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    SQUALENE AND SQUALANE OF HIGH QUALITY PRODUCED BY MICROWAVE ASSISTED PROCESS
    1.
    发明申请
    SQUALENE AND SQUALANE OF HIGH QUALITY PRODUCED BY MICROWAVE ASSISTED PROCESS 审中-公开

    公开(公告)号：WO2020070707A1

    公开(公告)日：2020-04-09

    申请号：PCT/IB2019/058477

    申请日：2019-10-04

    Applicant: SCHOLZ, Gertraud

    Inventor： SCHOLZ, Gertraud

    IPC: C07C5/03 ,  C07C7/17 ,  C07C9/22 ,  C07C11/21

    Abstract: The present invention relates to a product comprising squalene according to Formula I in an amount of equal or more than 50 wt.-% related to the total weight of the product according to Formula I, the product being produced by a continuous flow, microwave assisted process comprising the steps: a) preparing a reaction mixture containing an oily or fatty material of plant origin and aqueous methanol or aqueous ethanol, b) continuously conveying of the reaction mixture through a microwave-transparent reaction zone and irradiating the reaction mixture with microwaves inside the reaction zone in the presence of an acidic catalyst, whereby the retention time of the reaction mixture in the microwave-transparent reaction zone is 1 s to 180 s, the temperature in the reaction zone being equal to or between 100 °C and 220 °C, the pressure in the reaction zone being 1.5 bar to 30 bar, wherein a reaction of the reaction mixture takes place in the reaction zone resulting in a mixture of polar substances comprising glycerol, methanol or ethanol, and water, and non-polar substances comprising fatty acid methylesters or fatty acid ethylesters and unsaponifiable components, c) releasing the pressure to ambient pressure, d) after phase separation the polar phase is separated from the non-polar phase containing the non-polar substances, e) separating fatty acid methylesters or fatty acid ethylesters from the non-polar phase by falling film evaporation or thin-layer evaporation, f) separating squalene according to Formula I from the unsaponifiable components by molecular distillation, short-pass distillation, extraction or freeze separation.

    METHOD FOR THE ETHENOLYSIS OF POLYTERPENES AND DECOMPOSITION PRODUCTS OBTAINABLE THEREFROM
    5.
    发明申请
    METHOD FOR THE ETHENOLYSIS OF POLYTERPENES AND DECOMPOSITION PRODUCTS OBTAINABLE THEREFROM 审中-公开
    方法对乙烯醇及萜类文章，获取矿产品

    公开(公告)号：WO2012085013A9

    公开(公告)日：2012-09-27

    申请号：PCT/EP2011073493

    申请日：2011-12-20

    Applicant: UNIV DARMSTADT TECH ,  PLENIO HERBERT ,  WOLF STEFANIE

    Inventor： PLENIO HERBERT ,  WOLF STEFANIE

    IPC: C07C11/21 ,  C07C6/04 ,  C08C19/08

    CPC classification number: C07C11/21 ,  A01N49/00 ,  B01J31/2265 ,  B01J31/2273 ,  B01J2531/66 ,  B01J2531/821 ,  B01J2531/825 ,  C07C6/04 ,  C07C2531/22 ,  C08C19/08

    Abstract: The invention relates to a method for the ethenolysis of acyclic polyterpenes which comprise trisubstituted double bonds. The polyterpene is reacted with a catalyst complex [(NHC)(NHCewg)MeX2(CHPh)] and [(NHC)(NHCeWg)MeX2(3-phenylindenylid-1-ene)] in the presence of ethene. NHC and NHCewg are N-heterocyclic carbene ligands, where NHC is at least as rich in electrons as NHCewg, Me is Ru, Os or W, and X is selected from F, Cl, Br, I, CN, SCN, OCN, and NCO. The polyterpene is particularly advantageously selected from natural rubber, liquid natural rubber and squalene, or from vulcanized rubber, selected from used tires, used tire granules and powdered rubber. The invention provides, for the first time, decomposition products of the polyterpenes natural rubber, liquid natural rubber, squalene and vulcanized rubber, which can be produced with the aid of the method according to the invention.

    Abstract translation: 本发明提供了包含三取代双键，准备无环萜的乙烯醇分解的过程。 在此，多萜是[（NHCeWg）MEX 2（3-苯基茚基-1-烯）（NHC）]在乙烯的存在下与催化剂络合物[（NHC）（NHCewg）MEX 2（CHPh配合）]和。 NHC NHCewg并且是N-杂环卡宾配体，其中NHC至少与作为NHCewg富电子中，Me为Ru，O或W和X是选自F，Cl，溴，I，CN，SCN，OCN，NCO选择。 特别有利的是从天然橡胶，液态天然橡胶和角鲨烯或从轮胎，废轮胎和橡胶颗粒面粉所选硫化橡胶中选择的多萜。 本发明提供了一种用于天然橡胶的多萜首次降解产物，液态天然橡胶，角鲨烯和硫化橡胶制备的其可通过所述方法根据本发明来制造。

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