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    LOW PRESSURE PROCESS FOR THE HYDROCONVERSION OF HEAVY HYDROCARBO NS
    1.
    发明申请
    LOW PRESSURE PROCESS FOR THE HYDROCONVERSION OF HEAVY HYDROCARBO NS 审中-公开
    用于重油液压烃的低压工艺

    公开(公告)号：WO1997029841A2

    公开(公告)日：1997-08-21

    申请号：PCT/US1997002409

    申请日：1997-02-14

    Applicant: TEXACO INCORPORATED ,  SHERWOOD, David, Edward, Jr. ,  PORTER, Michael, Kevin

    Inventor： TEXACO INCORPORATED

    IPC: B01J00/00

    CPC classification number: C10G47/26 ,  C10G47/02

    Abstract: This invention relates to a process of catalytic hydroconversion of a heavy hydrocarbon oil containing a substantial portion of components having an atmospheric boiling point above 565 DEG C to give a product hydrocarbon oil containing components having a boiling point below about 565 DEG C. The process includes steps of mixing a heavy hydrocarbon oil with an oil soluble molybdenum compound, introducing the resulting mixture into a hydroconversion zone, introducing a reactor feed gas into the hydroconversion zone, and recovering the product hydrocarbon oil from the hydroconversion zone.

    Abstract translation: 本发明涉及含有大部分沸点高于565℃的大部分组分的重烃油的催化加氢转化方法，得到含有沸点低于约565℃的组分的产物烃油。该方法包括 将重质烃油与油溶性钼化合物混合的步骤，将所得混合物引入加氢转化区，将反应器进料气体引入加氢转化区，以及从加氢转化区回收产物烃油。

    PROCESS FOR THE PREPARATION OF FREE-FLOWING VERY ACIDIC CATION EXCHANGERS
    2.
    发明申请
    PROCESS FOR THE PREPARATION OF FREE-FLOWING VERY ACIDIC CATION EXCHANGERS 审中-公开
    用于生产自由流动的强酸性阳离子

    公开(公告)号：WO1997023282A2

    公开(公告)日：1997-07-03

    申请号：PCT/EP1996005785

    申请日：1996-12-20

    Applicant: IAB IONENAUSTAUSCHER GMBH ,  BACHMANN, Reinhard ,  FEISTEL, Lothar ,  SEIDEL, Rüdiger ,  SIEKIERA, Karl-Heinz ,  WEGEWITZ, Kurt

    Inventor： IAB IONENAUSTAUSCHER GMBH

    IPC: B01J00/00

    CPC classification number: B01J39/20 ,  C08F8/36 ,  C08F2800/20 ,  C08F212/08

    Abstract: The invention relates to a process for the preparation of free-flowing end products of very acidic cation exchangers. The grain pile of end products of the very acidic cation exchangers produced in the process described in the patent application P 195 48 012.0 cannot flow freely. By adding linking wetting agents or water-soluble initiators or tensides during polymerisation or after filtration of the end product and/or by taking technical measures, the grain pile of the very acidic cation exchangers is able to flow freely permanently or temporarily using the following process: (1) by adding to the copolymerisation system, known wetting agents in quantities of up to 0.25 g/l of the aqueous phase or water-soluble initiators in quantities of from 0.05 to 20 g/l of the aqueous phase 20 to 120 minutes after reaching the point of gelification; (2) by treating the very acidic cation exchangers with aqueous solution of surfactants with a content of from 0.1 to 5 g/l in the batch or column process; (3) by 1 to 4 hours of washing of the very acidic cation exchangers with water of at least 60 DEG C, subsequent separation off of the water and drying of the end product using sensible heat.

    Abstract translation: 本发明涉及一种用于自由流动的强酸性阳离子交换剂的最终产品的制备方法。 根据该专利申请在上述中得到的对195 48 012.0处理强酸性阳离子交换剂，其最终产品的Kornhaufwerke不能自由流动的。 Kornhaufwerke强酸性阳离子交换剂的永久或临时自由流动性通过加入在聚合或最终产品和/或工艺工程措施的过滤后的润湿剂或表面活性剂或水溶性引发剂的应用以下程序来实现的。 1.由于在加入已知的润湿剂的水相中或水溶性引发剂的至多0.25克/升的量在0.05至20g的量/水相的升深远Kopolymerisationssystem凝胶点之后是20分钟至120分钟。 2.治疗的具有0.1至5g / l的在批处理含量的表面活性物质的水溶液的强酸性阳离子交换剂 - 或柱方法。 3.1-至4小时洗涤具有至少60℃的热水的强酸性阳离子交换剂，然后通过水的分离和最终产物利用显热的干燥。

    VANADIUM-CONTAINING CATALYST SYSTEM
    3.
    发明申请
    VANADIUM-CONTAINING CATALYST SYSTEM 审中-公开
    含钒的催化剂体系

    公开(公告)号：WO1996031274A2

    公开(公告)日：1996-10-10

    申请号：PCT/US1996004367

    申请日：1996-03-29

    Applicant: QUANTUM CHEMICAL CORPORATION

    Inventor： QUANTUM CHEMICAL CORPORATION ,  WINSLOW, Linda, N. ,  KLENDWORTH, Douglas, D. ,  MENON, Raghu ,  LYNCH, Michael, W. ,  FIELDS, Garry, L. ,  JOHNSON, Kenneth, W.

