公开(公告)号：WO2015108781A1

公开(公告)日：2015-07-23

申请号：PCT/US2015/010832

申请日：2015-01-09

Applicant: GRAHAM PACKAGING COMPANY, L.P.

Inventor： AKKAPEDDI, Murali, K. ,  LYNCH, Brian, A.

IPC: C08G65/20 ,  C08G65/332 ,  C08G65/334

CPC classification number: C09K15/12 ,  B65D81/266 ,  B65D81/267 ,  C08G65/20 ,  C08G65/3322 ,  C08G65/3344 ,  C08G65/3346 ,  C08K5/098 ,  C08K5/42 ,  C08K2201/012 ,  C08L71/02 ,  C09K15/06 ,  C09K15/10

Abstract: The present invention provides an oxygen scavenging composition for incorporation into a wall of a package. The composition comprises a polyester base polymer, at least one oligomeric, oxidizable poly(alkylene ether) glycol-a,α, ω-diester having the formula (1) and at least one transition metal in a positive oxidation state. The compositions of the present invention do not exhibit an induction period prior to the onset of oxygen scavenging upon formation into a container.

Abstract translation: 本发明提供一种用于结合到包装壁中的除氧组合物。 该组合物包含聚酯基聚合物，至少一种具有式（1）的低聚，可氧化聚（亚烷基醚）二醇a，α，ω-二酯和至少一种正氧化态的过渡金属。 本发明的组合物在形成容器后在除氧之前不具有诱导期。

公开(公告)号：WO2019074924A1

公开(公告)日：2019-04-18

申请号：PCT/US2018/055012

申请日：2018-10-09

Applicant: GRAHAM PACKAGING COMPANY, L.P.

Inventor： AKKAPEDDI, Murali, K. ,  LYNCH, Brian, A.

IPC: C08K5/09

Abstract: The present invention provides a composition comprising: a polyester base polymer; an oxidizable polyether-based additive; a transition metal catalyst; a colorant; and a polyunsaturated fatty ester additives, wherein the polyester base polymer is substantially free of antimony and substantially free of phosphorous. Containers made from the composition are colored and exhibit excellent oxygen scavenging properties with no induction period.

公开(公告)号：WO2014022226A1

公开(公告)日：2014-02-06

申请号：PCT/US2013/052267

申请日：2013-07-26

Applicant: GRAHAM PACKAGING COMPANY, L.P.

Inventor： AKKAPEDDI, Murali, K.

IPC: C08G63/82 ,  C08K3/08 ,  C08F2/44

CPC classification number: B65D81/266 ,  B29D22/00 ,  B29D23/00 ,  B32B1/08 ,  B32B15/08 ,  B65D43/00 ,  C08F2/44 ,  C08G18/08 ,  C08G63/826 ,  C08K3/00 ,  C08K3/08 ,  C08K3/10 ,  C08K3/38 ,  C08K2201/003 ,  C08K2201/011 ,  Y10T428/1352 ,  Y10T428/1355 ,  C08L67/02

Abstract: A method of making a polymer composition comprising dispersed nanoparticles of an oxygen scavenging catalyst includes polymerizing one or more monomers or pre-polymers in the presence of a platinum group metal catalyst or precursor to obtain a polymer composition having dispersed nanoparticles of the platinum group metal. The oxygen scavenging catalyst is added during the polymerization as a solution of the platinum group metal or a compound thereof and a polyhydric alcohol (e.g., glycols). The food or beverage containers made from such polymer compositions exhibit high clarity and high oxygen scavenging properties.

Abstract translation: 制备包含除氧催化剂的分散纳米颗粒的聚合物组合物的方法包括在铂族金属催化剂或前体存在下聚合一种或多种单体或预聚物以获得具有铂族金属分散的纳米颗粒的聚合物组合物。 在聚合过程中加入氧清除催化剂作为铂族金属或其化合物和多元醇（例如二醇）的溶液。 由这种聚合物组合物制成的食品或饮料容器具有高透明度和高氧清除性能。

公开(公告)号：WO2018182824A1

公开(公告)日：2018-10-04

申请号：PCT/US2018/014226

申请日：2018-01-18

Applicant: GRAHAM PACKAGING COMPANY, L.P.

Inventor： AKKAPEDDI, Murali, K. ,  LYNCH, Brian, A.

IPC: C08L67/02 ,  B65D81/26

Abstract: A composition comprising: a polyester base polymer; a blend of two distinct polyether-based oxygen scavenging additives, OS1 and OS2, wherein each of OS1 and OS2 is selected from the group consisting of a polyether diol, an ester end-capped derivative of a polyether diol, a polyether-polyester block copolymer, and an ether end-capped derivative of a polyetherdiol, wherein OS1 has a molecular weight of from 10,000 to 100,000 and OS2 has a molecular weight of from 200 to 5,000; and a transition metal catalyst.

