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    CARBONYLATIVE POLYMERIZATION METHODS
    1.
    发明申请
    CARBONYLATIVE POLYMERIZATION METHODS 审中-公开
    碳化聚合方法

    公开(公告)号：WO2011163309A2

    公开(公告)日：2011-12-29

    申请号：PCT/US2011041364

    申请日：2011-06-22

    Applicant: UNIV CORNELL ,  COATES GEOFFREY W ,  DUNN ERIN

    Inventor： COATES GEOFFREY W ,  DUNN ERIN

    IPC: C08G63/78 ,  C08G63/08 ,  C08G63/82

    CPC classification number: C08G63/823

    Abstract: Provided are methods forming polymers. The methods include, for example, tandem carbonylation and polymerization reactions, where epoxides are catalytically carbonylated to form lactones and the lactones catalytically polymerized to form polymers without the need to isolate or purify the lactone intermediate. Also provided are methods for catalytically polymerizing beta-propiolactone. Homopolymers and copolymers can be formed using the methods disclosed herein.

    Abstract translation: 提供了形成聚合物的方法。 这些方法包括例如串联羰基化和聚合反应，其中环氧化物被催化羰基化以形成内酯，并且内酯被催化聚合以形成聚合物，而不需要分离或纯化内酯中间体。 还提供了用于催化聚合β-丙内酯的方法。 均聚物和共聚物可以使用本文公开的方法形成。

    PYRIDLYAMIDOHAFNIUM CATALYST PRECURSORS, ACTIVE SPECIES FROM THIS AND USES THEREOF TO POLYMERIZE ALKENES
    2.
    发明申请
    PYRIDLYAMIDOHAFNIUM CATALYST PRECURSORS, ACTIVE SPECIES FROM THIS AND USES THEREOF TO POLYMERIZE ALKENES 审中-公开
    PYRIDLYAMIDOHAFNIUM催化剂前体，其主要物种及其用于聚合烯烃的用途

    公开(公告)号：WO2008112133A3

    公开(公告)日：2008-11-06

    申请号：PCT/US2008003010

    申请日：2008-03-07

    Applicant: UNIV CORNELL ,  COATES GEOFFREY W ,  DOMSKI GREGORY J

    Inventor： COATES GEOFFREY W ,  DOMSKI GREGORY J

    IPC: B01J21/00

    CPC classification number: A61K31/7072

    Abstract: Cs-Symmetric pyridylamidohafhium catalyst precursors and active species based thereon are described. The active species are used for living polymerization of C 2 -C 20 alkenes and provide highly isotactic polypropylene and are useful to provide multi-block copolymer with end blocks of isotactic polypropylene or isotactic poly(4-methyl-1-pentene).

    Abstract translation: 描述了Cs-对称吡啶基酰胺铪催化剂前体和基于其的活性物质。 活性物质用于C 2 -C 20 -C 20烯烃的活性聚合，并提供高度全同立构聚丙烯，并且可用于向全同立构聚丙烯的末端嵌段提供多嵌段共聚物或 全同立构聚（4-甲基-1-戊烯）。

    POLYETHERS, METHODS OF MAKING SAME, AND USES THEREOF
    3.
    发明申请
    POLYETHERS, METHODS OF MAKING SAME, AND USES THEREOF 审中-公开
    聚酯，其制备方法及其用途

    公开(公告)号：WO2012166889A3

    公开(公告)日：2013-05-02

    申请号：PCT/US2012040165

    申请日：2012-05-31

    Applicant: UNIV CORNELL ,  COATES GEOFFREY W ,  WIDGER PETER C B

    Inventor： COATES GEOFFREY W ,  WIDGER PETER C B

    IPC: C08G65/08 ,  C08G18/48 ,  C08G65/10 ,  C08L71/02 ,  C08L75/04

    CPC classification number: C08G65/2609 ,  C08G18/4825 ,  C08G65/2606 ,  C08G65/266

    Abstract: Isotactic polyethers, methods of making polyethers, and uses of polyethers. The polyethers have a chain transfer group formed from a chain transfer agent. The methods of making the polyethers use monoalcohol chain transfer agents or multifunctional chain transfer agents. The polyethers can be used in materials, such as polyurethanes, elastomers, thermoset plastics, and thermoplastics, and as non-ionic surfactants.

