CARBOXY-TERMINATED OLIGOMERIC POLYESTER COMPOSITIONS AND METHOD FOR MAKING
    1.
    发明申请
    CARBOXY-TERMINATED OLIGOMERIC POLYESTER COMPOSITIONS AND METHOD FOR MAKING 审中-公开
    羧基封端的低聚物组合物和制备方法

    公开(公告)号:WO2006057810A1

    公开(公告)日:2006-06-01

    申请号:PCT/US2005/040523

    申请日:2005-11-09

    CPC classification number: C08G63/85 C08G63/191 C08G63/64

    Abstract: The present invention provides carboxy-terminated oligomeric polyester compositions useful in the preparation of "weatherable" polymeric materials, for example weatherable copolyestercarbonates. In one aspect the present invention provides an oligomeric polyester composition comprising structural units derived from at least one diacid, at least one diaryl carbonate and at least one diol. The structural units derived from the diacid are present in a molar excess of from about 10% to about 40% based on a ratio of moles of diacid-derived structural units to moles of diol-derived structural units present in the oligomeric polyester composition. The oligomeric polyester composition is further characterized by the presence of atleast some phenoxy end groups.

    Abstract translation: 本发明提供了可用于制备“耐候性”聚合物材料的羧基封端的低聚聚酯组合物,例如耐候性共聚酯碳酸酯。 一方面,本发明提供了一种低聚聚酯组合物,其包含衍生自至少一种二酸,至少一种碳酸二芳基酯和至少一种二醇的结构单元。 基于二酸衍生的结构单元的摩尔数与存在于低聚聚酯组合物中的二醇衍生的结构单元的摩尔数的比例,衍生自二酸的结构单元的摩尔过量为约10%至约40%。 低聚聚酯组合物的特征还在于存在至少一些苯氧基端基。

    POLYARYLATE ACID CHLORIDE COMPOSITIONS AND DERIVATES THEREFROM
    2.
    发明申请
    POLYARYLATE ACID CHLORIDE COMPOSITIONS AND DERIVATES THEREFROM 审中-公开
    聚芳酯酸氯化物组合物及其衍生物

    公开(公告)号:WO2007070377A3

    公开(公告)日:2007-07-26

    申请号:PCT/US2006046863

    申请日:2006-12-08

    CPC classification number: C08G63/191 C08G63/672 C08G63/79 C08G63/916

    Abstract: Disclosed herein are polyarylate acid chloride compositions derived from aromatic diacid chlorides and dihydroxy aromatic compounds that are made by reacting a stoichiometric excess of said aromatic diacid chlorides with the dihydroxy aromatic compounds. Disclosed also are a wide variety of compositions derived from said polyarylate acid chlorides. In one instance new compositions are prepared by reacting the polyarylate acid chlorides with a nucleophile containing carboxylate functionality to provide an acid end-capped polyarylate. Alternately, the polyarylate acid chlorides may be hydrolyzed to provide carboxylate end-capped polyarylates. Disclosed further are methods to make described compositions.

    Abstract translation: 本文公开了由芳族二酰氯和二羟基芳族化合物衍生的聚芳酯酰氯组合物,其通过使化学计量过量的所述芳族二酰氯与二羟基芳族化合物反应而制备。 还公开了衍生自所述聚芳酯酰氯的各种组合物。 在一种情况下,通过使多芳基化合物酰氯与含亲核试剂的羧酸酯官能团反应以提供酸封端的多芳基化合物来制备新的组合物。 或者,多芳基化合物酰基氯可以被水解以提供羧酸酯封端的多芳基化合物。 还公开了制造所述组合物的方法。

    CARBOXY-TERMINATED OLIGOMERIC POLYESTER COMPOSITIONS AND METHOD FOR MAKING
    3.
    发明申请
    CARBOXY-TERMINATED OLIGOMERIC POLYESTER COMPOSITIONS AND METHOD FOR MAKING 审中-公开
    羧基封端的低聚聚酯组合物和制备方法

    公开(公告)号:WO2006057810A8

    公开(公告)日:2007-07-05

    申请号:PCT/US2005040523

    申请日:2005-11-09

    CPC classification number: C08G63/85 C08G63/191 C08G63/64

    Abstract: The present invention provides carboxy-terminated oligomeric polyester compositions useful in the preparation of "weatherable" polymeric materials, for example weatherable copolyestercarbonates. In one aspect the present invention provides an oligomeric polyester composition comprising structural units derived from at least one diacid, at least one diaryl carbonate and at least one diol. The structural units derived from the diacid are present in a molar excess of from about 10% to about 40% based on a ratio of moles of diacid-derived structural units to moles of diol-derived structural units present in the oligomeric polyester composition. The oligomeric polyester composition is further characterized by the presence of atleast some phenoxy end groups.

