POLYCARBONATE COPOLYMER BLENDS, ARTICLES FORMED THEREFROM, AND METHODS OF MANUFACTURE

    公开(公告)号:WO2019165062A1

    公开(公告)日:2019-08-29

    申请号:PCT/US2019/018941

    申请日:2019-02-21

    Abstract: A polymer blend including 5 to 95 weight percent of a poly(ester-carbonate-carbonate) comprising 40 to 95 mole percent of ester units comprising low heat bisphenol groups and high heat bisphenol groups, wherein the ester units comprise 20 to 80 mole percent of the low heat bisphenol groups and 20 to 80 mole percent of the high heat bisphenol groups, based on the total moles of ester units in the poly(ester-carbonate-carbonate), and 5 to 60 mole percent of carbonate units comprising the low heat bisphenol groups and the high heat bisphenol groups, wherein the carbonate units comprise 20 to 80 mole percent of the low heat bisphenol groups and 20 to 80 mole percent of the high heat bisphenol groups, based on the total moles of carbonate units in the poly(ester-carbonate-carbonate); and 5 to 95 weight percent of a poly(etherimide), wherein the weight percent of each polymer is based on the total weight of the polymers in the blend, and a molded 0.125-inch thick ASTM tensile bar comprising the polymer blend has a haze value of less than 25% as determined according to ASTM D1003 using the color space CIE1931 with Illuminant C and a 2° observer.

    SULFUR-STABILIZED THERMOPLASTIC COMPOSITIONS, METHODS OF MAKING, AND ARTICLES FORMED THEREFROM

    公开(公告)号:WO2020112591A1

    公开(公告)日:2020-06-04

    申请号:PCT/US2019/062920

    申请日:2019-11-25

    Abstract: A copolycarbonate included 2-95 mole percent of high heat carbonate units derived from a high heat aromatic dihydroxy monomer, wherein a polycarbonate homopolymer derived from the high heat aromatic dihydroxy monomer has a glass transition temperature of 175-330C determined by differential scanning calorimetry as per ASTM D3418 with a 20C/min heating rate, and 5-98 mole percent of a low heat carbonate units derived from a low heat aromatic monomer, wherein a polycarbonate homopolymer derived from the low heat aromatic monomer has a glass transition temperature of less than 170C determined by differential scanning calorimetry as per ASTM D3418 with a 20C/min heating rate, each based on the sum of the moles of the carbonate units; and a sulfur-containing stabilizer compound, wherein the sulfur-containing stabilizer compound is a thioether carboxy compound, a thioether dicarboxy compound, a thioether ester compound, or a combination thereof, wherein the sulfur-containing stabilizer compound is present in an amount effective to provide 5-50 parts per million by weight of added sulfur, based on the total parts by weight of the copolycarbonate, wherein a source of the added sulfur is the sulfur-containing stabilizer.

    WEATHERABLE THERMOPLASTIC COMPOSITIONS, METHOD OF MANUFACTURE, AND ARTICLES THEREFROM
    4.
    发明申请
    WEATHERABLE THERMOPLASTIC COMPOSITIONS, METHOD OF MANUFACTURE, AND ARTICLES THEREFROM 审中-公开
    耐候性热塑性组合物,制造方法及其制品

    公开(公告)号:WO2016085790A1

    公开(公告)日:2016-06-02

    申请号:PCT/US2015/061760

    申请日:2015-11-20

    CPC classification number: C08L69/005 C08K5/3432 C08L67/02 C08L69/00

    Abstract: A thermoplastic composition including a polyaryl ester, a polymer different from the polyaryl ester, and a phthalone compound according to the formula (I) wherein Z 1 represents the atoms necessary to complete a 9- to 13-membered single or fused aromatic ring structure, Z 2 represents the atoms necessary to complete a pyridine or quinoline ring, each R 1 and each R 2 are independently halogen, an alkyl group, an aryl group, a heterocyclic group, an alkoxy group, an aryloxy group, an aromatic or aliphatic thioether group, an aromatic or aliphatic carboxylic acid ester group, or an aromatic or aliphatic amide group, a is 0 to 6, b is 0 to 4, n is 1 or 2, and X is present only if n= 2 and is a single bond or a divalent organic radical bonded to the Z 1 ring structure through an ether, ketone, or thio linkage.

    Abstract translation: 包括聚芳酯,不同于聚芳酯的聚合物和根据式(I)的二苯酮酮化合物的热塑性组合物,其中Z1表示完成9至13元单或稠合芳环结构所必需的原子,Z 2 表示完成吡啶或喹啉环所需的原子,每个R 1和R 2各自独立地为卤素,烷基,芳基,杂环基,烷氧基,芳氧基,芳族或脂族硫醚基,芳族 或脂肪族羧酸酯基,或芳香族或脂肪族酰胺基,a为0〜6,b为0〜4,n为1或2,X仅在n = 2时存在且为单键或2价 通过醚,酮或硫键与Z1环结构键合的有机基团。

    ADDITIVE MANUFACTURING ARTICLES USEFUL IN AIRCRAFT
    7.
    发明申请
    ADDITIVE MANUFACTURING ARTICLES USEFUL IN AIRCRAFT 审中-公开
    用于航空器的添加制造文章

    公开(公告)号:WO2017100397A1

    公开(公告)日:2017-06-15

    申请号:PCT/US2016/065516

    申请日:2016-12-08

    Abstract: Disclosed are methods of making articles useful in aircraft or other passenger conveyance (and specific articles made), these methods including melt extruding a plurality of layers comprising a thermoplastic polymer composition in a preset pattern; and fusing the plurality of layers to provide the article; wherein the thermoplastic polymer composition is a combination of polycarbonate polymer or copolymer, a polyetherimide polymer or copolymer, a polyarylethersulfone polymer or copolymer, and a non-brominated and non-chlorinated organic phosphorus-containing additive that will lower the Tg of the thermoplastic polymer from 5 to 100 degrees C, wherein the article meets Federal Aviation Regulation FAR 25.853 (d).

