SOLVENTLESS POLYURETHANE SPRAY COMPOSITIONS AND METHOD FOR APPLYING THEM
    2.
    发明申请
    SOLVENTLESS POLYURETHANE SPRAY COMPOSITIONS AND METHOD FOR APPLYING THEM 审中-公开
    无溶剂聚氨酯喷涂组合物及其应用方法

    公开(公告)号:WO1987007287A1

    公开(公告)日:1987-12-03

    申请号:PCT/US1987001216

    申请日:1987-05-26

    Applicant: AMERON, INC.

    Abstract: A method for preparing polyurethane by spraying solventless, equal volume mixtures of: (a) a liquid polyisocyanate; polyisocyanurate or isocyanate terminated quasi-prepolymer; and (b) a curing agent comprised of a blend of from about 0 to 15 % of a polyamine having an equivalent weight from about 30 to about 200, about 10 to 20 % of a low molecular weight glycol having an equivalent weight of from about 30 to 200, about 40 to 80 % of a relatively high molecular weight polyol or polyamine having an equivalent weight of about 350 to 2000, and about 1 to 20 % of a synthetic zeolite molecular sieve, wherein the average equivalent weight of (b) is from about 150 to 500.

    CATALYSTS FOR LOW TEMPERATURE CURE OF BLOCKED ISOCYANATES
    4.
    发明申请
    CATALYSTS FOR LOW TEMPERATURE CURE OF BLOCKED ISOCYANATES 审中-公开
    用于低温阻塞异氰酸酯的催化剂

    公开(公告)号:WO1995004093A1

    公开(公告)日:1995-02-09

    申请号:PCT/US1994008293

    申请日:1994-07-26

    Abstract: The present invention comprises a curable composition comprising: (i) a blocked reactive component comprising a blocked isocyanate or a blocked isothiocyanate; (ii) a functional component containing reactive hydrogen; (iii) a triorganotin catalyst for promoting the reaction of the blocked reactive component with the functional component. The composition may also be admixed with water. A co-catalyst may also be employed based on Cu, Zn, Ni, Fe, Co, V, Sb and Bi and especially oxides, salts or chelates of said metal where said metals are divalent. The invention also relates to a method for curing a blocked isocyanate or blocked isothiocyanate at a temperature below about 150 DEG C which comprises combining a triorganotin catalyst with the blocked reactive component and functional component and heating at a temperature less than about 150 DEG C to obtain a cured urethane or thiourethane.

    Abstract translation: 本发明包括可固化组合物,其包含:(i)包含封端异氰酸酯或封端异硫氰酸酯的封闭反应性组分; (ii)含有反应性氢的功能组分; (iii)用于促进阻断的反应性组分与官能组分的反应的三有机锡催化剂。 组合物也可以与水混合。 还可以使用基于Cu,Zn,Ni,Fe,Co,V,Sb和Bi的助催化剂,特别是所述金属的二价氧化物,盐或螯合物。 本发明还涉及一种在低于约150℃的温度下固化封端的异氰酸酯或封闭的异硫氰酸酯的方法,该方法包括将三有机锡催化剂与封闭的反应性组分和官能组分组合并在小于约150℃的温度下加热得到 固化的氨基甲酸酯或硫代氨基甲酸酯。

    WATER BASED, SOLVENT FREE, TWO COMPONENT ALIPHATIC POLYURETHANE COATING
    7.
    发明申请
    WATER BASED, SOLVENT FREE, TWO COMPONENT ALIPHATIC POLYURETHANE COATING 审中-公开
    基于水,无溶剂,两种组分亲水聚氨酯涂料

    公开(公告)号:WO1994020559A1

    公开(公告)日:1994-09-15

    申请号:PCT/US1994002604

    申请日:1994-03-10

    Abstract: A water based, solvent free, two component polyurethane-polyurea dispersion containing up to 65% solids. The first component is a polyester-polyol phase and an aqueous amine phase mixture. The polyester-polyol is a combination of modified polyester-polyols, low viscosity polyether or polyester-polyols, chain extending low molecular weight polyols, neutralizing amines and a detergent. It has a solids content of 90-100% and is totally hydroxyl functional with a carboxylic acid number of 10 and 50, a hydroxyl number of 180 and 300, an equivalent weight range of 165 and 365 and a viscosity of 600-1500 cps at 25 DEG C. The amine phase is a combination of neutralizing and chain extending amines having ratios preformulated to provide a balanced chain extending cross-linking reaction in aqueous phase with -NCO reactive groups. The aqueous amine blend has an equivalent weight of 40 to 50 and a solids content of 40-60%. The polyester-polyol and amine phases are combined in water at room temperature to form an aqueous component having a solids content of 33 to 48% and has an equivalent ratio between polyester-polyol phase and amine phase of 1.75:1 to 2.25:2. The second component is a 100% solids aliphatic isocyanate having a viscosity of between 1000-3500 cps at 25 DEG C and provides an NCO to functional groups in the polyester-polyol/amine component ratio of between about 1:1.3 to 1:1.7. This solvent free dispersion dries to a film coating having properties equal to conventional solvent based polyurethane coatings.

    Abstract translation: 含有高达65%固体含量的无水溶剂的双组分聚氨酯 - 聚脲分散体。 第一组分是聚酯 - 多元醇相和胺相混合物。 聚酯多元醇是改性聚酯多元醇,低粘度聚醚或聚酯多元醇,链延长低分子量多元醇,中和胺和洗涤剂的组合。 固体含量为90-100%,羧酸数为10和50,羟基数为180和300,当量重为165和365,粘度为600-1500cps,完全为羟基官能度 胺相是中和和链延长胺的组合,其具有预配制的比例,以在水相中与-NCO反应性基团提供平衡的链延伸交联反应。 含水胺混合物的当量为40至50,固体含量为40-60%。 将聚酯 - 多元醇和胺相在室温下在水中合并,形成固体含量为33-48%的水性组分,其聚酯 - 多元醇相和胺相的当量比为1.75:1-2.25:2。 第二组分是在25℃下粘度为1000-3500cps的100%固体脂肪族异氰酸酯,并且在聚酯 - 多元醇/胺组分中的官能团的NCO为约1:1.3至1:1.7。 这种无溶剂的分散体干燥至具有等于常规溶剂型聚氨酯涂料性能的薄膜涂层。

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