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1.发明申请CONTROLLED CONVERSION OF DIMETHYL BENZYL ALCOHOL TO CUMENE HYDROPEROXIDE FORMED DURING THE CUMENE OXIDATION PROCESS 审中-公开二甲基苄基醇在CUMENE氧化过程中形成的CUMENE氢过氧化物的控制转化
公开(公告)号：WO2016020897A1
公开(公告)日：2016-02-11
申请号：PCT/IB2015/056026
申请日：2015-08-07
发明人： NELSON, Mark Erik , DYKMAN, Arkady Samuilovich , ZINENKOV, Andrey Vladimirovich , PINSON, Victor Vladimrovich
CPC分类号： B01J10/007 , C07C1/24 , C07C29/50 , C07C37/08 , C07C45/53 , C07C407/00 , C07C409/10 , C07C39/04 , C07C49/08 , C07C15/44 , C07C33/20
摘要： The disclosure concerns systems and methods for the production of phenol and acetone from cumene oxidation products. One method comprises reacting cumene and an oxidizing agent to produce a cumene oxidation product comprising cumene hydroperoxide and dimethyl benzyl alcohol, converting at least a portion of the dimethyl benzyl alcohol to cumene hydroperoxide by reacting the at least a portion of the dimethyl benzyl alcohol with hydrogen peroxide in both an organic phase and an aqueous to produce a converted cumene oxidation product, and cleaving the converted cumene oxidation product to produce an output product comprising one or more of phenol, acetone, and alpha-methylstyrene.
摘要翻译： 本公开涉及从枯烯氧化产物生产苯酚和丙酮的系统和方法。 一种方法包括使异丙基苯和氧化剂反应以产生包含氢过氧化枯烯和二甲基苄醇的异丙苯氧化产物，通过使至少一部分二甲基苄醇与氢气反应将至少一部分二甲基苄醇转化为氢过氧化枯烯 过氧化物在有机相和水溶液中以产生转化的异丙基苯氧化产物，并切割转化的枯烯氧化产物以产生包含苯酚，丙酮和α-甲基苯乙烯中的一种或多种的输出产物。
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公开(公告)号：WO2021178393A1
公开(公告)日：2021-09-10
申请号：PCT/US2021/020445
申请日：2021-03-02
IPC分类号： C07C407/00 , C07C409/10
摘要： A method for oxidizing a hydrocarbon includes feeding an oxidant to a top portion of a reactor; reacting the hydrocarbon with the oxidant in the reactor to obtain a reaction product stream, the reaction product stream exiting a reactor outlet at a bottom portion of the reactor; and recycling a portion of the reaction product stream to the top portion of the reactor; and introducing the oxidant into an oxidation liquid comprising the portion of the reaction product stream recycled to the top portion of the reactor to form a reaction media stream entering a reactor inlet at the top portion of the reactor. A pressure of the reactor outlet exceeds a pressure of the reactor inlet by at least 5%. The reaction media stream moves vertically downwards in the reactor.
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3.发明申请METHOD FOR CONTROLLING CLEAVAGE OF HYDROPEROXIDES OF ALKYLAROMATIC HYDROCARBONS 审中-公开用于控制碱性烃类氢过氧化物的清除方法
公开(公告)号：WO2016020879A1
公开(公告)日：2016-02-11
申请号：PCT/IB2015/055985
申请日：2015-08-06
CPC分类号： C07C37/08 , B01J19/0006 , B01J19/245 , B01J2219/00051 , B01J2219/00162 , B01J2219/00164 , B01J2219/24 , C07C2/66 , C07C45/53 , C07C407/00 , C07C2529/06 , C07C2601/14 , C08G64/38 , C07C49/08 , C07C39/04 , C07C409/14 , C07C15/073 , C07C15/107 , C07C15/02 , C07C15/085
摘要： A method of producing phenol and acetone can comprise: alkylating benzene with a C 2-6 alkyl source in the presence of a zeolite catalyst to produce a C 8-12 alkylbenzene; oxidizing the C 8-12 alkylbenzene in the presence of an oxygen containing gas to produce a C 8-12 alkylbenzene hydroperoxide; cleaving decomposing the C 8-12 alkylbenzene hydroperoxide in the presence of an acid catalyst to produce phenol, a C 3-6 ketone, and undesirable side products such as, but not limited to acetaldehyde, DMBA, acetophenone, AMS, AMS dimers, unidentified heavies, or a combination comprising at least one of the foregoing; and monitoring a concentration of the C 8-12 alkylbenzene hydroperoxide in a process stream of a reactor in real time at a temperature and a pressure of the process stream; and in real time, controlling a parameter of the reactor and/or the cleaving decomposing in response to the concentration of the C 8-12 alkylbenzene hydroperoxide.
摘要翻译： 一种生产苯酚和丙酮的方法可以包括：在沸石催化剂存在下，用C2-6烷基源烷基化苯，得到C8-12烷基苯; 在含氧气体存在下使C8-12烷基苯氧化，得到C8-12烷基苯氢过氧化物; 在酸催化剂的存在下分解C8-12烷基苯氢过氧化物以产生苯酚，C3-6酮和不期望的副产物，例如但不限于乙醛，DMBA，苯乙酮，AMS，AMS二聚体，不明重的重质物， 或包含前述的至少一种的组合; 并且在反应器的工艺流中在工艺流的温度和压力下实时监测C8-12烷基苯氢过氧化物的浓度; 并且实时地响应于C8-12烷基苯氢过氧化物的浓度控制反应器的参数和/或裂解分解。
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4.发明申请
公开(公告)号：WO2016020895A1
公开(公告)日：2016-02-11
申请号：PCT/IB2015/056023
申请日：2015-08-07
CPC分类号： C07C37/08 , B01J19/0093 , B01J31/06 , B01J2219/00783 , B01J2219/00795 , B01J2219/00819 , B01J2219/00822 , B01J2219/00835 , B01J2219/00837 , B01J2219/00842 , B01J2219/00862 , B01J2219/00885 , B01J2219/0099 , C07C1/20 , C07C45/53 , C07C407/00 , Y02P20/52 , C07C39/04 , C07C49/08 , C07C409/16 , C07C15/44
摘要： The disclosure concerns methods comprising forming a phenol and acetone mixture from decomposition of a cumene hydroperoxide or a phenol, acetone, and AMS from the decomposition of a mixture containing dicumyl peroxide in a system comprising one or more reactors where at least a portion of an inner surface of the one or more reactors has a polymer coating and wherein the coating inhibits build-up of a fouling precipitate on the coated inner surface of the one or more reactors as compared to such build-up in the absence of the coating.