    Abstract translation: 公开了制造用于飞机或其他乘客运输工具(以及制造的特定制品)的制品的方法,这些方法包括:以预设图案熔融挤出包含热塑性聚合物组合物的多个层; 并熔化所述多个层以提供所述物品; 其中所述热塑性聚合物组合物是聚碳酸酯聚合物或共聚物,聚醚酰亚胺聚合物或共聚物,聚芳醚砜聚合物或共聚物以及将使所述热塑性聚合物的Tg降低的非溴化和非氯化有机含磷添加剂的组合 5至100摄氏度,其中该物品符合美国联邦航空条例FAR 25.853(d)。

    THERMOPLASTIC COMPOSITIONS, METHOD OF MANUFACTURE, AND ARTICLES THEREFROM
    8.
    发明申请
    THERMOPLASTIC COMPOSITIONS, METHOD OF MANUFACTURE, AND ARTICLES THEREFROM 审中-公开
    热塑性组合物,制造方法及其制品

    公开(公告)号:WO2016085928A1

    公开(公告)日:2016-06-02

    申请号:PCT/US2015/062322

    申请日:2015-11-24

    Abstract: A thermoplastic composition including a polycarbonatesiloxane-arylate; a phthalone compound; and optionally an additional component different from the polycarbonatesiloxane- arylate and the phthalone compound; wherein the phthalone compound has a formula: wherein Z 1 represents the atoms necessary to complete a 9- to 13-membered single or fused aromatic ring structure, Z 2 represents the atoms necessary to complete a pyridine or quinoline ring, each R 1 and each R 2 are independently halogen, an alkyl group, an aryl group, a heterocyclic group, an alkoxy group, an aryloxy group, an aromatic or aliphatic thioether group, an aromatic or aliphatic carboxylic acid ester group, or an aromatic or aliphatic amide group, a is an integer from 0 to 6, b is an integer from 0 to 4, n is 1 or 2, and X is present only if n= 2 and is a single bond or a divalent organic radical bonded to the Z 1 ring structure through an ether, ketone, or thio linkage.

    Abstract translation: 一种热塑性组合物,包括聚碳酸酯硅氧烷 - 芳基化物; 酞酮化合物 和任选的不同于聚碳酸酯硅氧烷 - 芳基化合物和邻苯二甲酸酯化合物的另外的组分; 其中所述酞酮化合物具有下式:其中Z1表示完成9至13元单或稠合芳环结构所必需的原子,Z 2表示完成吡啶或喹啉环所需的原子,每个R 1和R 2各自独立地 卤素,烷基,芳基,杂环基,烷氧基,芳氧基,芳香族或脂肪族硫醚基,芳香族或脂肪族羧酸酯基或芳香族或脂肪族酰胺基,a为整数 0〜6,b为0〜4的整数,n为1或2,X仅在n = 2时存在且为单键或通过醚键接到Z1环结构的二价有机基团,酮 ,或硫键。

    THERMOPLASTIC POLYCARBONATE COPOLYMER COMPOSITIONS, METHODS OF THEIR MANUFACTURE, AND USES THEREOF
    10.
    发明申请
    THERMOPLASTIC POLYCARBONATE COPOLYMER COMPOSITIONS, METHODS OF THEIR MANUFACTURE, AND USES THEREOF 审中-公开
    热塑性聚碳酸酯共聚物组合物,其制造方法及其用途

    公开(公告)号:WO2013130802A1

    公开(公告)日:2013-09-06

    申请号:PCT/US2013/028316

    申请日:2013-02-28

    CPC classification number: B32B5/00 C08K5/523 C09K21/12 C09K21/14 Y10T428/1397

    Abstract: This disclosure relates to thermoplastic compositions comprising a polycarbonate copolymer, the polycarbonate copolymer comprising first repeating carbonate units and second repeating units selected from carbonate units that are different from the first carbonate units, polysiloxane units, and a combination comprising at least one of the foregoing unit; and an organophosphorus flame retardant in an amount effective to provide 0.1 to 1.0 wt% phosphorus based on the total weight of the composition, wherein an article molded from the composition has a smoke density after 4 minutes (Ds-4) of less than or equal to 600 determined according to ISO 5659-2 on a 3 mm thick plaque, and a material heat release of less than or equal to 160 kW/m 2 determined according to ISO 5660-1 on a 3 mm thick plaque.

    Abstract translation: 本公开涉及包含聚碳酸酯共聚物的热塑性组合物,聚碳酸酯共聚物包含第一重复碳酸酯单元和选自不同于第一碳酸酯单元的碳酸酯单元的第二重复单元,聚硅氧烷单元,以及包含至少一个上述单元 ; 和有机磷阻燃剂,其量有效地提供0.1至1.0重量%的磷,基于组合物的总重量,其中由该组合物模制的制品在4分钟后具有小于或等于4分钟的烟密度(Ds-4) 至600根据ISO 5659-2测定,厚度为3毫米厚,根据ISO 5660-1测定的材料放热量小于或等于160千瓦/平方米,厚度为3毫米厚。

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