公开(公告)号：WO2011140473A1

公开(公告)日：2011-11-10

申请号：PCT/US2011/035570

申请日：2011-05-06

Applicant: GRAHAM PACKAGING COMPANY, L.P. ,  AKKAPEDDI, Murali, K. ,  LYNCH, Brian, A.

Inventor： AKKAPEDDI, Murali, K. ,  LYNCH, Brian, A.

IPC: C08K5/3445 ,  C08K3/00 ,  C08K3/10 ,  C08K5/20 ,  C08K5/3415 ,  C08L67/02

CPC classification number: C08K5/098 ,  C08K5/3415 ,  C08K5/3417 ,  C08K2201/012

Abstract: The present invention provides a composition comprising: a base polymer; at least one compound having the structure of Formula I or II, wherein Ar is an o-, m-, or p-phenylene moiety, a substituted phenylene moiety, or a naphthalene moiety; R 1 and R 2 are independently selected from the group consisting of: hydrogen, alkyl, alkenyl, and aryl; and X is O or -(CH 2 ) n -; n = 0, 1, or 2; and p = 0, 1, or 2; and; and at least one transition metal in a positive oxidation state, said metal being present in the composition in an amount of from about 10 to about 400 ppm, wherein said compound is present in an amount of from about 0.10 to about 10 weight percent of the composition.

Abstract translation: 本发明提供一种组合物，其包含：基础聚合物; 至少一种具有式I或II结构的化合物，其中Ar是邻 - ，间 - 或对 - 亚苯基部分，取代的亚苯基部分或萘部分; R 1和R 2独立地选自：氢，烷基，烯基和芳基; 且X为O或 - （CH 2）n - ; n = 0,1或2; 和p = 0,1或2; 和; 和至少一种正氧化态的过渡金属，所述金属以约10至约400ppm的量存在于所述组合物中，其中所述化合物的存在量为所述化合物的约0.10至约10重量％ 组成。

公开(公告)号：WO2020102205A1

公开(公告)日：2020-05-22

申请号：PCT/US2019/060936

申请日：2019-11-12

Applicant: GRAHAM PACKAGING COMPANY, L.P.

Inventor： AKKAPEDDI, Murali, K. ,  LYNCH, Brian, A.

IPC: C08L67/02

Abstract: A wall for a package comprising a composition wherein the composition comprises:a polyester base polymer; a polyolefin polymer; a functionalized polyolefin polymer selected from the group consisting of a maleic anhdride-grafted polypropylene, a maleic anhydride- grafted polypropylene adhesive resin, an acrylic acid-grafted polyproylene, a maleic anhydride-grafted styrene-ethylene-butylene-styrene copolymer, an ethylene-butyl acrylate- maleic anhydride terpolymer, an ethylene-butyl acrylate-glycidyl methacrylate terpolymer, an oxidized polyethylene wax, and mixtures thereof; an oxidizable polyether-based additive; and a transition metal catalyst.

公开(公告)号：WO2016123330A1

公开(公告)日：2016-08-04

申请号：PCT/US2016/015346

申请日：2016-01-28

Applicant: GRAHAM PACKAGING COMPANY, L.P.

Inventor： AKKAPEDDI, Murali, K. ,  LYNCH, Brian, A.

IPC: C08L67/00

CPC classification number: C08L67/02 ,  B65D81/266 ,  C08K3/24 ,  C08K5/0025 ,  C08K5/09 ,  C08L71/02

Abstract: The present invention provides a wall for a package comprising at least one layer, the layer comprising a composition, the composition comprising: a polyester base polymer; at least one polyether polyol at a concentration of from 0.3 to 0.7 wt. %; and at least one transition metal in a positive oxidation state, the metal being present in the composition in an amount of from 10 to 400 ppm.

Abstract translation: 本发明提供一种用于包装的壁，其包括至少一层，所述层包含组合物，所述组合物包含：聚酯基础聚合物; 至少一种浓度为0.3-0.7重量％的聚醚多元醇。 ％; 和至少一种正氧化态的过渡金属，该组合物中金属的存在量为10-400ppm。

公开(公告)号：WO2016073300A1

公开(公告)日：2016-05-12

申请号：PCT/US2015/058287

申请日：2015-10-30

Applicant: GRAHAM PACKAGING COMPANY, L.P.

