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    2차원 하이브리드 복합체 제조 방법
    1.
    发明申请
    2차원 하이브리드 복합체 제조 방법 审中-公开
    制造二维混合复合材料的方法

    公开(公告)号：WO2017065340A1

    公开(公告)日：2017-04-20

    申请号：PCT/KR2015/011833

    申请日：2015-11-05

    Applicant: 한국세라믹기술원

    Inventor： 허승헌

    IPC: C01B31/02 ,  C01B31/04 ,  B01J19/10

    CPC classification number: C10M103/02 ,  B01J27/051 ,  B01J35/004 ,  C10M103/06 ,  C10M2201/0413 ,  C10M2201/065 ,  C10M2201/066 ,  H01B1/04

    Abstract: 본 발명은 2차원 판상소재에서 발생하는 문제 즉, 2차원 판상소재가 겹쳐짐에 따라 발생하는 단차 문제, 결함문제, 퍼짐문제 등을 해결할 수 있는 2차원 하이브리드 복합체 제조 방법에 관한 것이다. 본 발명은 「(a) 제1판상소재를 고상 또는 액상으로 준비하는 단계; (b) 상기 제1판상소재 보다 두께가 얇고 유연성이 있는 제2판상소재를 상기 제1판상소재와 혼합시키는 단계; (c) 고상 또는 액상의 결합재를 상기 제1·2판상소재와 혼합시켜 상기 제1·2판상소재가 일부 접촉하거나 상호 이격되도록 하는 단계; 및 (d) 상기 (a)단계 내지 (c)단계를 거쳐 형성된 복합체를 고상화시키는 단계; 를 포함하는 2차원 하이브리드 복합체 제조 방법」을 제공한다.

    Abstract translation:

    本发明是在于，在重叠引起的步骤的问题的二维片材料的片材的二维问题，缺陷问题，铺展问题解决二维杂化复合物制备的 ＆lt; （A）制备固体或液体形式的第一板材; （b）将厚度小于第一板状材料的厚度且具有挠性的第二板状材料与第一板状材料混合; （c）将固体或液体粘合剂与第一和第二板状材料混合，使得第一和第二板状材料彼此部分接触或间隔开; （d）固化通过上述步骤（a）至（c）形成的配合物; ＆lt; 1＆gt;＆lt;

    METHODS AND SYSTEMS FOR UPGRADING HEAVY OIL USING CATALYTIC HYDROCRACKING AND THERMAL COKING
    4.
    发明申请
    METHODS AND SYSTEMS FOR UPGRADING HEAVY OIL USING CATALYTIC HYDROCRACKING AND THERMAL COKING 审中-公开
    使用催化水解和热处理提高重油的方法和系统

    公开(公告)号：WO2014022243A1

    公开(公告)日：2014-02-06

    申请号：PCT/US2013/052422

    申请日：2013-07-26

    Applicant: HEADWATERS HEAVY OIL, LLC ,  HARRIS, Everette ,  GENDLER, Jeffrey

    Inventor： HARRIS, Everette ,  GENDLER, Jeffrey

    IPC: C10G47/06

    CPC classification number: C10G69/06 ,  B01J23/28 ,  B01J27/043 ,  B01J27/047 ,  B01J27/051 ,  B01J35/026 ,  B01J35/108 ,  B01J35/109 ,  B01J37/04 ,  B01J37/086 ,  B01J37/20 ,  C10B55/00 ,  C10B57/045 ,  C10G9/005 ,  C10G47/12 ,  C10G2300/206

    Abstract: Methods and systems for hydro processing heavy oil feed stocks to form an upgraded material involve the use of a well-dispersed metal sulfide catalyst (e.g., colloidal or molecular catalyst) dispersed within a heavy oil feedstock, a pre-coking hydro cracking reactor, a separator, and a coking reactor. The metal sulfide catalyst promotes upgrading reactions that reduce the quantity of asphaltenes or other coke forming precursors in the feedstock, increase hydrogen to carbon ratio in the upgraded material, and decrease boiling points of hydrocarbons in the upgraded material. The methods and systems can be used to upgrade vacuum tower bottoms and other low grade heavy oil feed stocks. The result is one or more of increased conversion level and yield, improved quality of upgraded hydrocarbons, reduced coke formation, reduced equipment fouling, processing of a wider range of lower quality feed stocks, and more efficient use of supported catalyst if used in combination with the metal sulfide catalyst, as compared to a conventional hydro cracking process or a conventional thermal coking process.

