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公开(公告)号:WO2019083846A1
公开(公告)日:2019-05-02
申请号:PCT/US2018/056727
申请日:2018-10-19
发明人: LEYSHON, David W.
CPC分类号: C07C1/22 , B01J21/16 , B01J29/85 , C07C1/20 , C07C1/24 , C07C4/06 , C07C2521/08 , C07C2521/16 , C07C2527/173 , C07C2529/40 , C07C2529/82 , C10G3/49 , C10G11/05 , C10G2400/20 , C07C11/04 , C07C11/06 , C07C11/08
摘要: Methods of producing at least one of ethylene and propylene. The methods may include contacting a mixture of C4+ compounds with a catalyst to convert at least a portion of the C4+ compounds to at least one of ethylene and propylene. The catalyst can include a phosphorus treated zeolite, and the mixture of C4+ compounds can include at least one of t-butyl alcohol and methyl t-butyl ether.
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公开(公告)号:WO2019152980A1
公开(公告)日:2019-08-08
申请号:PCT/US2019/016631
申请日:2019-02-05
发明人: ROSS-MEDGAARDEN, Elizabeth I. , LEYSHON, David W. , RUFENER, Karl P. , KONGKITISUPCHAI, Sunti , WOLFF, Richard J. , PETRY, Kimberly A.
IPC分类号: C07D301/32 , B01D3/32
CPC分类号: C07D301/32 , B01D3/008 , B01D3/143 , B01D3/40 , B01D3/4227
摘要: A propylene oxide separation system comprising a heavies distillation column configured to receive a crude propylene oxide stream and discharge a heavies purge bottoms comprising at least one impurity selected from acetone, methanol, aldehydes, aldehyde derivatives, water, heavy hydrocarbons comprising C 5+ , or combinations thereof, and discharge a heavies distillation column overhead stream comprising a majority of the propylene oxide entering with the crude propylene oxide stream, and a first extractive distillation column configured to receive the heavies distillation column overhead stream and a first extraction solvent stream comprising a hydrocarbon solvent, and discharge a lights purge overhead comprising at least one impurity selected from aldehydes (e.g., acetaldehyde, formaldehyde, etc.) methyl formate, methanol, water, C 3 hydrocarbons, C 4 hydrocarbons, or combinations thereof, and discharge a rich solvent bottoms stream comprising a majority of the propylene oxide entering via the heavies distillation column overhead stream. A propylene oxide purification method is also provided.
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