公开(公告)号：WO2015021111A1

公开(公告)日：2015-02-12

申请号：PCT/US2014/049878

申请日：2014-08-06

Applicant: UOP LLC

Inventor： LAPINSKI, Mark P. ,  FUNK, Gregory

IPC: C10G35/00 ,  C10G3/00

CPC classification number: C07C5/2206 ,  C07C5/277 ,  C07C6/10 ,  C07C2521/04 ,  C07C2523/42 ,  C10G45/58 ,  Y02P30/20 ,  C07C9/15 ,  C07C9/10 ,  C07C9/14

Abstract: A process for increasing disproportionation and ring opening reactions an isomerization zone which converts iso-paraffins to normal paraffins. In order to promote these reactions, the amount of C 6 cyclic hydrocarbons entering the isomerization zone is reduced. Disproportionation reaction selectivity is observed which produces valuable C 3 hydrocarbons and C 4 hydrocarbons. Also, a higher ring opening conversion of C 5 cyclic hydrocarbons is observed. Conversion of iC 4 hydrocarbons, iC 5 hydrocarbons, and iC 6 hydrocarbons may occur in the same isomerization zone.

Abstract translation: 增加歧化和开环反应的方法是将异链烷烃转化为正构烷烃的异构化区。 为了促进这些反应，进入异构化区的C6环烃的量减少。 观察到歧化反应选择性，产生有价值的C3烃和C4烃。 此外，观察到C5环烃的较高的开环转化率。 iC4烃，iC5烃和iC6烃的转化可能发生在相同的异构化区域。

公开(公告)号：WO2021183323A1

公开(公告)日：2021-09-16

申请号：PCT/US2021/020489

申请日：2021-03-02

Applicant: UOP LLC

Inventor： FUNK, Gregory ,  PLOENTHAM, Cora Wang ,  MININ, Marina S. ,  LAPINSKI, Mark P. ,  SHECTERLE, David J. ,  BOEHM, Ernest J.

IPC: C07C5/13 ,  C07C5/27 ,  C07C9/16

Abstract: A process increases the concentration of normal paraffins in a feed stream comprising separating a naphtha feed stream into a normal paraffin rich stream and a non-normal paraffin rich stream. The non-normal paraffin rich stream is isomerized over a first isomerization catalyst to convert non-normal paraffins to normal paraffins and produce a first isomerization effluent stream. An iso-C4 stream is separated from the first isomerization effluent stream and isomerized over a second isomerization catalyst to convert iso-C4 hydrocarbons to normal C4 hydrocarbons and produce a second isomerization effluent stream. The normal paraffin rich stream, the normal paraffins in the first isomerization effluent stream and/or the second isomerization effluent stream may be fed to a steam cracker.

公开(公告)号：WO2015167841A2

公开(公告)日：2015-11-05

申请号：PCT/US2015/026590

申请日：2015-04-20

Applicant: UOP LLC

Inventor： LAPINSKI, Mark P. ,  LIPPMANN, Matthew ,  FUNK, Gregory ,  SHECTERLE, David James ,  MOKKA, Lakshmi P.

CPC classification number: C07C7/005 ,  C07C4/06 ,  C07C5/00 ,  C07C5/27 ,  C07C5/2754 ,  C07C6/123 ,  C07C7/04 ,  C07C7/13 ,  C07C2521/04 ,  C07C2523/42 ,  C10G45/62 ,  C10G2300/1044 ,  C10G2300/1081 ,  C07C9/16 ,  C07C9/18 ,  C07C9/08 ,  C07C9/10 ,  C07C9/12 ,  C07C9/14

Abstract: A process for controlling a yield of an isomerization zone. Prior to entering the isomerization zone, C 6 cyclic hydrocarbons are removed from a feed stream. Disproportionation reaction selectivity is observed which produces valuable C 3 hydrocarbons and C 4 hydrocarbons. Also, a higher ring opening conversion of C 5 cyclic hydrocarbons is observed. The disproportionation reactions and the ring opening reactions may be selectively controlled by adjusting an amount of C 6 cyclic hydrocarbons passed into the isomerization zone.

Abstract translation: 用于控制异构化区的产率的方法。 在进入异构化区之前，从进料流中除去C6环烃。 观察到歧化反应选择性，产生有价值的C3烃和C4烃。 此外，观察到C5环烃的较高的开环转化率。 歧化反应和开环反应可以通过调节进入异构化区的C6环烃的量来选择性地控制。

公开(公告)号：WO2015126705A1

公开(公告)日：2015-08-27

申请号：PCT/US2015/015523

申请日：2015-02-12

Applicant: UOP LLC

Inventor： MOSER, Mark D. ,  SERBAN, Manuela ,  LAPINSKI, Mark P.

