公开(公告)号：WO1996033151A1

公开(公告)日：1996-10-24

申请号：PCT/US1995006254

申请日：1995-06-06

Applicant: MOBIL OIL CORPORATION

Inventor： MOBIL OIL CORPORATION ,  AGASKAR, Pradyot, Adwaitanand ,  GRASSELLI, Robert, Karl ,  MICHAELS, James, Nathaniel ,  REISCHMAN, Paul, Thomas ,  STERN, David, Lawrence ,  TSIKOYIANNIS, John, George

IPC: C07C05/333

CPC classification number: C07C5/42 ,  C07C2523/42 ,  C07C2523/44 ,  C07C11/02

Abstract: A process for the net catalytic oxidative dehydrogenation of alkanes to produce alkenes is provided. The process involves simultaneous equilibrium dehydrogenation of alkanes to alkenes and combustion of the hydrogen formed to drive the equilibrium dehydrogenation reaction further to the product alkenes. In the present reaction, the alkane feed is passed into a reactor containing both an equilibrium dehydrogenation catalyst and a reducible metal oxide, whereby the alkane is dehydrogenated and the hydrogen produced is simultaneously and selectively conbusted in oxidation/reduction (REDOX) reaction with the reducible metal oxide. This particular mode of operation is termed a same reactor, REDOX mode. The equilibrium dehydrogenation catalyst may comprise platinum and the reducible metal oxide may contain bismuth, antimony, indium, or molybdenum, or a mixture thereof.

Abstract translation: 提供了一种用于烷烃净催化氧化脱氢制备烯烃的方法。 该方法包括将烷烃同时平衡脱氢至烯烃，形成氢气的燃烧以进一步促进产物烯烃的平衡脱氢反应。 在本反应中，将烷烃进料送入含有平衡脱氢催化剂和可还原金属氧化物的反应器中，由此烷烃脱氢，产生的氢气同时选择性地与可还原的氧化还原（REDOX）反应 金属氧化物。 这种特定的操作模式称为相同的反应器，REDOX模式。 平衡脱氢催化剂可以包含铂，可还原的金属氧化物可以含有铋，锑，铟或钼，或其混合物。

公开(公告)号：WO1996033150A1

公开(公告)日：1996-10-24

申请号：PCT/US1995005975

申请日：1995-05-17

Applicant: MOBIL OIL CORPORATION

Inventor： MOBIL OIL CORPORATION ,  AGASKAR, Pradyot, Adwaitanand ,  GRASSELLI, Robert, Karl ,  MICHAELS, James, Nathaniel ,  REISCHMAN, Paul, Thomas ,  STERN, David, Lawrence ,  TSIKOYIANNIS, John, George

IPC: C07C05/333

CPC classification number: C07C5/3337 ,  C07C2529/44 ,  C07C11/02

Abstract: A process for the net catalytic oxidative dehydrogenation of alkanes to produce alkenes is provided. The process involves simultaneous equilibrium dehydrogenation of alkanes to alkenes and combustion of the hydrogen formed to drive the equilibrium dehydrogenation reaction further to the product alkenes. In the present reaction, the alkane feed is dehydrogenated over an equilibrium dehydrogenation catalyst in a first reactor (110) and the effluent, along with oxygen is then passed into the second reactor (120) containing a metal oxide catalyst which serves to selectively catalyze the combustion of hydrogen. The equilibrium dehydrogenation catalyst may comprise platinum and the selective metal oxide combustion catalyst may contain bismuth, antimony, indium, or molybdenum, or a mixture thereof.

