公开(公告)号：WO2012102764A1

公开(公告)日：2012-08-02

申请号：PCT/US2011/052248

申请日：2011-09-20

Applicant: PPG INDUSTRIES OHIO, INC.

Inventor： KABAGAMBE, Benjamin ,  MCCAMY, James W. ,  BOYD, Donald W.

IPC: C25D13/12 ,  C25D13/22 ,  F16B2/06

CPC classification number: C25D13/22 ,  C25D13/12 ,  F16B2/10

Abstract: A protective coating is applied to the electrically conductive surface of a reflective coating of a solar mirror by biasing a conductive member having a layer of a malleable electrically conductive material, e.g. a paste, against a portion of the conductive surface while moving an electrodepositable coating composition over the conductive surface. The moving of the electrodepositable coating composition over the conductive surface includes moving the solar mirror through a flow curtain of the electrodepositable coating composition and submerging the solar mirror in a pool of the electrodepositable coating composition. The use of the layer of a malleable electrically conductive material between the conductive member and the conductive surface compensates for irregularities in the conductive surface being contacted during the coating process thereby reducing the current density at the electrical contact area.

Abstract translation: 通过偏置具有可延展导电材料层的导电构件（例如，导电构件），将保护涂层施加到太阳能反射镜的反射涂层的导电表面。 在导电表面上移动可电沉积涂料组合物时，将其粘贴到导电表面的一部分上。 可电沉积涂料组合物在导电表面上的移动包括通过可电沉积涂料组合物的流动幕移动太阳镜，并将太阳镜浸没在可电沉积涂料组合物的池中。 在导电构件和导电表面之间使用可延展的导电材料层补偿了在涂覆过程期间接触的导电表面中的不规则性，从而降低了电接触区域处的电流密度。

公开(公告)号：WO2013106312A2

公开(公告)日：2013-07-18

申请号：PCT/US2013/020647

申请日：2013-01-08

Applicant: PPG INDUSTRIES OHIO, INC.

Inventor： GANJOO, Ashtosh ,  HASKINS, David R. ,  MCCAMY, James W. ,  NELIS, Gary J. ,  TAUSCH, Peter

IPC: C03C17/245 ,  H01B1/08 ,  H01L31/0224 ,  H05B33/06

CPC classification number: H01L31/022425 ,  C03C17/2453 ,  C03C17/3417 ,  C03C17/3671 ,  C03C17/3678 ,  C03C2217/734 ,  C03C2217/94 ,  C03C2218/152 ,  C03C2218/156 ,  C03C2218/365 ,  H01B1/08 ,  H01L31/022466 ,  H01L31/022475 ,  H01L51/5206 ,  H05B33/06 ,  Y10T428/24942 ,  Y10T428/265

Abstract: A glass sheet has an electrically conductive film having a sheet resistance in the range of 9.5 to 14.0 ohms/square; an emissivity in the range of 0.14 to 0.17 and an absorption coefficient of greater than 1.5 x10 3 cm -1 in the wavelength range of 400-1100 nanometers, and a surface roughness of less than 15 nanometers Root Means Square. A glass sheet of another embodiment of the invention has an electrically conductive film having a phosphorous-fluorine doped tin oxide pyrolytically deposited film on the surface of the glass sheet, wherein the ratio of phosphorous precursor to tin precursor is in the range of greater than 0-0.4. The coated glass sheets of the invention can be used in the manufacture of multi sheet insulating units, OLEDs and solar cells.

Abstract translation: 玻璃板具有导电膜，其具有在9.5至14.0欧姆/平方范围内的薄层电阻; 在波长400-1100纳米范围内的发射率在0.14-0.17范围内和大于1.5×10 -3 cm -1的吸收系数，并且表面粗糙度 小于15纳米的根指平方米。 本发明另一实施方案的玻璃板具有导电膜，在玻璃板的表面上具有磷 - 氟掺杂的氧化锡热解沉积膜，其中磷前体与锡前体的比率在大于0的范围内 -0.4。 本发明的涂覆的玻璃板可以用于制造多片绝缘单元，OLED和太阳能电池。

公开(公告)号：WO2011139523A2

公开(公告)日：2011-11-10

申请号：PCT/US2011/032645

申请日：2011-04-15

Applicant: PPG INDUSTRIES OHIO, INC.

Inventor： LU, Songwei ,  MCCAMY, James W. ,  FINLEY, James J.

