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    HIGH PERFORMANCE CROSS-LINKED POLYBENZOXAZOLE AND POLYBENZOTHIAZOLE POLYMER MEMBRANES
    1.
    发明申请
    HIGH PERFORMANCE CROSS-LINKED POLYBENZOXAZOLE AND POLYBENZOTHIAZOLE POLYMER MEMBRANES 审中-公开

    公开(公告)号：WO2010110975A3

    公开(公告)日：2010-09-30

    申请号：PCT/US2010/024855

    申请日：2010-02-22

    Applicant: UOP LLC ,  LIU, Chunqing ,  TANG, Man-Wing ,  SERBAYEVA, Raisa ,  ZHOU, Lubo

    Inventor： LIU, Chunqing ,  TANG, Man-Wing ,  SERBAYEVA, Raisa ,  ZHOU, Lubo

    IPC: B01D71/64 ,  B01D67/00 ,  C08J5/22 ,  C08G73/22 ,  C08G75/32

    Abstract: In the present invention high performance cross-linked polybenzoxazole and polybenzothiazole polymer membranes and methods for making and using these membranes have been developed. The cross-linked polybenzoxazole and polybenzothiazole polymer membranes are prepared by: 1) first synthesizing polyimide polymers comprising pendent functional groups (e.g., -OH or -SH) ortho to the heterocyclic imide nitrogen and cross-linkable functional groups in the polymer backbone; 2) fabricating polyimide membranes from these polymers; 3) converting the polyimide membranes to polybenzoxazole or polybenzothiazole membranes by heating under inert atmosphere such as nitrogen or vacuum; and 4) finally converting the membranes to high performance cross-linked polybenzoxazole or polybenzothiazole membranes by a crosslinking treatment, preferably UV radiation. The membranes can be fabricated into any convenient geometry. The high performance cross-linked polybenzoxazole and polybenzothiazole polymer membranes of the present invention are suitable for a variety of liquid, gas, and vapor separations.

    POLYBENZAZOLE BLOCK COPOLYMER
    2.
    发明申请
    POLYBENZAZOLE BLOCK COPOLYMER 审中-公开
    聚苯并唑嵌段共聚物

    公开(公告)号：WO2006051064A1

    公开(公告)日：2006-05-18

    申请号：PCT/EP2005/055778

    申请日：2005-11-07

    Applicant: SOLVAY (Société Anonyme) ,  MARTIN, Roland

    Inventor： MARTIN, Roland

    IPC: C08G73/22 ,  C08G73/18 ,  C08G75/32 ,  B01D71/62 ,  H01M8/10 ,  H01M8/02

    CPC classification number: C08G73/22 ,  B01D71/62 ,  B01D71/68 ,  B01D71/80 ,  C08G73/18 ,  H01M8/1027 ,  H01M8/103 ,  H01M8/1048 ,  H01M8/1081 ,  H01M2300/0082 ,  Y02P70/56

    Abstract: The invention concerns a polybenzazole block copolymer suitable for solid polymer electrolyte membranes application comprising: at least one block (Bl) comprising recurring units (R), more than 50 % of said recurring units comprising at least one benzimidazole group (formula 1a and 1b) and at least one sulfonic acid group (formula 2) [recurring units (R1)]; wherein E in formula 1a can be a substituted or non-substituted carbon atom or nitrogen atom, and Q in formula 1 can be a hydrogen atom or a group comprising a sulfonic acid group; and at least one block (B2) comprising recurring units (R'), more than 50 % by moles of said recurring units comprising at least one benzazole group chosen among benzoxazole group (formula 3a and 3b) and benzothiazole group (formula 4a and 4b) [recurring units (R2)], wherein E' and E" in formula 3a and 4a, respectively, can be a substituted or non-substituted carbon atom or nitrogen atom, and the block (B2) is free from sulfonic acid groups. The invention also relates to a polybenzazole polymer composition thereof, a solid polymer electrolyte membrane therefrom, a solid polymer electrolyte doped membrane therefrom, and the fuel cell therefrom.

    Abstract translation: 本发明涉及适用于固体聚合物电解质膜应用的聚吲哚嵌段共聚物，其包含：至少一个包含重复单元（R）的嵌段（B1），超过50％的所述重复单元包含至少一个苯并咪唑基（式1a和1b） 和至少一个磺酸基（式2）[重复单元（R 1）]; 其中式1a中的E可以是取代或未取代的碳原子或氮原子，式1中的Q可以是氢原子或包含磺酸基的基团; 和包含重复单元（R'）的至少一个嵌段（B2），大于50摩尔％的所述重复单元包含至少一个选自苯并恶唑基（式3a和3b）的苯并唑基和苯并噻唑基（式4a和4b ）[重复单元（R2）]，其中式3a和4a中的E'和E“分别可以是取代或未取代的碳原子或氮原子，并且嵌段（B2）不含磺酸基团。 本发明还涉及其聚吲哚聚合物组合物，其固体聚合物电解质膜，由其固体聚合物电解质掺杂的膜及其燃料电池。