    Abstract translation: 本发明提供了可用于制备“耐候性”聚合物材料的羧基封端的低聚聚酯组合物,例如耐候性共聚酯碳酸酯。 在一个方面,本发明提供了包含衍生自至少一种二酸,至少一种碳酸二芳酯和至少一种二醇的结构单元的低聚聚酯组合物。 基于二酸衍生的结构单元的摩尔数与存在于低聚聚酯组合物中的二醇衍生的结构单元的摩尔数的比例,衍生自二酸的结构单元的摩尔过量为约10%至约40%。 低聚聚酯组合物的特征还在于存在至少一些苯氧基端基。

    METHODS FOR PREPARATION OF POLYESTER VIA BASE CATALYSIS
    7.
    发明申请
    METHODS FOR PREPARATION OF POLYESTER VIA BASE CATALYSIS 审中-公开
    通过基础催化制备聚酯的方法

    公开(公告)号:WO2014160333A1

    公开(公告)日:2014-10-02

    申请号:PCT/US2014/026337

    申请日:2014-03-13

    CPC classification number: C08G63/83 C08G63/183 C08G63/19 C08G63/78 C08G63/87

    Abstract: Presented herein are methods and systems for preparing polyester, e.g., polybutylene terephthalate (PBT), using a base catalyst, e.g., a heterocyclic amine such as triazabicyclodecene (TBD). It is found that such base catalysts are effective in the production of polyester, and they reduce the potential for undesired byproducts such as furans (e.g., THF) and acetaldehyde (AA), which result from diol side reactions.

    Abstract translation: 本文提出了使用碱催化剂例如三氮杂双环十碳烯(TBD)等杂环胺制备聚酯例如聚对苯二甲酸丁二醇酯(PBT)的方法和系统。 发现这种碱催化剂在聚酯的生产中是有效的,并且它们降低了由二醇副反应产生的不希望的副产物如呋喃(例如THF)和乙醛(AA)的可能性。

    POLYARYLATE ACID CHLORIDE COMPOSITIONS AND DERIVATES THEREFROM
    9.
    发明申请
    POLYARYLATE ACID CHLORIDE COMPOSITIONS AND DERIVATES THEREFROM 审中-公开
    聚酰胺酸氯化物组合物及其衍生物

    公开(公告)号:WO2007070377A2

    公开(公告)日:2007-06-21

    申请号:PCT/US2006/046863

    申请日:2006-12-08

    CPC classification number: C08G63/191 C08G63/672 C08G63/79 C08G63/916

    Abstract: Disclosed herein are polyarylate acid chloride compositions derived from aromatic diacid chlorides and dihydroxy aromatic compounds that are made by reacting a stoichiometric excess of said aromatic diacid chlorides with the dihydroxy aromatic compounds. Disclosed also are a wide variety of compositions derived from said polyarylate acid chlorides. In one instance new compositions are prepared by reacting the polyarylate acid chlorides with a nucleophile containing carboxylate functionality to provide an acid end-capped polyarylate. Alternately, the polyarylate acid chlorides may be hydrolyzed to provide carboxylate end-capped polyarylates. Disclosed further are methods to make described compositions.

    Abstract translation: 本文公开了衍生自芳族二酰氯和二羟基芳族化合物的多芳基化合物酰氯组合物,其通过使化学计量过量的所述芳族二酰氯与二羟基芳族化合物反应而制备。 还公开了从所述多芳基化合物酰氯衍生的各种组合物。 在一个实例中,通过使多芳基化合物酰氯与含有亲核试剂的羧酸酯官能团反应制备酸性封端的多芳基化合物来制备新的组合物。 或者,多芳基化合物酰氯可以水解以提供羧酸酯封端的多芳基化合物。 还公开了制备所述组合物的方法。

Patent Agency Ranking