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    FLUOROALLYLSULFONYL AZIDE MONOMERS AND POLYMERS THERE FROM
    1.
    发明申请
    FLUOROALLYLSULFONYL AZIDE MONOMERS AND POLYMERS THERE FROM 审中-公开
    氟聚醚砜单体和聚合物

    公开(公告)号：WO2013087498A1

    公开(公告)日：2013-06-20

    申请号：PCT/EP2012/074627

    申请日：2012-12-06

    Applicant: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.

    Inventor： WLASSICS, Ivan ,  TORTELLI, Vito ,  MARRANI, Alessio

    IPC: C08F14/18 ,  C08F214/22 ,  C07C247/00 ,  C07C311/49 ,  C08K5/00

    CPC classification number: C08F214/222 ,  C07C311/49 ,  C08F14/18 ,  C08F214/22 ,  C08K5/0025 ,  C08K5/43

    Abstract: This invention pertains to fluoroallylsulfonyl azide compounds of formula: CF 2 =CF-CF 2 -O-R f -SO 2 N 3 formula (I) wherein R f is a divalent (per)fluorinated group, optionally comprising one or more than one ethereal oxygen atom [monomer (Az)], which are useful as functional monomers in fluoropolymers, to the fluoropolymers which comprise recurring units derived from such fluoroallylsulfonyl azide compounds, to a process for their manufacture, to a curable compound comprising the same and to a method for crosslinking the same.

    Abstract translation: 本发明涉及式CF 2 = CF-CF 2 -O-Rf-SO 2 N 3式（I）的氟代烯丙基磺酰基叠氮化合物，其中R f是二价（全）氟化基团，任选地包含一个或多于一个醚氧原子[单体（Az ）]，其作为含氟聚合物中的官能单体可用于含有源自这些氟代烯丙基磺酰基叠氮化合物的重复单元的含氟聚合物，其制备方法，包含该聚合物的可固化化合物及其交联方法。

    HYDROPHILIC FLUOROPOLYMER
    2.
    发明申请
    HYDROPHILIC FLUOROPOLYMER 审中-公开
    水解氟聚合物

    公开(公告)号：WO2014095902A1

    公开(公告)日：2014-06-26

    申请号：PCT/EP2013/076952

    申请日：2013-12-17

    Applicant: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.

    Inventor： WLASSICS, Ivan ,  BIANCARDI, Roberto ,  CAMPANELLI, Pasquale ,  DI NICOLO', Emanuele ,  SANGUINETI, Aldo ,  TONELLI, Claudio Adolfo Pietro

    IPC: C08F214/22 ,  C08F251/02 ,  C08F290/04 ,  C08F290/10 ,  C08G77/46 ,  C08F214/00

    CPC classification number: C08G81/025 ,  B01D67/0023 ,  C08F214/22 ,  C08F214/225 ,  C08G65/007 ,  C08G2261/128 ,  C08G2650/48 ,  C08L63/00 ,  C08L71/00 ,  C08L2205/05 ,  C08L27/16

    Abstract: The present invention pertains to a process for the manufacture of a grafted fluoropolymer [polymer (Fg)], said process comprising reacting: A) at least one fluoropolymer comprising at least one functional group selected from the group consisting of a hydroxyl group and a carboxylic acid group [polymer (F)], B) at least one polyoxyalkylene (POA) of formula (I): R B -(CH 2 -O) x -(CH 2 CHR A O) n -(CH 2 -O) x' -R C , wherein at least one of R B and R C is a reactive group comprising at least one heteroatom selected from oxygen and nitrogen different from the hydroxyl group, the remaining, if any, being a -[O] z -CH 3 alkyl group, wherein z is 0 or 1, R A is a hydrogen atom or a C 1 -C 5 alkyl group, x and x', equal to or different from each other, are independently 0 or 1, and n is an integer comprised between 2 and 1000, preferably between 5 and 200, C) optionally, in the presence of at least one catalyst, and D) optionally, in the presence of at least one organic solvent (S). The present invention also pertains to grafted fluoropolymers obtained from said process and to uses of said grafted fluoropolymers for manufacturing porous membranes.