    Abstract translation: 用于加氢重油原料以形成改质材料的方法和系统包括使用分散在重油原料中的良好分散的金属硫化物催化剂（例如胶体或分子催化剂），预焦化氢裂解反应器， 分离器和焦化反应器。 金属硫化物催化剂促进升级反应，其降低原料中沥青质或其它焦炭形成前体的量，提高改质材料中的氢碳比，并降低改质材料中烃的沸点。 该方法和系统可用于升级真空塔底部和其他低级重油原料。 结果是提高的转化水平和产率，提高的碳氢化合物的质量，降低的焦炭形成，减少的设备结垢，加工更广泛的较低质量的原料的一个或多个，以及更有效地使用负载型催化剂，如果与 金属硫化物催化剂，与常规的水解裂化工艺或传统的热焦化工艺相比。

    PROCESS FOR TREATING A HYDROCARBON-CONTAINING FEED
    7.
    发明申请
    PROCESS FOR TREATING A HYDROCARBON-CONTAINING FEED 审中-公开
    处理含油料饲料的方法

    公开(公告)号：WO2012078835A3

    公开(公告)日：2013-03-21

    申请号：PCT/US2011063876

    申请日：2011-12-08

    Applicant: SHELL OIL CO ,  SHELL INT RESEARCH ,  MILAM STANLEY NEMEC ,  REYNOLDS MICHAEL ANTHONY ,  WELLINGTON SCOTT LEE ,  RANGANATHAN EASWAR SANTHOSH ,  CHAN WIN SIM

    Inventor： MILAM STANLEY NEMEC ,  REYNOLDS MICHAEL ANTHONY ,  WELLINGTON SCOTT LEE ,  RANGANATHAN EASWAR SANTHOSH ,  CHAN WIN SIM

    IPC: C10G69/04

    CPC classification number: C10G69/04 ,  B01J27/047 ,  B01J27/051 ,  C10G11/182 ,  C10G45/04 ,  C10G47/02 ,  C10G47/06 ,  C10G47/26 ,  C10G65/12 ,  C10G2300/202 ,  C10G2300/205 ,  C10G2300/301 ,  C10G2300/4006 ,  C10G2300/4012 ,  C10G2400/02

    Abstract: A process is provided in which a first hydrocarbon-containing composition is provided. The first hydrocarbon-containing composition contains hydrocarbons having a boiling range of from 25 °C to 538 °C and contains from 0.1 wt.% to 5 wt.% sulfur on an atomic basis. At least 40 wt.% of the sulfur, on an atomic sulfur basis, is contained in hydrocarbon compounds having a boiling point of less than 343°C, and at least 40 wt. % of the sulfur contained in hydrocarbon compounds having a boiling point of less than 343 °C in the first hydrocarbon-containing composition is contained in benzothiophenic compounds. The first hydrocarbon-containing composition is contacted with hydrogen and a catalyst containing a Column 6 metal at a temperature of 260 °C-425 °C to produce a second hydrocarbon-containing composition. The second hydrocarbon-containing composition is separated into fractions, one of the fractions being a heavy hydrocarbon fraction comprised of hydrocarbons having a boiling point of at least 343 °C. The heavy hydrocarbon fraction is contacted with a fluidizable cracking catalyst at a temperature of at least 500 °C.

    Abstract translation: 提供了提供第一含烃组合物的方法。 第一含烃组合物含有沸点范围为25℃至538℃的烃，其原子含量为0.1重量％至5重量％。 至少40重量％的硫以原子硫为基准包含在沸点小于343℃的烃化合物中，并且至少40重量％ 在第一含烃组合物中沸点低于343℃的烃化合物中所含的硫的％含在苯并噻吩类化合物中。 将第一含烃组合物与氢气和含有第6列金属的催化剂在260℃-425℃的温度下接触以产生第二含烃组合物。 将第二含烃组合物分离成馏分，其中一个馏分是由沸点为至少343℃的烃组成的重质烃馏分。 重质烃馏分在至少500℃的温度下与可流化的裂化催化剂接触。

    CATALYTIC SYSTEM AND PROCESS FOR THE TOTAL HYDROCONVERSION OF HEAVY OILS
    8.
    发明申请
    CATALYTIC SYSTEM AND PROCESS FOR THE TOTAL HYDROCONVERSION OF HEAVY OILS 审中-公开
    催化体系及重油总氢过程

    公开(公告)号：WO2013034642A1

    公开(公告)日：2013-03-14

    申请号：PCT/EP2012/067412

    申请日：2012-09-06

    Applicant: ENI S.P.A. ,  MOLINARI, Daniele ,  BELLUSSI, Giuseppe ,  LANDONI, Alberto ,  POLLESEL, Paolo

