公开(公告)号：WO2011019528A2

公开(公告)日：2011-02-17

申请号：PCT/US2010/044064

申请日：2010-08-02

Applicant: HONEYWELL INTERNATIONAL INC. ,  WILLIAMS, David J. ,  GITTERE, Clifford P. ,  VAN DER PUY, Michael

Inventor： WILLIAMS, David J. ,  GITTERE, Clifford P. ,  VAN DER PUY, Michael

IPC: C08J9/14 ,  C08G18/18 ,  C08L75/04 ,  C08L23/28 ,  C08G101/00

CPC classification number: C08G18/1808 ,  C08G18/1816 ,  C08G2101/00 ,  C08G2101/005 ,  C08G2105/02 ,  C08J9/144 ,  C08J9/146 ,  C08J2375/04

Abstract: The invention provides foam forming methods that comprise: (a) preparing a foamable system comprising at least one hydrohaloolefin; and (b) ensuring either (i) the substantial absence of long-term decomposition-inducing contact between said hydrofluoroolefin and an amine-containing catalyst; (ii) that an effective amount of surfactant is available in the system under conditions which prevent long term exposure of the surfactant to a long-term decomposition reaction environment; or (iii) a combination of (i) and (ii). Related methods, foamable systems and foams are also disclosed. Preferred embodiments provide polyurethane and polyisocyanurate foams and methods for the preparation thereof, including closed-celled, polyurethane and polyisocyanurate foams and methods for their preparation. The preferred foams are characterized by a fine uniform cell structure and little or no foam collapse. The foams are preferably produced with a polyol premix composition which comprises a combination of a hydrohaloolefin blowing agent, a polyol, a silicone surfactant, a catalyst and is further characterized by being substantially free of added water.

Abstract translation: 本发明提供泡沫形成方法，其包括：（a）制备包含至少一种氢卤代烯烃的可发泡体系; 和（b）确保（i）所述氢氟烯烃和含胺催化剂之间基本上不存在长期分解诱导的接触; （ii）在防止表面活性剂长期暴露于长期分解反应环境的条件下，系统中可获得有效量的表面活性剂; 或（iii）（i）和（ii）的组合。 还公开了相关方法，可发泡体系和泡沫体。 优选的实施方案提供聚氨酯和聚异氰脲酸酯泡沫及其制备方法，包括闭孔，聚氨酯和聚异氰脲酸酯泡沫及其制备方法。 优选的泡沫的特征在于细小的均匀的细胞结构和很少或没有泡沫崩溃。 泡沫优选用多元醇预混合物组合物制备，该组合物包含氢卤烯烃发泡剂，多元醇，硅氧烷表面活性剂，催化剂的组合，并且其特征还在于基本上不含加水。

公开(公告)号：WO2014133986A1

公开(公告)日：2014-09-04

申请号：PCT/US2014/018142

申请日：2014-02-25

Applicant: HONEYWELL INTERNATIONAL INC.

Inventor： YU, Bin ,  WILLIAMS, David J.

IPC: C08G18/10 ,  C08G18/28 ,  C08J9/06 ,  C08K5/02

CPC classification number: C08J9/0057 ,  C08G18/22 ,  C08G18/227 ,  C08G2101/00 ,  C08J9/144 ,  C08J2201/022 ,  C08J2203/162 ,  C08J2375/04 ,  C08K5/02 ,  C08K5/098

Abstract: Disclosed are polyol premix compositions, and foams formed therefrom, which comprise a combination of a hydrohaloolefin blowing agent, a polyol, a silicone surfactant, and a catalyst system that includes a bismuth-based metal catalyst. Such catalysts may be used alone or in combination with an amine catalyst and/or other non-amine catalysts.

Abstract translation: 公开了多元醇预混物组合物和由其形成的泡沫，其包含氢卤烯烃发泡剂，多元醇，硅氧烷表面活性剂和包含铋基金属催化剂的催化剂体系的组合。 这样的催化剂可以单独使用或与胺催化剂和/或其它非胺催化剂组合使用。

公开(公告)号：WO2009067720A2

公开(公告)日：2009-05-28

申请号：PCT/US2008/084512

申请日：2008-11-24

Applicant: HONEYWELL INTERNATIONAL INC. ,  BOWMAN, James M. ,  WILLIAMS, David J.

Inventor： BOWMAN, James M. ,  WILLIAMS, David J.