IPC: C10G11/02 ,  C10G11/00

CPC classification number: C07C2/76 ,  C10G35/09 ,  C10G2400/30

Abstract: A process for generating aromatics from a hydrocarbon feedstream is disclosed. The process includes the steps of (a) passing the hydrocarbon feedstream to a reformer, wherein the reformer is operated at a temperature greater than 540°C; and (b) reforming the hydrocarbon feedstream to aromatics in the presence of a catalyst, wherein the catalyst comprises (i) a refractory inorganic oxide support, (ii) a platinum group metal, (iii) a Group IVA metal, (iv) a third metal selected from alkali metals and alkaline earth metals, and (v) a halogen.

Abstract translation: 公开了一种从烃类原料流产生芳族化合物的方法。 该方法包括以下步骤：（a）使烃进料流通入重整器，其中重整器在大于540℃的温度下操作; 和（b）在催化剂存在下将烃进料流重整成芳族化合物，其中催化剂包括（i）耐火无机氧化物载体，（ii）铂族金属，（iii）第IVA族金属，（iv） 选自碱金属和碱土金属的第三种金属，和（v）卤素。

公开(公告)号：WO2020028285A1

公开(公告)日：2020-02-06

申请号：PCT/US2019/044013

申请日：2019-07-30

Applicant: UOP LLC

Inventor： LUEBKE, Charles P. ,  JIN, Lin ,  DIGIULIO, Christopher ,  LAPINSKI, Mark P.

IPC: C10G69/08 ,  C10G63/00 ,  C07C5/22

Abstract: An integrated process for production of gasoline has been described. The process includes a C 5 -C 6 isomerization zone, two C 7 isomerization zones separate by a deisoheptanizer, and a reforming zone. The use of two C 7 isomerization zones eliminates the need for the large recycle stream from the deisoheptanizer. The low temperature in first C 7 isomerization zone favors the formation of multi-branched C 7 paraffins and cyclohexanes and maximizes C 5 + yield. The separation between paraffin and cycloalkane in deisoheptanizer becomes easier due to conversion of cycloalkanes to cyclohexanes in the first C 7 isomerization zone. Further, the high temperature in second C 7 isomerization zone favors the formation of higher octane cyclopentanes over cyclohexanes. An aromatic-containing stream can be introduced to second C 7 isomerization zone. The saturation of the aromatics in the second C 7 isomerization zone provides heat that increases the reactor outlet temperature in the isomerization reactors to favor cyclopentanes.

公开(公告)号：WO2012148830A3

公开(公告)日：2012-11-01

申请号：PCT/US2012/034606

申请日：2012-04-23

Applicant: UOP LLC ,  MOSER, Mark D. ,  SADLER, Clayton C. ,  LAPINSKI, Mark P.

Inventor： MOSER, Mark D. ,  SADLER, Clayton C. ,  LAPINSKI, Mark P.

IPC: C10G61/02 ,  C10G59/02 ,  C10G35/04

Abstract: A process for reforming a hydrocarbon stream is presented. The process involves increasing the processing temperatures in the reformers. The reformers are operated under different conditions to utilize advantages in the equilibriums, but require modifications to prevent increasing thermal cracking and to prevent increases in coking. The process utilizes a common catalyst, and common downstream processes for recovering the desired aromatic compounds generated.

公开(公告)号：WO2011075410A2

公开(公告)日：2011-06-23

申请号：PCT/US2010/059875

申请日：2010-12-10

Applicant: UOP LLC ,  SERBAN, Manuela ,  LAPINSKI, Mark P. ,  MOSER, Mark D.

Inventor： SERBAN, Manuela ,  LAPINSKI, Mark P. ,  MOSER, Mark D.

IPC: C10G61/04 ,  C10G35/04 ,  C10G25/00

CPC classification number: C10G25/003 ,  C10G61/06 ,  C10G2300/1044 ,  C10G2300/1096 ,  C10G2300/301 ,  C10G2300/305 ,  C10G2300/4018 ,  C10G2400/02

Abstract: An exemplary embodiment can be a process for removing one or more polynuclear aromatics from at least one reformate stream from a reforming zone. The PNAs may be removed using an adsorption zone. The adsorption zone can include first and second vessels each vessel containing an activated carbon adsorbent. Generally, the process includes passing the at least a portion of an effluent of the reforming zone through the first vessel containing a first activated carbon adsorbent wherein the first activated carbon adsorbent comprises iron.