摘要翻译： 本公开涉及包括在包含一种或多种反应器的系统中从含二枯基过氧化物的混合物的分解中形成苯酚和丙酮混合物从氢过氧化枯烯或苯酚，丙酮和AMS分解的方法，其中至少一部分内部 一个或多个反应器的表面具有聚合物涂层，并且其中与在不存在涂层的情况下的这种积聚相比，涂层抑制了在一个或多个反应器的涂覆内表面上的结垢沉淀物的积聚。
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5.发明申请THE OPTIMIZATION OF O-SULFONATED PHENOL PRODUCTION FOR CUMENE HYDROPEROXIDE CLEAVAGE 审中-公开用于CUMENE HYDROPEROXIDE CLEAVAGE的O-SULFONATED PHENOL生产的优化
公开(公告)号：WO2016020896A1
公开(公告)日：2016-02-11
申请号：PCT/IB2015/056024
申请日：2015-08-07
发明人： NELSON, Mark Erik , DYKMAN, Arkady Samuilovich , ZINENKOV, Andrey Vladimirovich , PINSON, Victor Vladimirovich , ZHUKOV, Dmitrij Nikolayevich
IPC分类号： C07C37/08 , C07C37/20 , C07C303/06 , C07C45/53 , C08G64/30
CPC分类号： C07C37/08 , B01J31/0225 , C07C37/20 , C07C45/53 , C07C303/06 , C07C309/73 , Y02P20/52 , C07C39/16 , C07C39/04 , C07C49/08 , C07C309/42
摘要： A method for the manufacture of a sulfonated phenol for use as a cumene hydroperoxide decomposition catalyst can comprise: combining phenol and a sulfonating agent at a first temperature that is 1 º C to 15 º C higher than a melting temperature of the phenol, to form a reaction mixture at the first temperature; reducing the first temperature of the reaction mixture to a second temperature that is 10 to 40°C lower than the first temperature; and forming the sulfonated phenol at the second temperature.
摘要翻译： 制造用作异丙基氢过氧化物分解催化剂的磺化苯酚的方法可以包括：在比苯酚的熔融温度高1℃至15℃的第一温度下将苯酚和磺化剂混合以形成 第一温度下的反应混合物; 将反应混合物的第一温度降低到比第一温度低10至40℃的第二温度; 并在第二温度下形成磺化苯酚。
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6.发明申请ALKYLBENZENE HYDROPEROXIDE PRODUCTION USING DISPERSED BUBBLES OF OXYGEN CONTAINING GAS 审中-公开使用分散的含氧气体的烷基苯乙烯氢过氧化物生产
公开(公告)号：WO2016020889A1
公开(公告)日：2016-02-11
申请号：PCT/IB2015/056012
申请日：2015-08-07
IPC分类号： C07C37/08 , C07C45/53 , C07C407/00 , B01J19/26 , B01J4/00
CPC分类号： C07C407/00 , B01J4/004 , B01J10/002 , B01J19/0006 , B01J19/2425 , B01J19/248 , B01J2219/00094 , B01J2219/00166 , B01J2219/00177 , C07C37/08 , C07C45/53 , C07C39/04 , C07C49/08 , C07C409/10
摘要： An apparatus for oxidation of a C 8 -C 12 alkylbenzene reactant to a C 8 -C 12 alkylbenzene hydroperoxide product, the reactor can comprise: a flow reactor comprising a reactant inlet, an oxidate product outlet, wherein the reactor is configured to provide a liquid flow from the reactant inlet to the product outlet, a gas inlet configured to introduce an oxygen-containing gas into the reactor, and an inlet sparger configured to flow gas bubbles comprising the oxygen-containing gas within the liquid flow, and wherein: the inlet sparger is configured to flow the gas bubbles having a diameter of 1.0 mm to 5.0 mm over a gas bubble residence time from 1 to 200 seconds, and/or the inlet sparger configured to flow the gas bubbles such that greater than or equal to 80% of the gas bubbles do not coalesce into larger bubbles over a gas bubble residence time of 1 to 200 seconds.
摘要翻译： 用于将C 8 -C 12烷基苯反应物氧化成C 8 -C 12烷基苯氢过氧化物产物的装置，所述反应器可包括：流动反应器，其包含反应物入口，氧化物产物出口，其中所述反应器构造成提供来自 产物出口的反应物入口，构造成将含氧气体引入反应器的气体入口，以及配置成将包含含氧气体的气泡流入液体流中的入口喷射器，其中：配置入口喷射器 在气泡停留时间为1至200秒时将具有1.0mm直径的气泡流动至5.0mm，和/或构造成使气泡流动的入口喷射器使得大于或等于气体的80％ 在气泡停留时间为1至200秒时，气泡不会聚结成较大的气泡。
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