IN-SITU ELECTROLYTE PREPARATION IN FLOW BATTERY

    公开(公告)号:WO2014189503A3

    公开(公告)日:2014-11-27

    申请号:PCT/US2013/042174

    申请日:2013-05-22

    Abstract: A method of in-situ electrolyte preparation in a flow battery includes providing a vanadium-based electrolyte solution having vanadium ions of predominantly vanadium V 4+ to a first electrode and a second electrode of at least one cell of a flow battery. The vanadium V 4+ at the first electrode is converted to vanadium V 3+ and the vanadium V 4+ at the second electrode is converted to vanadium V 5+ by providing electrical energy to the electrodes. A reducing agent is then provided to the vanadium V 5+ at the second electrode to reduce the V 5+ to vanadium V 4+ . The vanadium V 3+ at the first electrode is then converted to vanadium V 2+ and the vanadium V 4+ at the second electrode is then converted to vanadium V 5+ by providing electrical energy to the electrodes. A simple method to produce predominantly vanadium V 4+ electrolyte from a V 5+ source, such as V 2 O 5 , is also taught.

    CARBON ELECTRODE AND METHOD THEREFOR
    3.
    发明申请
    CARBON ELECTRODE AND METHOD THEREFOR 审中-公开
    碳电极及其方法

    公开(公告)号:WO2014098917A1

    公开(公告)日:2014-06-26

    申请号:PCT/US2012/071548

    申请日:2012-12-23

    CPC classification number: H01M4/96 H01M8/188 Y02E60/528

    Abstract: A method of treating a carbon electrode includes providing a carbon-based electrode that has a surface with chemically different carbon oxides. The surface is treated with a reducing agent to reduce at least a portion of the oxides to a target carbon oxide. In an aspect, a method of treating a carbon electrode includes providing a carbon-based electrode that has a surface with an initial non-zero concentration of a target carbon oxide. The surface is then treated with a reducing agent to increase the initial non-zero concentration of the target carbon oxide.

    Abstract translation: 一种处理碳电极的方法包括提供具有化学上不同的碳氧化物的表面的碳基电极。 用还原剂处理表面以将至少一部分氧化物还原成目标碳氧化物。 在一方面,一种处理碳电极的方法包括提供具有目标碳氧化物的初始非零浓度的表面的碳基电极。 然后用还原剂处理表面以增加目标碳氧化物的初始非零浓度。

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