IPC: C03C17/00

CPC classification number: C03C17/3417 ,  C03C17/002 ,  C03C17/2456 ,  C03C17/256 ,  C03C2217/212 ,  C03C2217/218 ,  C03C2217/24 ,  C03C2217/94 ,  C03C2218/112 ,  C03C2218/152

Abstract: A coated article includes a pyrolytic applied transparent electrically conductive oxide film of niobium doped titanium oxide. The article can be made by using a coating mixture having a niobium precursor and a titanium precursor. The coating mixture is directed toward a heated substrate to decompose the coating mixture and to deposit a transparent electrically conductive niobium doped titanium oxide film on the surface of the heated substrate. In one embodiment of the invention, the method is practiced using a vaporized coating mixture including a vaporized niobium precursor; a vaporized titanium precursor, and a carrier gas to deposit a niobium doped titanium oxide film having a sheet resistance greater than 1.2 and an index of refraction of 2.3 or greater. The chemical formula for the niobium doped titanium oxide is Nb:TiO X where X is in the range of 1.8-2.1.

Abstract translation: 涂覆制品包括掺铌掺杂的氧化钛的热解涂覆的透明导电氧化物膜。 该制品可以通过使用具有铌前体和钛前体的涂料混合物来制备。 涂层混合物指向加热的基底以分解涂层混合物并在被加热的基底的表面上沉积透明导电的掺铌的氧化钛膜。 在本发明的一个实施方案中，该方法是使用包括蒸发的铌前体的蒸发涂层混合物来实施的; 蒸发的钛前体和载气，以沉积具有大于1.2的薄层电阻并且折射率为2.3或更大的掺铌氧化钛膜。 掺杂铌的氧化钛的化学式是Nb：TiOX，其中X在1.8-2.1的范围内。

公开(公告)号：WO2011041030A1

公开(公告)日：2011-04-07

申请号：PCT/US2010/045562

申请日：2010-08-16

Applicant: PPG INDUSTRIES OHIO, INC.

Inventor： MCCAMY, James W. ,  SOPKO, John F.

IPC: C23C16/44 ,  C23C16/455 ,  C23C16/54

CPC classification number: C23C16/4401 ,  C23C16/4412 ,  C23C16/45502 ,  C23C16/45563 ,  C23C16/45578 ,  C23C16/45587 ,  C23C16/54

Abstract: A coating apparatus includes non-orthogonal coater geometry to improve coatings on a glass ribbon, and to improve yields of such coatings. The apparatus includes a first arrangement to move the ribbon along a first imaginary straight line (23) through a coating zone provided in a glass forming chamber. The coater has a coating nozzle (80) and an exhaust slot, (83) each have a longitudinal axis. The coating nozzle (80) directs coating vapors toward the coating zone, and the exhaust slot (82) removes vapors from the coating zone. A second arrangement mounts the coater in spaced relation to the path with the coating nozzle (80) and the exhaust slot (82) facing the coating zone. A second imaginary straight line (94) is normal to the longitudinal axis of the coating nozzle (80), and the first imaginary line (23) and the second imaginary line (94) suspend an angle in the range of greater than zero degrees to 90 degrees.

Abstract translation: 涂覆设备包括非正交涂布机几何形状以改善玻璃带上的涂层，并提高这种涂层的产量。 该装置包括第一装置，用于沿着第一假想直线（23）移动带子，穿过设置在玻璃形成室中的涂层区域。 涂布机具有涂覆喷嘴（80）和排气狭槽（83），每个具有纵向轴线。 涂覆喷嘴（80）将涂层蒸气引导到涂覆区域，并且排气狭槽（82）从涂覆区域去除蒸汽。 第二布置将涂布机与涂布喷嘴（80）和排气狭槽（82）面向涂布区域的路径间隔开。 第二假想直线（94）垂直于涂覆喷嘴（80）的纵向轴线，并且第一假想线（23）和第二假想线（94）悬挂在大于零度的范围内的角度至 90度。

公开(公告)号：WO2017048351A1

公开(公告)日：2017-03-23

申请号：PCT/US2016/042181

申请日：2016-07-14

Applicant: PPG INDUSTRIES OHIO, INC.

Inventor： MEDWICK, Paul A. ,  BASIL, John D. ,  KABAGAMBE, Benjamin ,  MCCAMY, James W. ,  BUHAY, Harry

IPC: C03C3/089 ,  C03C17/36 ,  G02B5/08 ,  G02B5/10

CPC classification number: G02B5/0875 ,  C03C17/3613 ,  C03C17/3639 ,  C03C17/3644 ,  C03C17/3655 ,  C03C17/3663 ,  F24S23/82 ,  G02B5/10

Abstract: A solar reflective mirror includes a parting film between solar reflecting sublayers to improve optics and stability of the solar mirror. The coating stack of the solar reflector mirror is encapsulated to increase the useable life of the solar mirror, and to eliminate the need for a permanent protection overcoat. Omission of the PPO film which is electrically non-conductive makes the coating stack electrically conductive eliminating the need for a two layer encapsulant when the encapsulant is e-coated. Another feature of the invention is applying the base coat of the encapsulant over the marginal edges of the PPO film leaving a center section without coverage and adding the top coating of the encapsulant over the base coat and the uncoated area.

