reactor, a hydrocarbon (or hydrocarbon-like) feedstock can be exposed to one or more types of catalyst particles at elevated temperatures and/or pressures. In addition to the one or more types of catalyst particles, a plurality of temperature-sensor structures can be included in a catalyst bed and/or a coating including one or more temperature-sensor structures can be provided on an interior wall or other interior surface in the reactor. The temperature-sensor structures can have a threshold temperature at which the temperature-sensor structure changes to allow introduction and/or release of a detectable substance.

摘要翻译： 提供了用于检测固定床反应器内的异常温度条件的系统和方法。 在固定床反应器中，烃（或烃类）原料可以在升高的温度和/或压力下暴露于一种或多种类型的催化剂颗粒。 除了一种或多种类型的催化剂颗粒之外，可以在催化剂床中包括多个温度传感器结构和/或可以在内壁或其他内表面上提供包括一个或多个温度传感器结构的涂层 在反应堆中。 温度传感器结构可具有温度传感器结构改变以允许引入和/或释放可检测物质的阈值温度。