Abstract translation: 示例性实施方案可以是用于从来自重整区的至少一种重整产品物流中除去一种或多种多核芳族化合物的方法。 可以使用吸附区域去除PNA。 吸附区可以包括第一和第二容器，每个容器含有活性炭吸附剂。 通常，该方法包括使重整区的流出物的至少一部分通过含有第一活性炭吸附剂的第一容器，其中第一活性炭吸附剂包含铁。

公开(公告)号：WO2013148388A1

公开(公告)日：2013-10-03

申请号：PCT/US2013/032755

申请日：2013-03-18

Applicant: UOP LLC

Inventor： LAPINSKI, Mark P. ,  VANDEN BUSSCHE, Kurt M. ,  SERBAN, Manuela

IPC: B01J37/00 ,  B01J23/58 ,  C10G35/09 ,  C10G59/02

CPC classification number: C10G35/24 ,  B01J23/96 ,  B01J38/44 ,  C10G35/04 ,  C10G35/06 ,  C10G35/12

Abstract: One exemplary embodiment can be a process for facilitating adding a promoter metal to at least one catalyst particle in situ in a catalytic naphtha reforming unit. The process can include introducing a compound comprising the promoter metal to the catalyst naphtha reforming unit and adding an effective amount of the promoter metal from the compound comprising the promoter metal to the catalyst particle under conditions to effect such addition and improve a conversion of a hydrocarbon feed.

Abstract translation: 一个示例性实施方案可以是促进助催化剂金属在催化石脑油重整单元中原位加入至少一种催化剂颗粒的方法。 该方法可以包括将催化剂石脑油重整单元引入包含助催化剂金属的化合物，并且在实施这种添加的条件下将有效量的助催化剂金属从包含促进剂金属的化合物加入催化剂颗粒中，并改善烃的转化率 饲料。

公开(公告)号：WO2012148834A2

公开(公告)日：2012-11-01

申请号：PCT/US2012/034610

申请日：2012-04-23

Applicant: UOP LLC ,  GAJDA, Gregory J. ,  WIER, Mary Jo ,  LAPINSKI, Mark P. ,  WEGERER, David A. ,  VANDEN BUSSCHE, Kurt M. ,  MOSER, Mark D.

Inventor： GAJDA, Gregory J. ,  WIER, Mary Jo ,  LAPINSKI, Mark P. ,  WEGERER, David A. ,  VANDEN BUSSCHE, Kurt M. ,  MOSER, Mark D.

IPC: C10G63/04 ,  C10G61/02 ,  C10G59/02 ,  C10G35/04

CPC classification number: C10G35/04 ,  C10G35/06 ,  C10G35/065 ,  C10G35/085 ,  C10G59/06 ,  C10G2300/1044 ,  C10G2400/30

Abstract: A process for reforming a hydrocarbon stream is presented. The process involves splitting a naphtha feedstream to at least two feedstreams and passing each feedstream to separation reformers. The reformers are operated under different conditions to utilize the differences in the reaction properties of the different hydrocarbon components. The process utilizes a common catalyst, and common downstream processes for recovering the desired aromatic compounds generated.

公开(公告)号：WO2010056412A2

公开(公告)日：2010-05-20

申请号：PCT/US2009/055639

申请日：2009-09-02

Applicant: UOP LLC ,  LAPINSKI, Mark P. ,  ROSIN, Richard R. ,  SCHREIER, Marc R.

Inventor： LAPINSKI, Mark P. ,  ROSIN, Richard R. ,  SCHREIER, Marc R.

IPC: C10G35/12 ,  C10G35/02

CPC classification number: C10G35/06 ,  B01J23/08 ,  B01J27/13 ,  B01J27/32 ,  B01J38/02 ,  B01J38/10 ,  B01J38/44 ,  B01J38/48 ,  B01J38/60 ,  C10G35/085 ,  C10G2300/1044 ,  C10G2300/70

Abstract: One exemplary embodiment can be a process for facilitating adding a promoter metal to at least one catalyst particle in situ in a catalytic naphtha reforming unit. The process can include introducing a compound comprising the promoter metal to the catalyst naphtha reforming unit and adding an effective amount of the promoter metal from the compound comprising the promoter metal to the catalyst particle under conditions to effect such addition and improve a conversion of a hydrocarbon feed.

Abstract translation: 一个示例性实施方案可以是促进将促进剂金属原位加入催化石脑油重整单元中的至少一种催化剂颗粒的方法。 该方法可包括将包含助催化剂金属的化合物引入催化剂石脑油重整单元，并在有效添加的条件下将含有助催化剂金属的化合物中的有效量的助催化剂金属加入催化剂颗粒中，并改善烃 进料。