公开(公告)号：WO2019070667A1

公开(公告)日：2019-04-11

申请号：PCT/US2018/053911

申请日：2018-10-02

Applicant: MASSACHUSETTS INSTITUTE OF TECHNOLOGY

Inventor： HATTON, T., Alan ,  SHAW, Ryan, Alex ,  WANG, Miao ,  VOSKIAN, Sahag

IPC: H01M8/0668 ,  B01D53/62

CPC classification number: B01D53/1475 ,  B01D53/22 ,  B01D53/228 ,  B01D53/965 ,  B01D61/422 ,  B01D63/02 ,  B01D63/08 ,  B01D71/16 ,  B01D71/34 ,  B01D71/68 ,  B01D2053/224 ,  B01D2252/2041 ,  B01D2257/504

Abstract: Systems and methods for at least partially removing carbon dioxide (CO 2 ) from a feed gas comprising CO 2 are generally provided.

公开(公告)号：WO2017083822A1

公开(公告)日：2017-05-18

申请号：PCT/US2016/061836

申请日：2016-11-14

Applicant: MASSACHUSETTS INSTITUTE OF TECHNOLOGY

Inventor： BAI, Peng ,  BAZANT, Martin Z. ,  BRUSHETT, Fikile R. ,  HAN, Jihyung ,  WANG, Miao

IPC: H01M4/02 ,  B01D61/42 ,  B81B7/00 ,  B81C1/00 ,  G06F19/00

CPC classification number: B01D69/12 ,  B01D67/0088 ,  B01D2313/345 ,  B01D2325/14 ,  B01D2325/16 ,  B01D2325/42 ,  C25D1/006 ,  H01M4/02 ,  H01M4/13 ,  H01M4/366

Abstract: Surface conduction in porous media can drastically alter the stability and morphology of electrodeposition at high rates, above the diffusion-limited current. Above the limiting current, surface conduction inhibits growth in the positive membrane and produces irregular dendrites, while it enhances growth and suppresses dendrites behind a deionization shock in the negative membrane. The discovery of uniform growth contradicts quasi-steady "leaky membrane" models, which are in the same universality class as unstable Laplacian growth, and indicates the importance of transient electro-diffusion or electro-osmotic dispersion. Shock electrodeposition could be exploited for high-rate recharging of metal batteries or manufacturing of metal matrix composite coatings.

Abstract translation: 多孔介质中的表面传导可以在扩散限制电流以上以高速率急剧改变电沉积的稳定性和形态。 在极限电流以上，表面传导抑制正膜中的生长并产生不规则的树枝状晶体，同时其增强生长并抑制负膜中去离子冲击后的树枝状晶体。 均匀生长的发现与准稳定的“渗漏膜” 模型与不稳定拉普拉斯增长具有相同的通用类，并且表明了瞬态电扩散或电渗透扩散的重要性。 冲击电沉积可用于金属电池的高速再充电或金属基复合材料涂层的制造。