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    A CATALYST COMPOSITION FOR DIRECT SYNTHESIS OF VINYL CHLORIDE FROM ETHYLENE
    2.
    发明申请
    A CATALYST COMPOSITION FOR DIRECT SYNTHESIS OF VINYL CHLORIDE FROM ETHYLENE 审中-公开
    一种从乙烯直接合成氯乙烯的催化剂组合物

    公开(公告)号：WO2018015363A3

    公开(公告)日：2018-01-25

    申请号：PCT/EP2017/068083

    申请日：2017-07-18

    Applicant: ETH ZURICH

    Inventor： PÉREZ-RAMIREZ, Javier ,  AMRUTE, Amol

    IPC: B01J37/03 ,  B01J37/08 ,  B01J37/24 ,  B01J23/10 ,  B01J27/10 ,  B01J35/02 ,  B01J35/10 ,  C07C21/06

    Abstract: The present invention relates to process for obtaining a catalyst composition that catalyzes a one-step synthesis of vinyl chloride from ethylene, wherein the catalyst composition comprises at least one rare earth metal. The invention relates also to a catalyst bed comprising said catalyst composition and a one-step process for the synthesis of vinyl chloride from ethylene.

    Abstract translation: 本发明涉及获得催化由乙烯一步合成氯乙烯的催化剂组合物的方法，其中催化剂组合物包含至少一种稀土金属。 本发明还涉及包含所述催化剂组合物和从乙烯合成氯乙烯的一步法的催化剂床。

    PROCESS FOR THE MANUFACTURE OF ETHYLENE DICHLORIDE (EDC), AND PROCESS FOR THE MANUFACTURE OF VINYL CHLORIDE MONOMER (VCM) AND OF POLYVINYL CHLORIDE (PVC)
    4.
    发明申请
    PROCESS FOR THE MANUFACTURE OF ETHYLENE DICHLORIDE (EDC), AND PROCESS FOR THE MANUFACTURE OF VINYL CHLORIDE MONOMER (VCM) AND OF POLYVINYL CHLORIDE (PVC) 审中-公开
    乙烯二氯化物（EDC）的制造方法以及制备氯乙烯（VCM）和氯化聚氯乙烯（PVC）的方法

    公开(公告)号：WO2014095441A1

    公开(公告)日：2014-06-26

    申请号：PCT/EP2013/075884

    申请日：2013-12-09

    Applicant: SOLVAY SA

    Inventor： DEGRAEVE, Paul Julius ,  MARTIN CARNICERO, Maria

    IPC: C07C17/02 ,  C07C17/156 ,  C07C17/25 ,  C07C19/045 ,  C07C21/06

    CPC classification number: C07C17/02 ,  C07C17/156 ,  C07C17/25 ,  C07C19/045 ,  C07C21/06

    Abstract: Process for the manufacture of EDC or Ethylene Di-Chloride by chlorination and/or oxychlorination of ethylene, said process comprising the purification of an EDC stream according to the following steps : - eventually removing the lower boiling impurities from the EDC stream so as to generate a stream of EDC substantially free from lower boiling impurities; - feeding this EDC stream to a heavy ends distillation column so as to get a top stream of substantially pure EDC and a bottom stream comprising higher boiling impurities and EDC, wherein the EDC stream fed to the heavy ends distillation column is at least partly heated up by a heater using waste heat available in the EDC manufacturing process itself or in a subsequent pyrolysis step of said EDC into vinyl chloride monomer or VCM or in an oxychlorination unit of ethylene to EDC.

    Abstract translation: 用于通过乙烯的氯化和/或氧氯化来制造EDC或二氯乙烯的方法，所述方法包括根据以下步骤纯化EDC流： - 最终从EDC流中除去较低沸点的杂质，以产生 一种基本上没有较低沸点杂质的EDC流; - 将该EDC流输送到重馏分蒸馏塔，以获得基本上纯的EDC的顶部流和包含较高沸点杂质和EDC的底部流，其中进料到重馏分蒸馏塔的EDC流至少部分地被加热 通过加热器使用EDC制造过程本身或在随后的所述EDC的热解步骤中可用的废热进入氯乙烯单体或VCM或乙烯到EDC的氧氯化单元。

    PROCESS FOR THE HYDROHALOGENATION OF AN UNSATURATED HYDROCARBON
    5.
    发明申请
    PROCESS FOR THE HYDROHALOGENATION OF AN UNSATURATED HYDROCARBON 审中-公开
    不饱和烃的氢化方法

    公开(公告)号：WO2014001420A1

    公开(公告)日：2014-01-03

    申请号：PCT/EP2013/063450

    申请日：2013-06-27

    Applicant: SOLVAY SA

    Inventor： STREBELLE, Michel ,  LIEBENS, Armin T. ,  BALTHASART, Dominique ,  PICCININI, Marco

    IPC: C07C17/08 ,  C07C21/06

    CPC classification number: C07C17/08 ,  B01J31/0284 ,  B01J2231/341 ,  C01B7/01 ,  C07C17/25 ,  C07C21/06 ,  C07C19/045

    Abstract: Process for the hydrohalogenation of an unsaturated hydrocarbon and for the manufacture of vinyl chloride by hydrochlorination of acetylene Process for the hydrohalogenation of an unsaturated hydrocarbon using a catalyst comprising at least one ionic liquid (IL) and at least one metal, according to which said IL and metal are supported on a solid carrier, said process being a continuous industrial process wherein the overall unsaturated hydrocarbon conversion is of at least 60 % during at least 500 hours.