Abstract translation: 提供了烷烃净催化氧化脱氢制备烯烃的方法。 该方法包括将烷烃同时平衡脱氢至烯烃，形成氢气的燃烧以进一步促进产物烯烃的平衡脱氢反应。 在本反应中，烷烃进料在第一反应器（110）中通过平衡脱氢催化剂脱氢，然后将流出物与氧一起进入含有金属氧化物催化剂的第二反应器（120），第二反应器（120）用于选择性催化 燃烧氢气。 平衡脱氢催化剂可以包含铂，并且选择性金属氧化物燃烧催化剂可以含有铋，锑，铟或钼，或其混合物。

公开(公告)号：WO1997023435A1

公开(公告)日：1997-07-03

申请号：PCT/US1996019760

申请日：1996-12-11

Applicant: MOBIL OIL CORPORATION

Inventor： MOBIL OIL CORPORATION ,  BECK, Jeffrey, Scott ,  STERN, David, Lawrence

IPC: C07C05/52

CPC classification number: C07C6/123 ,  B01J2229/12 ,  B01J2229/32 ,  C07C2529/40

Abstract: A process for shape-selective hydrocarbon conversion involves initially contacting a feedstream, which includes an alkylaromatic compound and a co-feed of water, under conversion conditions with a catalytic molecular sieve. Preferably, the catalytic molecular sieve has been modified by being ex situ selectivated with a silicon compound. After an effective amount of time, the water co-feed is omitted from the feedstream and the hydrocarbon conversion process is continued.

Abstract translation: 用于形状选择性烃转化的方法包括在转化条件下与催化分子筛接触包括烷基芳族化合物和水的共同进料的进料流。 优选地，通过用硅化合物进行异地选择来修饰催化分子筛。 在有效的时间之后，从进料流中省去水共同进料，继续进行烃转化过程。

公开(公告)号：WO1996033152A1

公开(公告)日：1996-10-24

申请号：PCT/US1995007088

申请日：1995-06-05

Applicant: MOBIL OIL CORPORATION

Inventor： MOBIL OIL CORPORATION ,  AGASKAR, Pradyot, Adwaitanand ,  GRASSELLI, Robert, Karl ,  MICHAELS, James, Nathaniel ,  REISCHMAN, Paul, Thomas ,  STERN, David, Lawrence ,  TSIKOYIANNIS, John, George

IPC: C07C05/333

CPC classification number: C07C5/48 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2523/08 ,  C07C2523/10 ,  C07C2523/14 ,  C07C2523/18 ,  C07C2523/28 ,  C07C2523/30 ,  C07C2523/42 ,  C07C2527/14 ,  C07C11/02

Abstract: A process for the net catalytic oxidative dehydrogenation of alkanes to produce alkenes is provided. The process involves simultaneous equilibrium dehydrogenation of alkanes to alkenes and combustion of the hydrogen formed to drive the equilibrium dehydrogenation reaction further to the product alkenes. In the present reaction, the alkane feed is passed, along with oxygen, into a reactor containing both an equilibrium dehydrogenation catalyst and a selective metal oxide combustion catalyst, whereby the alkane is dehydrogenated and the hydrogen produced is simultaneously and selectively combusted. This particular mode of operation is termed a same reactor, cofed oxygen mode. The equilibrium dehydrogenation catalyst may comprise platinum, and the selective metal oxide combustion catalyst may contain bismuth, antimony, indium, or molybdenum, or a mixture thereof.

Abstract translation: 提供了一种用于烷烃净催化氧化脱氢制备烯烃的方法。 该方法包括将烷烃同时平衡脱氢至烯烃，形成氢气的燃烧以进一步促进产物烯烃的平衡脱氢反应。 在本反应中，烷烃进料与氧一起通入含有平衡脱氢催化剂和选择性金属氧化物燃烧催化剂的反应器中，由此使烷烃脱氢，同时选择性地燃烧产生的氢气。 这种特定的操作模式被称为相同的反应器，共模氧模式。 平衡脱氢催化剂可以包含铂，并且选择性金属氧化物燃烧催化剂可以含有铋，锑，铟或钼或其混合物。

公开(公告)号：WO1996033145A1

公开(公告)日：1996-10-24

申请号：PCT/US1995006247

申请日：1995-05-17

Applicant: MOBIL OIL CORPORATION

Inventor： MOBIL OIL CORPORATION ,  AGASKAR, Pradyot, Adwaitanand ,  GRASSELLI, Robert, Karl ,  MICHAELS, James, Nathaniel ,  REISCHMAN, Paul, Thomas ,  STERN, David, Lawrence ,  TSIKOYIANNIS, John, George

