公开(公告)号：WO1995030105A1

公开(公告)日：1995-11-09

申请号：PCT/US1995004562

申请日：1995-04-20

Applicant: ITT MANUFACTURING, ENTERPRISES, INC.

Inventor： ITT MANUFACTURING, ENTERPRISES, INC. ,  NOONE, David, L. ,  MITCHELL, Frank, L. ,  WENIG, Peter

IPC: F16L11/12

CPC classification number: F16L11/125 ,  B32B1/08 ,  B32B27/08 ,  B32B27/30 ,  B32B27/32 ,  B32B27/34 ,  F16L9/12 ,  F16L9/121 ,  F16L9/123 ,  F16L11/045 ,  F16L11/12 ,  F16L11/127 ,  F16L2011/047 ,  Y10S138/07

Abstract: An elongated multi-layer tubing (10) is disclosed for connection to a motor vehicle system to handle fluids containing hydrocarbons. The tubing includes a first layer (14) disposed radially innermost and having an inner surface capable of prolonged exposure to a fluid containing hydrocarbons and an outer surface spaced a first predetermined radial thickness from the inner surface, the first layer (14) consisting essentially of an extrudable, melt-processible thermoplastic. The tubing (10) also includes a second layer (16) having a second predetermined radial thickness at most equal to the thickness of the first layer (14). The second layer (16) is uniformly and homogeneously connected to or bonded to the first layer (14) and consists essentially of an extrudable, melt-processible thermoplastic capable of sufficiently permanent laminar adhesion with the first layer (14) to prevent delamination during a desired lifetime of the tubing. At least one of the first and second layers (14, 16) is resistant to permeation by hydrocarbons. The tubing (10) includes a third layer (12) having a third predetermined radial thickness greater than the thickness of the first layer (14). The third layer (12) is capable of sufficiently permanent laminar adhesion to the second layer (16) to prevent delamination during said desired lifetime of said tubing. The third layer (12) is uniformly and homogeneously connected to or bonded to the second layer (16) and consists essentially of an extrudable, melt-processible thermoplastic. At least one layer of the tubing (10) is capable of dissipating electrostatic energy in a range between about 10 to 10 Ohm/cm .

Abstract translation: 公开了一种用于连接到机动车辆系统以处理含有烃的流体的细长多层管道（10）。 管道包括径向最内部设置的第一层（14），并且具有能够延长暴露于含有烃的流体的内表面和与内表面隔开第一预定径向厚度的外表面，第一层（14）主要由 可挤出，可熔融加工的热塑性塑料。 管道（10）还包括具有至多等于第一层（14）的厚度的第二预定径向厚度的第二层（16）。 第二层（16）均匀且均匀地连接到第一层（14）上，或者与第一层（14）结合，并且基本上由能够与第一层（14）充分永久的层状粘合的可挤出的可熔融加工的热塑性塑料组成，以防止在 所需管道寿命。 第一和第二层（14,16）中的至少一个能够耐受烃的渗透。 管道（10）包括具有大于第一层（14）的厚度的第三预定径向厚度的第三层（12）。 第三层（12）能够对第二层（16）进行充分永久的层状粘合，以防止在所述管道的期望寿命期间的分层。 第三层（12）均匀均匀地连接到第二层（16）上或者结合到第二层（16）上，并且基本上由可挤出的可熔融加工的热塑性材料组成。 至少一层管道（10）能够在约10 -4至10 -9 Ohm / cm 2之间的范围内消散静电能。

公开(公告)号：WO1996013680A1

公开(公告)日：1996-05-09

申请号：PCT/US1995013570

申请日：1995-10-11

Applicant: ITT MANUFACTURING ENTERPRISES, INC.

Inventor： ITT MANUFACTURING ENTERPRISES, INC. ,  MITCHELL, Frank, L. ,  NOONE, David, L. ,  NIE, Tao

IPC: F16L09/12

CPC classification number: B32B1/08 ,  B32B7/12 ,  B32B15/04 ,  B32B25/04 ,  B32B25/08 ,  B32B27/08 ,  B32B27/30 ,  B32B27/304 ,  B32B27/32 ,  B32B27/34 ,  B32B27/40 ,  B32B37/153 ,  B32B2311/00 ,  B32B2311/04 ,  B32B2311/08 ,  B32B2311/12 ,  B32B2311/22 ,  B32B2313/04 ,  B32B2327/06 ,  B32B2327/12 ,  B32B2375/00 ,  B32B2597/00 ,  B32B2605/00 ,  F16L9/12 ,  F16L9/121 ,  F16L9/123 ,  F16L9/125 ,  F16L11/045 ,  F16L11/125 ,  F16L11/127 ,  F16L2011/047

Abstract: A layered tubing (10) for use in a motor vehicle composed of a thick outer layer (12) having an inner and an outer face, the outer layer (12) made of an extrudable thermoplastic elastomer; a thin intermediate bonding layer (14) bonded to the inner face of the thick outer layer (12), the bonding layer (14) composed of an extrudable melt-processible thermoplastic capable of sufficiently permanent laminar adhesion with the thick outer layer (12); an interior layer (16) bonded to the intermediate bonding layer (14), the interior layer (16) composed of a fluoroplastic which is resistant to permeation by and interaction with short-chain aliphatic and aromatic compounds; and an innermost electrostatic dissipation layer (18).