Abstract translation: 太阳能反射镜包括在太阳能反射子层之间的分离膜，以改善太阳能反射镜的光学和稳定性。 太阳能反射镜的涂层堆叠被封装以增加太阳能反射镜的可使用寿命，并且消除对永久保护外罩的需要。 省略不导电的PPO膜使得涂层堆叠导电，当密封剂被涂覆时，不需要双层密封剂。 本发明的另一个特征是将密封剂的底涂层涂覆在PPO膜的边缘上，离开中心部分而没有覆盖，并且在底涂层和未涂覆区域上添加密封剂的顶部涂层。

公开(公告)号：WO2014085086A1

公开(公告)日：2014-06-05

申请号：PCT/US2013/069835

申请日：2013-11-13

Applicant: PPG INDUSTRIES OHIO, INC.

Inventor： SHELESTAK, Larry J. ,  MCCAMY, James W. ,  OHODNICKI, JR., Paul R. ,  LI, Hong ,  POLCYN, Adam D.

IPC: C03C3/087

CPC classification number: C03C3/087 ,  G11B5/7325 ,  H01L31/0392 ,  H01L31/03925 ,  Y02E10/50

Abstract: The present invention relates to a glass composition that includes: 57 to 75 percent by weight of SiO 2 ; 3 to 11 percent by weight of Al 2 O 3 ; 6 to 11 percent by weight of Na 2 O; 16 to 21 percent by weight of CaO; 0.01 to 0.1 percent by weight of Li 2 O; and less than 0.05 percent by weight of K 2 O. Each percent by weight is based on total weight of the glass composition. Glass products are also provided that have a bulk glass composition as described above. The glass products, such as flat glass products and glass substrates, have a strain point of at least 590°C and a thermal expansion of at least 7.4 ppm/°C. The present invention also relates to magnetic recording articles and photovoltaic cells that include a glass substrate that has a bulk glass composition as described above.

Abstract translation: 本发明涉及一种玻璃组合物，其包含：57〜75重量％的SiO 2; 3〜11重量％的Al 2 O 3; 6至11重量％的Na 2 O; 16〜21重量％的CaO; 0.01〜0.1重量％的Li 2 O; 和小于0.05重量％的K 2 O。 每重量百分比是基于玻璃组合物的总重量。 还提供了具有如上所述的块状玻璃组合物的玻璃制品。 玻璃制品如平板玻璃制品和玻璃基材的应变点至少为590℃，热膨胀率至少为7.4ppm /℃。 本发明还涉及包括具有如上所述的块状玻璃组合物的玻璃基板的磁记录制品和光伏电池。

公开(公告)号：WO2016144869A1

公开(公告)日：2016-09-15

申请号：PCT/US2016/021178

申请日：2016-03-07

Applicant: PPG INDUSTRIES OHIO, INC.

Inventor： MCCAMY, James W. ,  MA, Zhixun ,  KABAGAMBE, Benjamin ,  KORAM, Kwaku K. ,  HUNG, Cheng-Hung ,  NELIS, Gary J.

IPC: H01L51/52 ,  H01L51/44 ,  H01L31/00 ,  C03B17/06 ,  H01L51/00

CPC classification number: H01L51/5215 ,  C03C17/36 ,  C03C17/3631 ,  C03C17/3668 ,  C03C17/3678 ,  C03C2217/94 ,  C23C16/407 ,  H01L51/0096 ,  H01L51/442 ,  H01L51/5268 ,  H01L51/5281 ,  Y02E10/549

Abstract: An optoelectronic device (10) includes a first substrate (12) having a first surface (14) and a second surface (16); an underlayer (18) located over the second surface (16); a first conductive layer (20) over the underlayer (18); an overlayer (22) over the first conductive layer (20); a semiconductor layer (24) over the first conductive layer (20); and a second conductive layer (26) over the semiconductor layer (24). The first conductive layer (20) includes a conductive oxide and at least one dopant selected from the group consisting of tungsten, molybdenum, niobium, and fluorine; and/or the overlayer (22) includes a buffer layer (42) including tin oxide and at least one material selected from the group consisting of zinc, indium, gallium, and magnesium.