    Abstract translation: 本发明涉及制备接枝氟聚合物[聚合物（Fg）]的方法，所述方法包括使A）至少一种含有至少一个选自羟基和羧基的官能团的含氟聚合物 酸性基团[聚合物（F）]，B）至少一种式（I）的聚氧化烯（POA）：RB-（CH 2 -O）x - （CH 2 CHRAO）n - （CH 2 -O）x'-RC， RB和RC中的至少一个是包含至少一个选自不同于羟基的氧和氮的杂原子的反应性基团，剩余的（如果有的话）是 - [O] z-CH 3烷基，其中z是0或1 RA为氢原子或C1-C5烷基，x和x'彼此相同或不同，分别为0或1，n为2〜1000，优选为5〜200的整数， C）任选地，在至少一种催化剂的存在下，和D）任选地，在至少一种有机溶剂（S）的存在下。 本发明还涉及从所述方法获得的接枝的含氟聚合物以及所述接枝的含氟聚合物用于制造多孔膜的用途。

    CROSSLINKABLE VINYLIDENE FLUORIDE AND TRIFLUOROETHYLENE POLYMERS
    3.
    发明申请
    CROSSLINKABLE VINYLIDENE FLUORIDE AND TRIFLUOROETHYLENE POLYMERS 审中-公开
    可交联的乙烯基氟化物和三氟乙烯聚合物

    公开(公告)号：WO2013087500A1

    公开(公告)日：2013-06-20

    申请号：PCT/EP2012/074629

    申请日：2012-12-06

    Applicant: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.

    Inventor： MARRANI, Alessio ,  WLASSICS, Ivan ,  TORTELLI, Vito ,  FALCO, Ivan

    IPC: C08F214/18 ,  C08F214/22 ,  C08K5/00

    CPC classification number: C08F214/22 ,  B05D1/00 ,  B05D2506/10 ,  C08F214/18 ,  C08F214/222 ,  C08J3/24 ,  C08J2327/16 ,  C08K5/28 ,  C08L27/16

    Abstract: The present invention pertains to semi-crystalline fluoropolymer [polymer (F)] comprising: - recurring units derived from vinylidene fluoride (VDF); - from 10% to 50% by moles [with respect to the total moles of recurring units of polymer (F)] of recurring units derived from trifluoroethylene (TrFE); and - from 0.01 % to 10% by moles [with respect to the total moles of recurring units of polymer (F)] of recurring units derived from at least one monomer comprising an azide group [monomer (Az)], to a process for its manufacture, to a crosslinkable composition comprising the same, to a process for crossliking the same and to a method for manufacturing one of electrical and electronic devices using the same.

    Abstract translation: 本发明涉及半结晶含氟聚合物[聚合物（F）]，其包含： - 衍生自偏二氟乙烯（VDF）的重复单元; - 相对于来自三氟乙烯（TrFE）的重复单元的聚合物（F）的重复单元的总摩尔数）为10〜50摩尔％。 和 - 从包含叠氮化物基团[单体（Az）]的至少一种单体衍生的重复单元的相对于聚合物（F）的重复单元的总摩尔数）为0.01〜10摩尔％ 其制造方法，涉及包含该组合物的可交联组合物，涉及其交叉的方法以及使用其制造电气和电子设备之一的方法。

    MIXTURES OF MONO-, BI- AND NON-FUNCTIONAL FLUORINATED POLYMERS COMPRISING A PLURALITY OF (PER)FLUOROPOLYETHER SEGMENTS
    6.
    发明申请
    MIXTURES OF MONO-, BI- AND NON-FUNCTIONAL FLUORINATED POLYMERS COMPRISING A PLURALITY OF (PER)FLUOROPOLYETHER SEGMENTS 审中-公开
    包含（PER）氟代聚乙烯部分多重性的单，二功能和非功能性氟化聚合物的混合物

    公开(公告)号：WO2016083280A1

    公开(公告)日：2016-06-02

    申请号：PCT/EP2015/077304

    申请日：2015-11-23

    Applicant: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.