    Abstract translation: 不饱和烃的氢卤化和通过氢化乙炔制造氯乙烯的方法使用包含至少一种离子液体（IL）和至少一种金属的催化剂对不饱和烃进行氢卤化的方法，根据该方法，所述IL 并且金属负载在固体载体上，所述方法是连续的工业方法，其中在至少500小时内总的不饱和烃转化率为至少60％。

    乙炔氢氯化制备氯乙烯的催化剂体系及其制备和应用
    7.
    发明申请
    乙炔氢氯化制备氯乙烯的催化剂体系及其制备和应用 审中-公开

    公开(公告)号：WO2011050614A1

    公开(公告)日：2011-05-05

    申请号：PCT/CN2010/073705

    申请日：2010-06-09

    Applicant: 于志勇

    Inventor： 于志勇

    IPC: B01J31/30 ,  B01J31/26 ,  B01J37/04 ,  C07C21/06 ,  C07C17/08

    CPC classification number: B01J31/0284 ,  B01J31/26 ,  B01J31/30 ,  C07C17/08 ,  C07C21/06

    Abstract: 本发明公开了一种乙炔氢氯化制备氯乙烯的催化剂体系及其制备和应用。催化剂体系包括催化剂载体和催化剂，其中催化剂载体为咪唑类离子液体，催化剂为金、铂、钯、锡、汞、铜或铑的氯化物中的一种或其两种以上任意组合。上述催化剂体系的制备方法为将催化剂溶于催化剂载体中。乙炔和氯化氢两种气体混合后在上述催化剂体系存在下进行反应。此制备工艺实现了乙炔氢氯化制备氯乙烯的液相反应，避免催化剂体系的损失，且更加环保和安全。提高了乙炔的转化率和氯乙烯的选择性。

    PROCESS FOR THE MANUFACTURE OF AT LEAST ONE ETHYLENE DERIVATIVE COMPOUND
    8.
    发明申请
    PROCESS FOR THE MANUFACTURE OF AT LEAST ONE ETHYLENE DERIVATIVE COMPOUND 审中-公开
    至少一种乙烯衍生化合物的制造方法

    公开(公告)号：WO2009106479A1

    公开(公告)日：2009-09-03

    申请号：PCT/EP2009/052005

    申请日：2009-02-20

    Applicant: SOLVAY (Société Anonyme) ,  PETITJEAN, Andre ,  LEMPEREUR, Michel ,  BALTHASART, Dominique ,  STREBELLE, Michel ,  GIANSANTE, Massimo

    Inventor： PETITJEAN, Andre ,  LEMPEREUR, Michel ,  BALTHASART, Dominique ,  STREBELLE, Michel ,  GIANSANTE, Massimo

    IPC: C07C17/02 ,  C07C17/156 ,  C07C17/25 ,  C07C19/045 ,  C07C21/06

    CPC classification number: C07C19/045 ,  C07C17/02 ,  C07C17/156 ,  C07C17/25 ,  Y02P20/582 ,  C07C21/06

    Abstract: Process for the manufacture of at least one ethylene derivative compound starting from a low value residual gas, preferably a ROG, according to which : a) the low value residual gas is subjected to a series of treatment steps in a low value residual gas recovery unit in order to remove the undesirable components present therein and to obtain a mixture of products containing ethylene and other constituents; b) the said mixture of products is separated into a fraction enriched with compounds which are lighter than ethylene, containing part of the ethylene (fraction A), into a fraction enriched with ethylene (fraction B) and into a heavy fraction (fraction C); c) fraction A and fraction B are separately conveyed to the manufacture of at least one ethylene derivative compound.

    Abstract translation: 用于从低值残留气体（优选ROG）开始制造至少一种乙烯衍生物的方法，其中：a）低值残留气体在低值残余气体回收单元中进行一系列处理步骤 以除去其中存在的不期望的组分并获得含有乙烯和其它组分的产物的混合物; b）将所述产物混合物分离成富含化合物的馏分，所述化合物比乙烯轻，含有部分乙烯（馏分A））成为富含乙烯（馏分B）的馏分和重馏分（馏分C） ; c）馏分A和馏分B分别输送至制造至少一种乙烯衍生物化合物。

    PROCESS FOR THE MANUFACTURE OF 1,2-DICHLOROETHANE
    9.
    发明申请
    PROCESS FOR THE MANUFACTURE OF 1,2-DICHLOROETHANE 审中-公开
    1,2-二氯乙烷的制备方法