Abstract translation: 光电子器件（10）包括具有第一表面（14）和第二表面（16）的第一衬底（12）。 位于第二表面（16）上方的底层（18）; 在所述底层（18）上方的第一导电层（20）; 在第一导电层（20）上方的覆盖层（22）; 在所述第一导电层（20）上方的半导体层（24）; 和在半导体层（24）上方的第二导电层（26）。 第一导电层（20）包括导电氧化物和选自钨，钼，铌和氟的至少一种掺杂剂; 和/或所述覆层（22）包括包含氧化锡和选自锌，铟，镓和镁中的至少一种材料的缓冲层（42）。

公开(公告)号：WO2014210114A1

公开(公告)日：2014-12-31

申请号：PCT/US2014/044027

申请日：2014-06-25

Applicant: PPG INDUSTRIES OHIO, INC. ,  JIAO, Yu ,  MCCAMY, James W. ,  HANEKAMP, David

Inventor： JIAO, Yu ,  MCCAMY, James W. ,  HANEKAMP, David

IPC: C03B17/06 ,  C03C17/00 ,  C03B18/04

CPC classification number: C03B18/04 ,  C03B17/064 ,  C03B18/02 ,  C03C17/002 ,  C03C2218/152 ,  G01B9/02091 ,  G01B11/06 ,  G01B11/14 ,  Y02P40/57

Abstract: A float glass system (10) includes a float bath (14) having a pool of molten metal (16). A chemical vapor deposition coater (32) is located in the float bath (14) above the pool of molten metal (16). The coater (32) includes at least one low-coherence interferometry probe (38) located in or on the coater (32) and connected to a low-coherence interferometry system (36). Another low-coherence interferometry probe 138 can be located outside an exit end of the float bath (14) and connected to the same or another low-coherence interferometry system (36).

Abstract translation: 浮法玻璃系统（10）包括具有熔融金属池（16）的浮浴（14）。 化学气相沉积涂布机（32）位于熔融金属池（16）上方的浮法槽（14）中。 涂布机（32）包括位于涂布机（32）中或涂布机（32）上并连接到低相干干涉测量系统（36）的至少一个低相干干涉测量探头（38）。 另一个低相干干涉测量探针138可位于浮浴（14）的出口端的外侧，并连接到相同或另一低相干干涉测量系统（36）。

公开(公告)号：WO2013002882A1

公开(公告)日：2013-01-03

申请号：PCT/US2012/033996

申请日：2012-04-18

Applicant: PPG INDUSTRIES OHIO, INC.

Inventor： KABAGAMBE, Benjamin ,  BUCHANAN, Michael J. ,  SCOTT, Matthew S. ,  REARICK, Brian K. ,  MEDWICK, Paul A. ,  MCCAMY, James W.

IPC: G02B5/08 ,  H01L31/052 ,  C03C17/36

CPC classification number: C03C17/38 ,  C03C17/42 ,  C03C2217/445 ,  C03C2217/465 ,  C03C2217/479 ,  G02B5/0808 ,  H01L31/0547 ,  Y02E10/52

Abstract: The present invention relates to reflective articles, such as solar mirrors, that include a sacrificial cathodic layer. The reflective article, more particularly includes a substrate (41), such as glass, having a multi - layered coating thereon that includes a lead- free sacrificial cathodic layer (29). The sacrificial cathodic layer (29) includes at least one transition metal, such as a particulate transition metal, which can be in the form of flakes (e.g., zinc flakes). The sacrificial cathodic layer can include an inorganic matrix formed from one or more organo - titanates. Alternatively, the sacrificial cathodic layer can include an organic polymer matrix (e.g., a crosslinked organic polymer matrix formed from an organic polymer and an aminoplast crosslinking agent). The reflective article also includes an outer organic polymer coating (32), that can be electrodeposited over the sacrificial cathodic layer (29).

Abstract translation: 本发明涉及包括牺牲阴极层的反射制品，例如太阳镜。 反射制品更具体地包括其上具有多层涂层的诸如玻璃的基底（41），其包括无铅牺牲阴极层（29）。 牺牲阴极层（29）包括至少一种过渡金属，例如粒状过渡金属，其可以是片状（例如锌片）的形式。 牺牲阴极层可以包括由一种或多种有机钛酸盐形成的无机基质。 或者，牺牲阴极层可以包括有机聚合物基质（例如，由有机聚合物和氨基塑料交联剂形成的交联的有机聚合物基质）。 反射制品还包括可以电沉积在牺牲阴极层（29）上的外部有机聚合物涂层（32）。