IPC: C07C01/00

CPC classification number: C07C5/3335 ,  C07C5/3337 ,  C07C5/42 ,  C07C2529/44 ,  C07C11/02

Abstract: There is provided a process for the net catalytic oxidative dehydrogenation of alkanes to produce alkenes. The process involves simultaneous equilibrium dehydrogenation of alkanes to alkenes and combustion of the hydrogen formed to drive the equilibrium dehydrogenation reaction further to the product alkenes. In the present reaction, the alkane feed is dehydrogenated over an equilibrium dehydrogenation catalyst in a first reactor, and the effluent from the first reactor is then passed into a second reactor containing a reducible metal oxide which serves to selectively combust hydrogen in an oxidation/reduction (REDOX) reaction. This particular mode of operation is termed a separate reactor, REDOX mode.

Abstract translation: 提供了用于烷烃的净催化氧化脱氢以产生烯烃的方法。 该方法包括将烷烃同时平衡脱氢至烯烃，形成氢气的燃烧以进一步促进产物烯烃的平衡脱氢反应。 在本反应中，烷烃进料在第一反应器中通过平衡脱氢催化剂脱氢，然后将来自第一反应器的流出物进入含有还原性金属氧化物的第二反应器，其用于选择性地在氧化/还原中燃烧氢 （REDOX）反应。 这种特定的操作模式被称为单独的反应器，REDOX模式。

公开(公告)号：WO1996016005A1

公开(公告)日：1996-05-30

申请号：PCT/US1995016006

申请日：1995-11-16

Applicant: MOBIL OIL CORPORATION

Inventor： MOBIL OIL CORPORATION ,  ABICHANDANI, Jeevan, Sahib ,  BECK, Jeffrey, Scott ,  BUNDENS, Robert, Glenn ,  BRECKENRIDGE, Lloyd, Lee ,  OLSON, David, Harold ,  REISCHMAN, Paul, Thomas ,  STERN, David, Lawrence ,  VENKAT, Chaya, Rao

IPC: C07C05/22

CPC classification number: C07C15/08 ,  B01J29/44 ,  B01J29/65 ,  B01J29/70 ,  B01J2229/12 ,  B01J2229/42 ,  C07C4/18 ,  C07C5/2708 ,  C07C15/00 ,  C07C15/067 ,  C07C2529/06 ,  C07C2529/40 ,  C07C2529/65 ,  C07C2529/70 ,  Y02P20/52 ,  C07C15/04

Abstract: A mixture of aromatic hydrocarbons, comprising ethylbenzene and at least one xylene, is isomerized using a two component catalyst system to convert the ethylbenzene to compounds that may be removed from the aromatic hydrocarbon stream and to produce a product stream wherein the para-xylene concentration is approximately equal to the equilibrium ratio of the para-isomer. The first catalyst comprises an intermediate pore size zeolite that is effective for ethylbenzene conversion. The first catalyst is preferably silica-bound. The second catalyst comprises an intermediate pore size zeolite, which further has a small crystal size and which is effective to catalyze xylene isomerization. Each of the catalysts of this invention may contain one or more hydrogenation/dehydrogenation component.

Abstract translation: 使用双组分催化剂体系将包含乙苯和至少一种二甲苯的芳族烃混合物转化成可将乙苯转化成可从芳族烃流中除去的化合物，并产生产物流，其中对二甲苯浓度为 大约等于对位异构体的平衡比。 第一种催化剂包括对乙苯转化有效的中等孔径的沸石。 第一催化剂优选是二氧化硅结合的。 第二种催化剂包括中等孔径的沸石，其进一步具有小的晶体尺寸并且有效催化二甲苯异构化。 本发明的每种催化剂可以含有一种或多种氢化/脱氢组分。

