液晶配向剤、液晶配向膜及び液晶素子

    公开(公告)号:WO2021070515A1

    公开(公告)日:2021-04-15

    申请号:PCT/JP2020/032937

    申请日:2020-08-31

    Abstract: 式(1)で表される化合物及び式(2)で表される化合物よりなる群から選択される少なくとも一種の単量体に由来する構造単位を有する重合体(A)を液晶配向剤に含有させる。式中、R1及びR2は、R1及びR2のうち一方が重合性基を有する1価の基であり、他方が水素原子若しくは1価の有機基であるか、又は、R1及びR2が互いに合わせられR1及びR2が結合する窒素原子と共に構成される環構造を表す。ただし、環構造は、重合性炭素-炭素不飽和結合を有する。A1は1価の有機基であり、A2は水酸基又は1価の有機基である。0≦n1+n2≦8を満たす。

    REACTIVE MULTI-ARM POLYMERS HAVING BRANCHED END GROUPS

    公开(公告)号:WO2021041234A1

    公开(公告)日:2021-03-04

    申请号:PCT/US2020/047450

    申请日:2020-08-21

    Abstract: In some aspects, the present disclosure pertains to a polymer that comprises a plurality of polymer arms, wherein a first portion of the polymer arms comprise a reactive end group and wherein a second portion of the polymer arms comprise a branched end group that comprise a plurality of covalently attached diagnostic and/or therapeutic groups, which may be, for example, radiocontrast groups or radioactive groups. Other aspects pertain to a system that comprises (a) a first composition comprising such a polymer and (b) a second composition comprising a multifunctional compound that comprises reactive functional groups that are reactive with the reactive end group of the multi-arm polymer. Still other aspects pertain to a crosslinked reaction product of (a) such a polymer and (b) a multifunctional compound that comprises functional groups that are reactive with the reactive end group of the multi-arm polymer.

    FUNCTIONALIZED (METH)ACRYLIC POLYMER OR COPOLYMER MACROPARTICULATES AND METHODS FOR PRODUCTION AND USE THEREOF

    公开(公告)号:WO2021007432A1

    公开(公告)日:2021-01-14

    申请号:PCT/US2020/041407

    申请日:2020-07-09

    Abstract: Macroparticulates may be formed through at least partial self-assembly by reacting an epoxide-containing (meth)acrylic polymer or copolymer with a compound bearing a nitrogen nucleophile, such as iminodiacetic acid or ethylenediamine. When the epoxide-containing (meth)acrylic polymer or copolymer is formed into a predetermined shape before reaction with the compound bearing the nitrogen nucleophile, a profile of the predetermined shape may be at least partially maintained and undergo expansion in the course of forming the reaction product, thereby producing macroparticulates having a larger volume than the predetermined shape itself. An internal cavity may be formed when generating the macroparticulates in this manner. Optionally, a hexasubstituted benzene or a supramolecular receptor may be adhered to a surface portion of the macroparticulates, either covalently or non-covalently. The compound bearing a nitrogen nucleophile may be further modified to form one or more functionalities capable of binding an analyte. Macroparticulates may be formed through at least partial self-assembly by reacting an epoxide-containing (meth)acrylic polymer or copolymer with a compound bearing a nitrogen nucleophile, such as iminodiacetic acid or ethylenediamine. When the epoxide-containing (meth)acrylic polymer or copolymer is formed into a predetermined shape before reaction with the compound bearing the nitrogen nucleophile, a profile of the predetermined shape may be at least partially maintained and undergo expansion in the course of forming the reaction product, thereby producing macroparticulates having a larger volume than the predetermined shape itself. An internal cavity may be formed when generating the macroparticulates in this manner. Optionally, a hexasubstituted benzene or a supramolecular receptor may be adhered to a surface portion of the macroparticulates, either covalently or non-covalently. The compound bearing a nitrogen nucleophile may be further modified to form one or more functionalities capable of binding an analyte.

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