    Inventor： MOLINARI, Daniele ,  BELLUSSI, Giuseppe ,  LANDONI, Alberto ,  POLLESEL, Paolo

    IPC: B01J27/051 ,  B01J29/78 ,  C10G45/12

    CPC classification number: B01J29/89 ,  B01J27/051 ,  B01J29/7876 ,  C10G45/12 ,  C10G47/16 ,  C10G65/12

    Abstract: A catalytic system characterized in that it comprises: a first catalyst, having a hydrogenating function, consisting of solid particles of which at least 95% by volume having an equivalent diameter smaller than 20 μm, containing one or more sulfides of metals of group VI and/or VIII B, possibly prepared starting from an oil- soluble precursor of the same; and a second catalyst, having a cracking function, consisting of solid particles of which at least 90% by volume having an equivalent diameter larger than 5 μm and smaller than 5 mm, containing an amorphous silico- aluminate and/or a crystalline silico-aluminate and/or an alumina, the equivalent average diameter of the solid particles of the second catalyst being greater than the equivalent average diameter of the solid particles of the first catalyst. Said catalytic system can be used in a process for the hydroconversion of heavy oils which comprises sending the heavy oil to a hydroprocessing step carried out in one or more slurry reactors, in the presence of hydrogen or a mixture of hydrogen and H 2 S, obtaining a stream of products in vapour or liquid-vapour phase, and extracting at the bottom, in continuous or discontinuous, a liquid stream containing non-converted products together with the two catalysts of said catalytic system, said liquid stream extracted then being separated into a clarified primary stream containing the first catalyst, which is at least partially recycled to the hydroprocessing step, and a stream rich in the second catalyst, which is regenerated in a regeneration step and at least partially recycled to the hydroprocessing step.

    Abstract translation: 一种催化体系，其特征在于它包括：具有氢化功能的第一催化剂，其由至少95体积％的当量直径小于20μm的固体颗粒组成，其含有一种或多种第VI族金属的硫化物，和 /或VIII B，可能从其油溶性前体开始制备; 和具有裂化功能的第二催化剂，其由固体颗粒组成，其中至少90体积％的当量直径大于5μm且小于5mm，其含有非晶硅铝酸盐和/或结晶硅铝酸盐 和/或氧化铝，所述第二催化剂的固体颗粒的当量平均直径大于所述第一催化剂的固体颗粒的当量平均直径。 所述催化体系可用于重油加氢转化的方法，其包括将重油送入在一种或多种淤浆反应器中，在氢气或氢气和H 2 S的混合物存在下进行的加氢处理步骤，获得流 的蒸气或液相 - 蒸气相中的产物，并且连续或不连续地将含有未转化产物的液体物流与所述催化体系的两种催化剂一起萃取，然后将所述液体流分离成澄清的初级 含有至少部分再循环到加氢处理步骤的第一催化剂的物流和富含第二催化剂的物流，其在再生步骤中再生并且至少部分地循环到加氢处理步骤。

    METHODS FOR PROMOTING SYNGAS-TO-ALCOHOL CATALYSTS
    10.
    发明申请
    METHODS FOR PROMOTING SYNGAS-TO-ALCOHOL CATALYSTS 审中-公开
    促进乙醇对醇催化剂的方法

    公开(公告)号：WO2010036848A3

    公开(公告)日：2010-06-24

    申请号：PCT/US2009058295

    申请日：2009-09-25

    Applicant: MEITZNER GEORGE ,  KHARAS KARL ,  RANGE FUELS INC

    Inventor： MEITZNER GEORGE ,  KHARAS KARL

    IPC: B01J27/051 ,  B01J23/04 ,  B01J37/00

    CPC classification number: B01J27/0515 ,  B01J27/051 ,  B01J27/232 ,  B01J35/002 ,  B01J37/08

    Abstract: The present invention provides methods of intercalating a catalyst promoter to form a catalyst composition suitable for converting syngas into alcohols, such as ethanol. Effective conditions for promoter intercalation are provided herein. This invention also provides novel compositions that can be characterized by interplanar spacings of the promoter within the catalyst composition.

    Abstract translation: 本发明提供了插入催化剂促进剂以形成适于将合成气转化为醇的催化剂组合物如乙醇的方法。 本文提供了启动子插入的有效条件。 本发明还提供了新颖的组合物，其特征在于助催化剂在催化剂组合物内的面间距。

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