IPC: C08J9/06 ,  C08K5/02 ,  C08J9/22 ,  C08J9/00 ,  C08K5/01

CPC classification number: C08J9/127 ,  B32B5/18 ,  C08F112/08 ,  C08G18/06 ,  C08J9/122 ,  C08J9/14 ,  C08J9/143 ,  C08J9/144 ,  C08J9/145 ,  C08J9/146 ,  C08J9/148 ,  C08J9/149 ,  C08J2203/06 ,  C08J2203/12 ,  C08J2203/14 ,  C08J2203/162 ,  C08J2207/04 ,  C08J2325/06 ,  C08J2375/04 ,  C08K5/02 ,  Y10T428/249989

Abstract: Disclosed are bowing agent compositions, foamable compositions, foams, foaming methods and/or foamed articles comprising one or more C2 to C6 fluoroalkenes, more preferably one or more C3 to C5 fluoroalkenes, and even more preferably one or more compounds having Formula I as follows: XCF z R 3-z (I) where X is a C 1 , C 2 , C 3 , C 4 , or C 5 unsaturated, substituted or unsubstituted radical, each R is independently Cl, F, Br, I or H, and z is 1 to 3, it generally being preferred that the fluoroalkene of the present invention has at least four (4) halogen substituents, at least three of which are F and even more preferably none of which are Br.

Abstract translation: 公开了包含一种或多种C2-C6氟代烯烃，更优选一种或多种C3-C5氟代烯烃，并且甚至更优选一种或多种C3-C5氟代烯烃的弯曲剂组合物，可发泡组合物，泡沫，发泡方法和/或发泡制品 或更多具有式I的化合物如下：其中X是C 1，C 1，C 3，C 4， 2，C 3，C 4或C 5不饱和，取代或未取代的基团，每个R独立地为Cl，F ，Br，I或H，z为1至3，通常优选的是本发明的氟代烯烃具有至少四个（4）卤素取代基，其中至少三个是F并且甚至更优选没有一个是 宽单峰

公开(公告)号：WO2014137969A1

公开(公告)日：2014-09-12

申请号：PCT/US2014/020100

申请日：2014-03-04

Applicant: HONEYWELL INTERNATIONAL INC.

Inventor： VAN DER PUY, Michael ,  WILLIAMS, David J.

IPC: C08J9/06 ,  C08G18/08 ,  C08G18/16 ,  C08G101/00

CPC classification number: C08G18/3206 ,  C08G18/14 ,  C08G18/1808 ,  C08G18/4816 ,  C08G2101/0008 ,  C08G2101/0016 ,  C08G2101/0025 ,  C08G2105/02 ,  C08J9/02 ,  C08J9/146 ,  C08J2201/022 ,  C08J2203/162 ,  C08J2375/04

Abstract: In certain non-limiting, aspects, the present invention relates to storage stable premixes of a polyol suitable for polyurethane or polyisocyanurate foam preparation having, at least, 1,1,1,4,4,4-hexafluoro-2-butene (1336mzzm) as the blowing agent and optional one or more additional additives and/or auxillary blowing agents in amounts suitable for polyurethane or polyisocyanurate foam preparation.

Abstract translation: 在某些非限制性方面，本发明涉及适用于具有至少1,1,1,4,4,4-六氟-2-丁烯（1336mzm）的聚氨酯或聚异氰脲酸酯泡沫制剂的多元醇的储存稳定的预混物 ）作为发泡剂和任选的一种或多种额外的添加剂和/或辅助发泡剂，其用量适用于聚氨酯或聚异氰脲酸酯泡沫制剂。

公开(公告)号：WO2014015315A1

公开(公告)日：2014-01-23

申请号：PCT/US2013/051391

申请日：2013-07-19

Applicant: HONEYWELL INTERNATIONAL INC.

Inventor： BOWMAN, James M. ,  WILLIAMS, David J.

IPC: C08J9/04 ,  C08J9/06 ,  B29C44/50 ,  C08L25/06 ,  C08K5/02

CPC classification number: B29C44/3442 ,  B29C44/50 ,  B29K2025/04 ,  B29L2031/00 ,  C08J9/144 ,  C08J9/146 ,  C08J2201/03 ,  C08J2203/162 ,  C08J2203/182 ,  C08J2325/06 ,  C08K5/02 ,  C08L25/06

Abstract: Disclosed are methods of forming an expanded polystyrene foam comprising: (a) providing a foamable resin comprising polystryrene and a blowing agent comprising (i) transHFO-1234ze and (ii) transHCFO-1233zd; and (b) extruding said foamable composition through a dye.