    Inventor： TONELLI, Claudio Adolfo Pietro ,  WLASSICS, Ivan ,  MARCHIONNI, Giuseppe ,  BRAGANTE, Letanzio

    IPC: C08G65/00 ,  C08G65/30 ,  C08G65/323 ,  C08G65/334

    CPC classification number: C08G65/3236 ,  C08G65/007 ,  C08G65/30 ,  C08G65/3346 ,  C08L71/02 ,  C08L2205/025

    Abstract: Disclosed are mixtures containing: mono- and bi-functional polymers [polymers (P-A) and (P-B)] comprising a plurality of (per)fluoropolyether segments [segments (S RF )] joined together by hydrogenated (poly)ether segments [segments (S H )], said polymers having two ends, wherein one or both ends comprises a hydroxy or a leaving group; a non-functional polymer comprising a plurality of (per)fluoropolyether segments (S RF ) joined together by hydrogenated (poly)ether segments (S H ), with the proviso that the hydrogenated (poly)ether segments (S H ) are not segments of formula -CH 2 OCH 2 OCH 2 -. Disclosed are also monofunctional polymers (P-A) that can be isolated from such mixtures. Methods for the obtainment of the mixtures and for separating the polymers therein contained are also provided, as well as methods of using the mixtures or each polymer therein contained as intermediates or building blocks for the synthesis of other polymers or as ingredients of compositions.

    Abstract translation: 公开了包含：单和双官能聚合物[聚合物（PA）和（PB）]，其包含通过氢化（多）醚链段连接在一起的多个（全）氟聚醚链段[链段（SRF）] [链段 ）]，所述聚合物具有两个末端，其中一个或两个末端包含羟基或离去基团; 包括通过氢化（多）醚链段（SH）连接在一起的多个（全）氟聚醚链段（SRF）的非功能性聚合物，条件是氢化（聚）醚链段（SH）不是式 - CH2OCH2OCH2-。 还公开了可从这种混合物中分离的单官能聚合物（P-A）。 还提供了获得混合物和分离其中所含的聚合物的方法，以及使用其中包含的混合物或其中的每种聚合物作为其它聚合物的合成或组合物成分的中间体或结构单元的方法。

    BIFUNCTIONAL FLUORINATED POLYMERS COMPRISING A PLURALITY OF (PER)FLUOROPOLYETHER SEGMENTS
    9.
    发明申请
    BIFUNCTIONAL FLUORINATED POLYMERS COMPRISING A PLURALITY OF (PER)FLUOROPOLYETHER SEGMENTS 审中-公开
    包含多（氟）氟聚乙烯部分的双功能荧光聚合物

    公开(公告)号：WO2016083279A1

    公开(公告)日：2016-06-02

    申请号：PCT/EP2015/077303

    申请日：2015-11-23

    Applicant: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.

    Inventor： TONELLI, Claudio Adolfo Pietro ,  BARBIERI, Solange ,  WLASSICS, Ivan ,  BRAGANTE, Letanzio ,  MARCHIONNI, Giuseppe

    IPC: C08G65/00 ,  C08G81/02 ,  C08G65/334

    CPC classification number: C08G65/007 ,  C08G65/334 ,  C08G65/3344 ,  C08G81/024 ,  C08G2650/48 ,  C10M107/32 ,  C10M2213/06

    Abstract: A polymer [polymer (P)] comprising a plurality of (per)fluoropolyether (PFPE) segments [segments (S RF )] joined together by hydrogenated (poly)ether segments [segments (S H )], said polymers (P) having two end groups [groups (E)], each group (E) comprising a hydroxy or a leaving group, with the proviso that the hydrogenated (poly)ether segment (S H ) is not a segment of formula -CH 2 OCH 2 OCH 2 - is herein disclosed. Disclosed is also a method for the manufacture of polymer (P) and a polymer obtainable by full or partial fluorination of polymer (P). Polymer (P) and polymers obtainable therefrom by full or partial fluorination can be conveniently used in the manufacture of lubricant compositions or of compositions for imparting hydro-/oleo-repellence to substrates. Said polymers can also be used as intermediates for the manufacture of other polymers or block copolymers.

    Abstract translation: 包含由氢化（多）醚链段[SHS]连接在一起的多个（全）氟聚醚（PFPE）链段[链段（SRF）]]的聚合物[聚合物（P）]]，所述聚合物（P） 基团（基团（E）]，每个基团（E）包含羟基或离去基团，条件是氢化（聚）醚链段（SH）不是式-CH 2 OCH 2 OCH 2 - 的链段。 还公开了制备聚合物（P）的方法和通过聚合物（P）的全部或部分氟化获得的聚合物。 聚合物（P）和通过全部或部分氟化获得的聚合物可以方便地用于制备润滑剂组合物或用于赋予基材的氢/疏油性的组合物。 所述聚合物也可用作制备其它聚合物或嵌段共聚物的中间体。

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