    IPC: B01J00/00

    CPC classification number: B01J31/2226 ,  B01J31/128 ,  B01J31/143 ,  B01J31/1616 ,  B01J2531/56 ,  C08F10/00 ,  C08F210/16 ,  C08F4/68 ,  C08F210/14 ,  C08F2500/17

    Abstract: A vanadium-containing catalyst system particularly suited to the polymerization of blow moldable olefin polymers. The catalyst system includes a supported, first catalyst component prepared by contacting preheated silica or silica pretreated with hexaalkyldisilazane, with (1) a compound or complex which includes at least one carbon to magnesium covalent bond and (2) a compound which includes at least one carbon to Group III metal covalent bond. The sequence of contact of the silica with compound or complex (1) and compound (2) is optional. However, unless the compound or complex (1) and the compound (2) contact the silica simultaneously, the product of this contact is next contacted with whichever of compound (1) or (2) does not initially contact the silica. Where the catalyst system involves the preheated silica, the product of the step of contacting with compounds (1) and (2) is contacted with a vanadium compound which includes at least one halogen atom. Where the catalyst system involves the silica pretreated with hexaalkyldisilazane, the product of the step of contacting with compounds (1) and (2) is washed and then contacted with a vanadium compound which includes at least one halogen atom. Finally, the product of the vanadium compound contacting step is contacted with an alcohol. A second component of the catalyst system is an organoaluminum compound cocatalyst. The catalyst system also includes a halocarbon compound promoter as a third catalyst component.

    Abstract translation: 一种特别适用于可吹塑烯烃聚合物聚合的含钒催化剂体系。 该催化剂体系包括通过将预处理的二氧化硅或六烷基二硅氮烷预处理的二氧化硅与（1）包含至少一个碳 - 镁共价键的化合物或络合物接触而制备的负载的第一催化剂组分和（2）包含至少一种 碳至III族金属共价键。 二氧化硅与化合物（1）和化合物（2）的接触顺序是任选的。 然而，除非化合物或络合物（1）和化合物（2）同时与二氧化硅接触，否则该接触的产物接下来与化合物（1）或（2）中最初不接触二氧化硅的化合物接触。 当催化剂体系涉及预热的二氧化硅时，与化合物（1）和（2）接触的步骤的产物与包含至少一个卤素原子的钒化合物接触。 当催化剂体系涉及用六烷基二硅氮烷预处理的二氧化硅时，将与化合物（1）和（2）接触的步骤的产物洗涤，然后与包含至少一个卤素原子的钒化合物接触。 最后，将钒化合物接触步骤的产物与醇接触。 催化剂体系的第二组分是有机铝化合物助催化剂。 催化剂体系还包括作为第三催化剂组分的卤代烃化合物促进剂。

    METHOD FOR MANUFACTURING COBALT CATALYSTS
    5.
    发明申请
    METHOD FOR MANUFACTURING COBALT CATALYSTS 审中-公开
    制备钴催化剂​​的方法

    公开(公告)号：WO1997000128A2

    公开(公告)日：1997-01-03

    申请号：PCT/US1996008662

    申请日：1996-06-04

    Applicant: THE PROCTER & GAMBLE COMPANY

    Inventor： THE PROCTER & GAMBLE COMPANY ,  PERKINS, Christopher, Mark

    IPC: B01J00/00

    CPC classification number: C07F15/065

    Abstract: A method for manufacturing cobalt complexes having the formula: [Co(NH3)5M] Ty wherein M ligands are selected from substituted and unsubstituted C1-C30 carboxylic acids having the formula: RC(O)O-; said method comprising reacting cobalt complexes having the formula: [Co(NH3)5X] Ty (e.g., X is chlorine) with concentrated ammonium hydroxide followed by carboxylic acid anhydride of the formula: RC(O)O(O)CR.

    Abstract translation: 具有下式的钴络合物的方法：[Co（NH 3）5 M] Ty其中M配体选自具有下式的取代和未取代的C 1 -C 30羧酸：RC（O）O-; 所述方法包括使具有下式的钴络合物：[Co（NH 3）5 X] Ty（例如，X是氯）与浓氢氧化铵反应，然后是下式的羧酸酐：RC（O）O（O）CR。

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