Abstract translation: 公开了形成发泡聚苯乙烯泡沫的方法，其包括：（a）提供包含聚苯乙烯的发泡树脂和发泡剂，其包含（i）反式HFO-1234ze和（ii）transHCFO-1233zd; 和（b）通过染料挤出所述可发泡组合物。

公开(公告)号：WO2013016632A2

公开(公告)日：2013-01-31

申请号：PCT/US2012/048538

申请日：2012-07-27

Applicant: HONEYWELL INTERNATIONAL INC. ,  BOGDAN, Mary C. ,  GITTERE, Clifford P. ,  HULSE, Ryan ,  ROSS, Michael A. ,  LING, Yiu Keung ,  WILLIAMS, David J.

Inventor： BOGDAN, Mary C. ,  GITTERE, Clifford P. ,  HULSE, Ryan ,  ROSS, Michael A. ,  LING, Yiu Keung ,  WILLIAMS, David J.

IPC: C09K21/08 ,  E04C2/02 ,  C09D5/18

CPC classification number: C08J9/06 ,  C08J9/146 ,  C08J2203/142 ,  C08J2203/162 ,  C08J2203/182 ,  C08J2375/04 ,  C08K5/02 ,  C09D5/18 ,  C09D7/48 ,  C09K21/14 ,  E04B1/942 ,  E04C2/205 ,  Y10T428/249954

Abstract: The present invention relates to building envelopes and methods of forming a building envelope comprising foams having a polymeric foam structure including a plurality of closed cells therein and trans-1-chloro-3,3,3-trifluoropropene (1233zd(E)) contained in at least a portion of said cells.

Abstract translation: 本发明涉及建筑围护结构和形成建筑围护结构的方法，所述建筑围护结构包括具有聚合物泡沫结构的泡沫，所述聚合物泡沫结构中包括多个闭孔，并且反式-1-氯-3,3,3-三氟丙烯 （1233zd（E））包含在至少一部分所述细胞中。

公开(公告)号：WO2012115936A2

公开(公告)日：2012-08-30

申请号：PCT/US2012/025884

申请日：2012-02-21

Applicant: HONEYWELL INTERNATIONAL INC. ,  ROSS, Michael ,  GROSSMAN, Ronald ,  WILLIAMS, David J. ,  GITTERE, Clifford P.

Inventor： ROSS, Michael ,  GROSSMAN, Ronald ,  WILLIAMS, David J. ,  GITTERE, Clifford P.

IPC: C08G18/06 ,  C08G18/16 ,  C08L75/04 ,  C08J9/06 ,  C08K5/02

CPC classification number: C08G18/163 ,  C08G18/092 ,  C08G18/14 ,  C08G18/1808 ,  C08G18/1816 ,  C08G18/2081 ,  C08G18/225 ,  C08G18/227 ,  C08G18/244 ,  C08G18/26 ,  C08G18/4018 ,  C08G18/4208 ,  C08G18/4804 ,  C08G18/5021 ,  C08G18/546 ,  C08G18/7664 ,  C08G2101/00 ,  C08G2101/0033 ,  C08G2105/02 ,  C08G2410/00 ,  C08J9/125 ,  C08J9/127 ,  C08J9/144 ,  C08J9/146 ,  C08J2203/10 ,  C08J2203/162 ,  C08J2203/182 ,  C08J2375/04 ,  C08J2375/08

Abstract: The invention provides polyurethane and polyisocyanurate foams and methods for the preparation thereof. More particularly, the invention relates to closed-celled, polyurethane and polyisocyanurate foams and methods for their preparation. The foams are characterized by a fine uniform cell structure and little or no foam collapse. The foams are produced with a polyol premix composition which comprises a combination of a hydrohaloolefin blowing agent, a polyol, a silicone surfactant, and a non-amine catalyst used alone or in combination with an amine catalyst.

Abstract translation: 本发明提供聚氨酯和聚异氰脲酸酯泡沫及其制备方法。 更具体地说，本发明涉及闭孔，聚氨酯和聚异氰脲酸酯泡沫及其制备方法。 泡沫的特征在于细小的均匀的细胞结构和很少或没有泡沫崩溃。 泡沫体是用多元醇预混物组合物生产的，该组合物包含氢卤烯烃发泡剂，多元醇，硅氧烷表面活性剂和单独使用或与胺催化剂组合使用的非胺催化剂的组合。

公开(公告)号：WO2012115929A2

公开(公告)日：2012-08-30

申请号：PCT/US2012/025869

申请日：2012-02-21

Applicant: HONEYWELL INTERNATIONAL INC. ,  WILLIAMS, David J. ,  BOGDAN, Mary C. ,  GITTERE, Clifford P. ,  POSS, Andrew J.

Inventor： WILLIAMS, David J. ,  BOGDAN, Mary C. ,  GITTERE, Clifford P. ,  POSS, Andrew J.