    Abstract translation: 全同立构聚醚，聚醚的制备方法和聚醚的用途。 聚醚具有由链转移剂形成的链转移基团。 制备聚醚的方法是使用一元醇链转移剂或多官能链转移剂。 聚醚可以用于诸如聚氨酯，弹性体，热固性塑料和热塑性塑料的材料中，也可用作非离子表面活性剂。

    GROUP IV OLEFIN POLYMERIZATION CATALYSTS AND POLYMERIZATION METHODS
    4.
    发明申请
    GROUP IV OLEFIN POLYMERIZATION CATALYSTS AND POLYMERIZATION METHODS 审中-公开
    第IV组烯烃聚合催化剂和聚合方法

    公开(公告)号：WO2010148381A2

    公开(公告)日：2010-12-23

    申请号：PCT/US2010039302

    申请日：2010-06-21

    Applicant: UNIV CORNELL ,  COATES GEOFFREY W ,  EDSON JOSEPH B

    Inventor： COATES GEOFFREY W ,  EDSON JOSEPH B

    IPC: C08F4/64 ,  C08F10/00 ,  C08F297/08

    CPC classification number: C08F297/083 ,  C08F10/00 ,  C08F110/06 ,  C08F210/06 ,  C08F210/16 ,  C08F236/20 ,  Y02P20/52 ,  C08F4/64155 ,  C08F2500/03 ,  C08F210/14

    Abstract: The present invention relates to olefin polymerization catalysts including a novel phenoxyaminetitanium(II) alkene complex, rac-Lig2 TiBn, which is inactive for olefin polymerization upon benzyl abstraction, treatment with ethylene leads to the formation of a stable titanacyclopentane complex (rac-Lig2(CH2)2TiBn). Six-membered metallacycle complexes (rac-Lig1ZrBn2-a,b and rac-Lig1HfBn2-a,b) were obtained from reaction of the vinylappended ligand with tetrabenzylzirconium (ZrBn4) or tetrabenzylhafnium (HfBn4). Living and isoselective polymerization of 1-hexene was promoted by rac-Lig1HfBn2- a,b/B(C6F5)3 at 0°C, while rac-Lig1ZrBn2-a,b/B(C6F5)3 catalyzed the living and isoselective polymerization of propylene at 0°C. This catalyst system was employed for the synthesis of a diblock copolymer featuring an isotactic polypropylene semicrystalline block and poly(ethylene-co-propylene) amorphous block. Complexes derived from rac-Lig1HfBn2-a,b and rac-Lig1ZrBn2-a,b also served as highly active cyclopolymerization catalysts for 1,5- hexadiene which furnished poly(methylene-l,3-cyclopentane) with a predominance of cis- cyclopentane rings. Lastly, cyclopolymerization of 1,6-heptadiene with rac-Lig1HfBn2- a,b/B(C6F5)3 produced poly(methylene-1,3-cyclohexane) with a nearly perfect cis-isotactic microstructure.

    Abstract translation: 本发明涉及烯烃聚合催化剂，其包括新颖的苯氧基氨基钛（II）烯烃配合物，外消旋-Lig2TiBn，其在苄基取代时对烯烃聚合无活性，用乙烯处理导致形成稳定的十二烷基环戊烷配合物（rac-Lig2（ CH2）2TiBn）。 通过乙烯基配体与四苄基锆（ZrBn4）或四苄基铪（HfBn4）的反应获得六元金属环络合物（rac-Lig1ZrBn2-a，b和rac-Lig1HfBn2-a，b）。 在0℃下，rac-Lig1HfBn2-a，b / B（C6F5）3促进了1-己烯的活性和异构选择性聚合，而rac-Lig1ZrBn2-a，b / B（C6F5）3催化活性和选择性聚合 丙烯在0℃。 该催化剂体系用于合成具有全同立构聚丙烯半结晶嵌段和聚（乙烯 - 共 - 丙烯）无定形嵌段的二嵌段共聚物。 衍生自rac-Lig1HfBn2-a，b和rac-Lig1ZrBn2-a，b的复合物也用作1,5-己二烯的高活性环聚合催化剂，其提供主要为顺式环戊烷的聚（亚甲基-1,3-环戊烷） 戒指。 最后，1,7-庚二烯与外消旋-Lig1HfBn2-a，b / B（C6F5）3的环化聚合产生了具有接近完美的顺式 - 全同立构微观结构的聚（亚甲基-1,3-环己烷）。

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