Abstract translation: 一种用于机动车辆的分层管道（10），其由具有内表面和外表面的厚的外层（12）组成，所述外层（12）由可挤出的热塑性弹性体制成; 结合到厚外层（12）的内表面的薄的中间粘合层（14），由能够与厚的外层（12）充分永久的层状粘合的可挤出的可熔融加工的热塑性塑料构成的粘接层（14） ; 结合到中间粘合层（14）的内层（16），由氟塑料组成的内层（16），其耐短纤维和芳族化合物的渗透和相互作用; 和最内侧的静电耗散层（18）。

公开(公告)号：WO1996021820A1

公开(公告)日：1996-07-18

申请号：PCT/US1996000467

申请日：1996-01-11

Applicant: ITT MANUFACTURING ENTERPRISES, INC.

Inventor： ITT MANUFACTURING ENTERPRISES, INC. ,  CHENEY, Craig ,  MITCHELL, Frank, L.

IPC: F16L11/12

CPC classification number: F16L11/12 ,  F16L9/12 ,  F16L9/121 ,  F16L2011/047

Abstract: An elongated fuel and vapor tube (10) suitable for conveying fluids containing hydrocarbons having a first layer (12) disposed radially innermost and having an inner surface capable of prolonged exposure to the hydrocarbon-containing fluid made up of a melt processible fluoroplastic terpolymer composed of a polyfluorinated alkylene, an alpha -fluoro-olefin and a fluorinated vinyl compound and a second layer bonded directly to the outwardly oriented face of the first layer. The second layer (14) is composed of a resinous thermoplastic material which is preferably a polyamide such as Nylon 12, Nylon 11, Nylon 6 or Nylon 6.6.

Abstract translation: 一种细长的燃料和蒸气管（10），其适于输送含有烃的流体，所述烃具有径向最内部设置的第一层（12），并且具有能够延长暴露于由可熔融加工的氟塑料三元共聚物组成的含烃流体的内表面 多氟化亚烷基，α-氟烯烃和氟化乙烯基化合物，以及直接结合到第一层向外取向面的第二层。 第二层（14）由优选为尼龙12，尼龙11，尼龙6或尼龙6.6的聚酰胺的树脂热塑性材料构成。

公开(公告)号：WO1995030109A1

公开(公告)日：1995-11-09

申请号：PCT/US1995005129

申请日：1995-04-25

Applicant: ITT MANUFACTURING ENTERPRISES, INC.

Inventor： ITT MANUFACTURING ENTERPRISES, INC. ,  IORIO, Ralph, A. ,  DAVIE, Robert, M. ,  McDANIEL, James, D. ,  MITCHELL, Frank, L. ,  NIE, Tao

IPC: F16L58/10

CPC classification number: B32B1/08 ,  B29C63/486 ,  B32B15/08 ,  B32B27/08 ,  B32B37/153 ,  B32B2311/20 ,  B32B2377/00 ,  B32B2597/00 ,  F16L9/147 ,  F16L58/1009 ,  F16L58/1045 ,  F16L58/109 ,  Y10S138/07

Abstract: A multi-layer tube (10) comprises a metal tube (12) having an outer surface (13) and a zinc layer (14) bonded to the metal tube outer surface (13), wherein the zinc layer (14) is selected from the group consisting of zinc plating, zinc nickel alloys, zinc cobalt alloys, zinc aluminum alloys, and mixtures thereof. A surface treatment layer (16) is bonded to the zinc layer (14), wherein the surface treatment layer (16) is selected from the group consisting of a zinz/aluminum/rare earth alloy, phosphate, chromate and mixtures thereof. A first polymeric layer (18) is bonded to the surface treatment layer (16), wherein the first polymeric layer (18) is selected from the group consisting of a thermoplastic elastomer, an ionomer, a nylon, a fluoropolymer, and mixtures thereof. A second polymeric layer (22) is bonded to the first polymeric layer (18), wherein the second polymeric layer (22) is selected from the group consisting of a nylon, a thermoplastic elastomer, a fluoropolymer, and mixtures thereof. A process for manufacturing a multi-layer tubing (10) for conveying fluids in a vehicle system comprises the step of extruding multiple layers of a melt-processible thermoplastic to a pretreated metal tube (12) having an external surface (13) with at least a zinc based coating (14) and a sealant coating on top of the zinc based coating (14).