Inventor： AKKAPEDDI, Murali, K. ,  LYNCH, Brian, A.

IPC: C08K5/103 ,  C08K5/12 ,  C08K5/098

CPC classification number: C08L67/02 ,  C08J5/18 ,  C08J2367/02 ,  C08J2467/02 ,  C08J2471/02 ,  C08K5/098 ,  C08K5/103 ,  C08K5/12

Abstract: The present invention provides a composition comprising: a polyester base polymer; an oxidizable polyether-based additive; and a transition metal catalyst, wherein the polyester base polymer is substantially free of antimony. Containers made include a wall made of the composition. The polyester base polymer may preferably include polyethylene terephthalate and include less than about 100 ppm of antimony, less than about 50 ppm, less than about 10 ppm, or between about 0 and about 2 ppm. Containers made from the composition are substantially clear and exhibit excellent oxygen scavenging properties with little to no induction period.

Abstract translation: 本发明提供一种组合物，其包含：聚酯基聚合物; 可氧化聚醚基添加剂; 和过渡金属催化剂，其中聚酯基础聚合物基本上不含锑。 制成的容器包括由该组合物制成的壁。 聚酯基础聚合物可以优选包括聚对苯二甲酸乙二醇酯，并且包括小于约100ppm的锑，小于约50ppm，小于约10ppm，或约0至约2ppm。 由组合物制成的容器基本上是透明的，并且具有优异的除氧性能，几乎没有诱导期。

公开(公告)号：WO2013172943A8

公开(公告)日：2013-11-21

申请号：PCT/US2013/030842

申请日：2013-03-13

Applicant: GRAHAM PACKAGING COMPANY, L.P.

Inventor： AKKAPEDDI, Murali, K. ,  LYNCH, Brian, A. ,  SCHNETZKA, Timothy

IPC: C08K5/00 ,  C08K3/08 ,  C08L67/02 ,  B65D81/26 ,  C08K5/10 ,  C08K5/20 ,  C09K3/10

Abstract: The present invention provides a composition comprising: a polyester base polymer; at least one non-polymeric oxidizable organic compound; at least one transition metal in a positive oxidation state, said metal being present in the composition in an amount of from about 10 to about 400 ppm, wherein the polyester base polymer comprises less than about 40 ppm phosphorous. The compositions of the present invention do not exhibit an induction period prior to the onset of oxygen scavenging upon formation into a container.

公开(公告)号：WO2012154379A1

公开(公告)日：2012-11-15

申请号：PCT/US2012/034235

申请日：2012-04-19

Applicant: GRAHAM PACKAGING COMPANY, L.P. ,  AKKAPEDDI, Murali, K. ,  LYNCH, Brian, A. ,  ZHONG, Yang

Inventor： AKKAPEDDI, Murali, K. ,  LYNCH, Brian, A. ,  ZHONG, Yang

IPC: C08K5/098 ,  C08K5/20 ,  C08L67/02 ,  C08K5/06 ,  C08K5/10

CPC classification number: C08L67/02 ,  C08K5/098 ,  C08K5/10 ,  C08K5/20 ,  C08K5/3415 ,  C08K5/3417 ,  C08K2201/012

Abstract: The present invention provides a composition comprising: a polyester base polymer; at least one non-polymeric oxidizable organic compound; at least one transition metal in a positive oxidation state, said metal being present in the composition in an amount of from about 10 to about 400 ppm; and at least one activator compound selected from the group consisting of: (i) a polyester ionomer containing a sulfoisophthalate moiety, (ii) a polyol derivative and (iii) a N-hydroxyimide, wherein the at least one non-polymeric oxidizable organic compound is present in an amount of from about 0.10 to about 10 weight percent of the composition, and wherein the at least one activator compound is present in an amount of from about 0.01 to about 5 weight percent of the composition. The compositions of the present invention do not exhibit an induction period prior to the onset of oxygen scavenging upon formation into a container.

Abstract translation: 本发明提供一种组合物，其包含：聚酯基聚合物; 至少一种非聚合的可氧化的有机化合物; 至少一种处于正氧化态的过渡金属，所述金属以约10至约400ppm的量存在于所述组合物中; 和至少一种选自以下的活化剂化合物：（i）含有磺基间苯二甲酸酯部分的聚酯离聚物，（ii）多元醇衍生物和（iii）N-羟基酰亚胺，其中所述至少一种非聚合可氧化有机化合物 以组合物的约0.10至约10重量％的量存在，并且其中所述至少一种活化剂化合物的存在量为组合物的约0.01至约5重量％。 本发明的组合物在形成容器后的氧清除开始之前不显示诱导期。