CPC classification number: C08G18/225 ,  C08G18/222 ,  C08G18/227 ,  C08G18/4018 ,  C08G18/5033 ,  C08G2101/0016 ,  C08G2101/0025 ,  C08G2101/0033 ,  C08J9/144 ,  C08J9/146 ,  C08J2201/022 ,  C08J2203/162 ,  C08J2207/04 ,  C08J2375/04

Abstract: The invention provides polyurethane and polyisocyanurate foams and methods for the preparation thereof. More particularly, the invention relates to closed-celled, polyurethane and polyisocyanurate foams and methods for their preparation. The foams are characterized by a fine uniform cell structure and little or no foam collapse. The foams are produced with a polyol premix composition which comprises a combination of a hydrohaloolefin blowing agent, a polyol, a silicone surfactant, and a non-amine catalyst used alone or in combination with an amine catalyst.

Abstract translation: 本发明提供聚氨酯和聚异氰脲酸酯泡沫及其制备方法。 更具体地说，本发明涉及闭孔，聚氨酯和聚异氰脲酸酯泡沫及其制备方法。 泡沫的特征在于细小的均匀的细胞结构和很少或没有泡沫崩溃。 泡沫体是用多元醇预混物组合物生产的，该组合物包含氢卤烯烃发泡剂，多元醇，硅氧烷表面活性剂和单独使用或与胺催化剂组合使用的非胺催化剂的组合。

公开(公告)号：WO2012024252A3

公开(公告)日：2012-02-23

申请号：PCT/US2011/047836

申请日：2011-08-16

Applicant: HONEYWELL INTERNATIONAL INC. ,  WILLIAMS, David J. ,  SINGH, Rajiv R. ,  BOWMAN, James M.

Inventor： WILLIAMS, David J. ,  SINGH, Rajiv R. ,  BOWMAN, James M.

IPC: C07C21/18 ,  C07C19/12 ,  C08J9/06 ,  C11D7/50 ,  C09K3/30

Abstract: The instant invention relates to compositions comprising a blend 1-chloro-3,3,3-trifluoropropene (HCFO 1233zd) and 1,1-dichloro-1-fluoroethane (HCFC 141b). In particular, the instant invention relates to blowing agents and foamable compositions containing at least such a blend, as well as solvents containing such a blend.

公开(公告)号：WO2012015865A2

公开(公告)日：2012-02-02

申请号：PCT/US2011/045455

申请日：2011-07-27

Applicant: HONEYWELL INTERNATIONAL INC. ,  BOWMAN, James M. ,  WILLIAMS, David J. ,  YANA MOTTA, Samuel F.

Inventor： BOWMAN, James M. ,  WILLIAMS, David J. ,  YANA MOTTA, Samuel F.

IPC: C09K5/04 ,  C09K5/00

CPC classification number: F16L59/028 ,  C08J9/127 ,  C08J9/149 ,  C08J2203/06 ,  C08J2203/12 ,  C08J2203/14 ,  C08J2203/142 ,  C08J2207/04 ,  C08K5/02 ,  C09K5/044 ,  C09K2205/122

Abstract: A heat transfer system and method for controlling heat transfer to and from a container having thermal insulation disposed with respect to said container or compartment so as to inhibit the flow of heat into and/or out of the compartment, said insulation comprising a polymeric material having closed cells therein wherein said cells are formed from and/or contain a haloalkene according to Formula IA: where each R is independently Cl, F, H, or CF 3 , provided that the total number of carbon atoms is either 3 or 4, R' is (CR 2 ) n Y, Y is CF 3 and n is 0 or 1; and a heat transfer system for adding and/or removing heat from the compartment or container by use of a heat transfer fluid comprising a haloalkene Formula IB: where each R is independently Cl, F or H R' is (CR 2 ) n Y, Y is CF 3 and n is 0 or 1.

Abstract translation: 传热系统和方法，用于控制往来于具有相对于所述容器或隔室布置的热绝缘的容器的热量传递，从而抑制热量流入和/或流出隔室 ，所述绝缘材料包含其中具有闭孔的聚合材料，其中所述孔由式IA的卤代烯烃形成和/或含有卤代烯烃：其中每个R独立地为Cl，F，H或CF 3， 条件是碳原子总数为3或4，R'为（CR2）nYY，Y为CF3和 n是0或1; 以及传热系统，用于通过使用包含卤代烯烃式IB的热传递流体来从隔室或容器添加和/或移除热量：其中每个R独立地是Cl，F或HR'是（CR 2） Y为CF 3，n为0或1。