公开(公告)号：WO1995003262A1

公开(公告)日：1995-02-02

申请号：PCT/US1994008131

申请日：1994-07-19

Applicant: MOBIL OIL CORPORATION

Inventor： MOBIL OIL CORPORATION ,  BASTIAN, Roy, Daniel ,  CHANG, Clarence, Dayton ,  HAN, Scott ,  SANTIESTEBAN, Jose, Guadalupe ,  STERN, David, Lawrence

IPC: C07C05/27

CPC classification number: C07C5/226 ,  C07C5/13 ,  C07C2521/06 ,  C07C2523/14 ,  C07C2523/42 ,  C07C2523/62 ,  C07C9/00

Abstract: The process comprises the ring-opening of aromatics and isomerization of aliphatics. The feedstream (10) comprises hydrocarbons having 6 carbon atoms. The process involves the use of a recycle stream (62) containing a source of chlorine. The process uses two reactors in series wherein the first reactor (20) contains a ring-opening catalyst while the second reactor (40), downstream of the first reactor, contains an isomerization catalyst wherein aliphatics are isomerized.

Abstract translation: 该方法包括芳族化合物的开环和脂肪族异构化。 进料流（10）包含具有6个碳原子的烃。 该方法包括使用含有氯源的再循环流（62）。 该方法使用串联的两个反应器，其中第一反应器（20）含有开环催化剂，而第一反应器下游的第二反应器（40）含有异构化催化剂，其中脂族化合物异构化。

公开(公告)号：WO1993021107A1

公开(公告)日：1993-10-28

申请号：PCT/US1993003534

申请日：1993-04-14

Applicant: MOBIL OIL CORPORATION

Inventor： MOBIL OIL CORPORATION ,  BUCHANAN, John, Scott ,  IYENGAR, Jagannathan, Nambi ,  SODOMIN, Joseph, Frank ,  STERN, David, Lawrence ,  TEITMAN, Gerald, Joseph

IPC: C01B17/00

CPC classification number: C01B17/0408 ,  B01D53/508 ,  B01D53/52 ,  B01D53/523 ,  B01D53/8609 ,  B01D53/8637 ,  C01B17/0456 ,  C01B17/0473

Abstract: A method and apparatus for removing sulphur from a gas stream containing at least one sulphur compound, comprising cumbusting said gas stream with an oxygen containing gas in an incinerator (10) to convert the or each sulphur compound to at least one sulphur oxide. A gas stream is then withdrawn from the incinerator, which contains the or each sulphur oxide. The sulphur oxide containing gas stream is then directed to an absorber (12) having an absorbent bed adapted to remove sulphur compounds. The absorbent bed is then contacted with a hydrogen and/or hydrocarbon containing stream to regenerate said absorbent bed by reducing the sulphur compounds absorbed in said absorbent bed to hydrogen sulphide and/or sulphur dioxide, and thereby forming off gas stream containing hydrogen sulphide and/or sulphur dioxide. Finally, sulphur is recovered from said hydrogen sulphide and/or sulphur dioxide bearing stream. The sulphur can be recovered by a Claus sulphur recovery process (16). The hydrogen sulphide containing gas stream can be ammonia acid gas stream, thereby causing N2 to be formed in the incinerator. The N2 is not absorbed in the absorbent bed.

Abstract translation: 一种用于从含有至少一种硫化合物的气流中除去硫的方法和装置，其包括在焚烧炉（10）中用含氧气体将所述气流与所述硫化合物或每种硫化合物转化为至少一种硫氧化物。 然后从包含该硫氧化物或每种硫氧化物的焚化炉中取出气流。 然后将含硫氧化物气流引导至具有适于除去硫化合物的吸收剂床的吸收器（12）。 然后使吸收剂床与含氢和/或烃的物流接触以通过将吸收床中吸收的硫化合物还原成硫化氢和/或二氧化硫来再生所述吸收剂床，从而形成含有硫化氢和/ 或二氧化硫。 最后，从所述硫化氢和/或含二氧化硫的流中回收硫。 硫可以通过克劳斯硫回收方法回收（16）。 含有硫化氢的气流可以是氨酸气流，从而在焚化炉中形成N 2。 吸收剂床不吸收N2。