Abstract translation: 多层管（10）包括金属管（12），其具有结合到金属管外表面（13）的外表面（13）和锌层（14），其中锌层（14）选自 由锌镀层，锌镍合金，锌钴合金，锌铝合金及其混合物组成的组。 表面处理层（16）结合到锌层（14）上，其中表面处理层（16）选自锌/铝/稀土合金，磷酸盐，铬酸盐及其混合物。 第一聚合物层（18）结合到表面处理层（16），其中第一聚合物层（18）选自热塑性弹性体，离聚物，尼龙，含氟聚合物及其混合物。 第二聚合物层（22）结合到第一聚合物层（18），其中第二聚合物层（22）选自尼龙，热塑性弹性体，含氟聚合物及其混合物。 一种用于制造用于在车辆系统中输送流体的多层管道（10）的方法包括将具有可熔融加工的热塑性塑料的多层挤出到具有至少具有外表面（13）的预处理金属管（12）的步骤 锌基涂层（14）和在锌基涂层（14）的顶部上的密封剂涂层。

公开(公告)号：WO1995027866A1

公开(公告)日：1995-10-19

申请号：PCT/US1995004427

申请日：1995-04-10

Applicant: ITT MANUFACTURING ENTERPRISES, INC.

Inventor： ITT MANUFACTURING ENTERPRISES, INC. ,  NOONE, David, L. ,  MITCHELL, Frank, L.

IPC: F16L09/12

CPC classification number: B29C47/0023 ,  B29C47/0033 ,  B29C47/0057 ,  B29C47/065 ,  B29C47/26 ,  B29L2023/005 ,  B32B1/08 ,  B32B27/08 ,  B32B27/30 ,  B32B27/32 ,  B32B27/34 ,  B32B27/36 ,  F02M25/08 ,  F02M37/0017 ,  F16L9/12 ,  F16L9/121 ,  F16L9/123 ,  F16L11/04 ,  F16L11/11 ,  F16L11/1185 ,  F16L11/125 ,  F16L2011/047 ,  Y10S138/01 ,  Y10S138/07

Abstract: A multi-layer tube (10) suitable for use on motor vehicles composed of a cylindrical wall having an outer surface, and an inner surface essentially parallel to the outer surface. The cylindrical wall has a first region (26) having an essentially uniform cross-sectional diameter and a second region (28) which has a cross-sectional diameter differing from the diameter of the first region (26). The second region (28) has at least one convolution or corrugation (30) contiguously adjacent to the cylindrical wall of the first region (26). The cylindrical wall is made up of a thick flexible outer layer (12) having an inner and an outer face, composed of an extrudable melt-processible thermoplastic; a thin intermediate bonding layer (16) bonded to the inner face of the thick outer layer (12), composed of an extrudable melt-processible thermoplastic capable of sufficiently permanent laminar adhesion to the outer layer to prevent delamination during the desired lifetime of the tubing; and an interior layer (14) composed of an extrudable melt-processable thermoplastic which is capable of sufficiently permanent laminar adhesion to the intermediate bonding layer (16) to prevent delamination of the tubing during the desired lifetime. The thermoplastic material in the interior layer has an elongation value at break of at least 150 % and an ability to withstand impacts of at least 2 foot-pounds below about -20 DEG C. The inner layer has a thickness less than the thickness of the outer layer.

Abstract translation: 一种适用于机动车辆的多层管（10），其由具有外表面的圆柱形壁和基本上平行于外表面的内表面组成。 圆柱形壁具有具有基本上均匀横截面直径的第一区域（26）和具有与第一区域（26）的直径不同的横截面直径的第二区域（28）。 第二区域（28）具有邻近第一区域（26）的圆柱形壁的至少一个卷积或波纹（30）。 圆柱形壁由具有内表面和外表面的厚的柔性外层（12）组成，该外表面由可挤出的可熔融加工的热塑性塑料构成; 结合到厚外层（12）的内表面的薄的中间粘合层（16），由可挤出的可熔融加工的热塑性材料构成，该热塑性塑料能够在外层具有足够的永久性层状粘合力，以防止管道期望寿命期间的分层 ; 以及由可挤出的可熔融加工的热塑性塑料组成的内层（14），其能够对中间粘合层（16）具有足够的永久性层状粘合，以防止在期望寿命期间管道的分层。 内层中的热塑性材料具有至少150％的断裂伸长率值和在约-20℃以下经受至少2英尺磅的冲击的能力。内层的厚度小于 外层。