    公开(公告)号：WO2006067192A1

    公开(公告)日：2006-06-29

    申请号：PCT/EP2005/057048

    申请日：2005-12-21

    Applicant: SOLVAY (Société Anonyme) ,  STREBELLE, Michel ,  BALTHASART, Dominique

    Inventor： STREBELLE, Michel ,  BALTHASART, Dominique

    IPC: C07C17/156 ,  C07C17/02 ,  C07C19/045 ,  C07C17/25 ,  C07C21/06 ,  C08F14/06

    CPC classification number: C07C21/06 ,  C07C17/02 ,  C07C17/156 ,  C07C17/25 ,  C07C19/045 ,  Y02P20/582

    Abstract: Process for the manufacture of 1,2-dichloroethane starting with a hydrocarbon source according to which: a) the hydrocarbon source is subjected to cracking which produces a mixture of products containing ethylene and other constituents; b) the said mixture of products is separated into at least one fraction containing ethylene and into a heavy fraction (fraction C); c) the fraction or fractions containing ethylene are conveyed to a chlorination reactor and/or to an oxychlorination reactor, in which reactors most of the ethylene present is converted to 1,2-dichloroethane; d) the 1,2-dichloroethane obtained is separated from the streams of products derived from the chlorination and oxychlorination reactors and it is conveyed to the pyrolysis oven; and e) the fraction C is conveyed to cracking or to the oven for pyrolysis of 1,2-dichloroethane as fuel.

    Abstract translation: 从烃源开始制造1,2-二氯乙烷的方法，其中：a）烃源受到裂化，产生含乙烯和其它组分的产物的混合物; b）将所述产物混合物分离成含有乙烯的至少一个馏分和重馏分（馏分C）; c）将含有乙烯的级分或级分输送到氯化反应器和/或氧氯化反应器，其中反应器将大部分乙烯转化为1,2-二氯乙烷; d）将得到的1,2-二氯乙烷与衍生自氯化和氧氯化反应器的产物流分离，并将其输送至热解炉; 和e）将馏分C输送至裂化或送入烘箱以热解1,2-二氯乙烷作为燃料。

    PROCESS FOR THE MANUFACTURE OF 1,2-DICHLOROETHANE
    10.
    发明申请
    PROCESS FOR THE MANUFACTURE OF 1,2-DICHLOROETHANE 审中-公开
    1,2-二氯乙烷的制备方法

    公开(公告)号：WO2006067191A1

    公开(公告)日：2006-06-29

    申请号：PCT/EP2005/057046

    申请日：2005-12-21

    Applicant: SOLVAY (Société Anonyme) ,  STREBELLE, Michel ,  BALTHASART, Dominique

    Inventor： STREBELLE, Michel ,  BALTHASART, Dominique

    IPC: C07C17/02 ,  C07C17/156 ,  C07C19/045 ,  C07C17/25 ,  C07C21/06 ,  C08F14/06

    CPC classification number: C07C17/02 ,  C07C17/156 ,  C07C17/25 ,  C07C19/045 ,  C07C21/06 ,  Y02P20/582

    Abstract: Process for the manufacture of 1,2-dichloroethane starting with a hydrocarbon source according to which : a) the hydrocarbon source is subjected to a first cracking step, namely a pyrolysis step carried out in a cracking oven, thus producing a mixture of cracking products; b) the said mixture of cracking products is subjected to a succession of treatment steps which make it possible to obtain a mixture of products containing ethylene and other constituents, among which an aqueous quenching step, an alkaline washing step aimed at removing at least most of the carbon dioxide generating an alkaline solution and an oxidation step aimed at removing the hydrogen sulphide contained in the mixture of cracking products; c) the mixture of products containing ethylene derived from step b) is separated into at least one fraction containing ethylene and into a heavy fraction; d) the fraction(s) containing ethylene is (are) conveyed to a chlorination reactor and/or an oxychlorination reactor, in which reactors most of the ethylene present is converted to 1,2-dichloroethane; e) the 1,2-dichloroethane obtained is separated from the streams of products derived from the chlorination and oxychlorination reactors.

    Abstract translation: 从烃源开始制造1,2-二氯乙烷的方法，其中：a）烃源进行第一裂化步骤，即在裂化炉中进行的热解步骤，从而产生裂化产物的混合物 ; b）所述裂化产物混合物经受一系列处理步骤，其可以获得含有乙烯和其它组分的产物的混合物，其中含水淬火步骤，碱性洗涤步骤，目的在于除去至少大部分 生成碱性溶液的二氧化碳和旨在除去裂化产物混合物中所含的硫化氢的氧化步骤; c）将含有来自步骤b）的乙烯的产物的混合物分离成至少一个含乙烯的馏分和重馏分; d）将含有乙烯的馏分输送到氯化反应器和/或氧氯化反应器，其中反应器将大部分乙烯转化为1,2-二氯乙烷; e）将获得的1,2-二氯乙烷与衍生自氯化和氧氯化反应器的产物流分离。

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