    METHOD OF PRODUCING A THERMALLY REARRANGED PBX, THERMALLY REARRANGED PBX AND MEMBRANE
    6.
    发明申请
    METHOD OF PRODUCING A THERMALLY REARRANGED PBX, THERMALLY REARRANGED PBX AND MEMBRANE 审中-公开
    生产热电复合PBX，热回收PBX和膜的方法

    公开(公告)号：WO2016120189A1

    公开(公告)日：2016-08-04

    申请号：PCT/EP2016/051415

    申请日：2016-01-25

    Applicant: HELMHOLTZ-ZENTRUM GEESTHACHT ZENTRUM FÜR MATERIAL- UND KÜSTENFORSCHUNG GMBH

    Inventor： TENA, Alberto ,  RANGOU, Sofia ,  SHISHATSKIY, Sergey

    IPC: B01D71/62 ,  C08G73/18 ,  C08G73/22 ,  C08G75/32 ,  B01D71/66

    CPC classification number: C08G73/22 ,  B01D53/228 ,  B01D69/12 ,  B01D71/62 ,  C08G73/18

    Abstract: The present invention concerns a method of producing a thermally rearranged polybenzoxazole, polybenzimidazole or polybenzothiazole (collectively denominated "TR PBX"), thermally arranged PBX and membranes comprising the same. The inventive method includes the method steps: preparing a polyimide or aromatic polyamide as a precursor polymer in a solution, wherein in each recurring monomer unit of the precursor polymer an aromatic ring is located adjacent to the nitrogen atom of the imide group or amide group of the monomer unit, wherein in some or all of the recurring monomer units the aromatic ring is functionalized with an -XR group as a side chain at the ortho -position to the nitrogen atom, wherein X=O, N or S, and performing a thermal treatment to carry out a thermal rearrangement resulting in the thermally rearranged polybenzoxazole, polybenzimidazole or polybenzothiazole, wherein R is an allyl group or an allyl-based group, wherein a processing temperature used during the thermal treatment for the thermal rearrangement is between 0 °C and 350 °C.

    Abstract translation: 本发明涉及一种制备热重排的聚苯并恶唑，聚苯并咪唑或聚苯并噻唑（统称为“TR PBX”），热排列的PBX及其组成的膜的方法。 本发明的方法包括方法步骤：在溶液中制备作为前体聚合物的聚酰亚胺或芳族聚酰胺，其中在前体聚合物的每个重复单体单元中，芳环位于邻近酰亚胺基或酰胺基的氮原子 所述单体单元，其中在一些或所有重复单体单元中，所述芳环在与所述氮原子邻位的-XR基团作为侧链进行官能化，其中X = O，N或S，并进行 进行热重排，导致热重排的聚苯并恶唑，聚苯并咪唑或聚苯并噻唑，其中R是烯丙基或烯丙基，其中在热重排的热处理期间使用的加工温度为0℃ 和350℃。

    HIGH PERFORMANCE CROSS-LINKED POLYBENZOXAZOLE AND POLYBENZOTHIAZOLE POLYMER MEMBRANES
    7.
    发明申请
    HIGH PERFORMANCE CROSS-LINKED POLYBENZOXAZOLE AND POLYBENZOTHIAZOLE POLYMER MEMBRANES 审中-公开
    高性能交联聚苯并噻唑和聚苯并噻唑聚合物膜

    公开(公告)号：WO2010110975A2

    公开(公告)日：2010-09-30

    申请号：PCT/US2010024855

    申请日：2010-02-22

    Applicant: UOP LLC ,  LIU CHUNQING ,  TANG MAN-WING ,  SERBAYEVA RAISA ,  ZHOU LUBO

    Inventor： LIU CHUNQING ,  TANG MAN-WING ,  SERBAYEVA RAISA ,  ZHOU LUBO

    IPC: B01D71/64 ,  B01D67/00 ,  C08G73/22 ,  C08G75/32 ,  C08J5/22

    CPC classification number: C08G75/32 ,  B01D67/0083 ,  B01D67/009 ,  B01D71/64 ,  B01D71/66 ,  B01D2323/30 ,  B01D2323/345 ,  C08G73/1042 ,  C08G73/22 ,  C08J7/08 ,  C08J2379/04 ,  C08L79/04 ,  C08L2205/05

    Abstract: In the present invention high performance cross-linked polybenzoxazole and polybenzothiazole polymer membranes and methods for making and using these membranes have been developed. The cross-linked polybenzoxazole and polybenzothiazole polymer membranes are prepared by: 1) first synthesizing polyimide polymers comprising pendent functional groups (e.g., -OH or -SH) ortho to the heterocyclic imide nitrogen and cross-linkable functional groups in the polymer backbone; 2) fabricating polyimide membranes from these polymers; 3) converting the polyimide membranes to polybenzoxazole or polybenzothiazole membranes by heating under inert atmosphere such as nitrogen or vacuum; and 4) finally converting the membranes to high performance cross-linked polybenzoxazole or polybenzothiazole membranes by a crosslinking treatment, preferably UV radiation. The membranes can be fabricated into any convenient geometry. The high performance cross-linked polybenzoxazole and polybenzothiazole polymer membranes of the present invention are suitable for a variety of liquid, gas, and vapor separations.

    Abstract translation: 在本发明中，开发了高性能交联聚苯并恶唑和聚苯并噻唑聚合物膜以及制备和使用这些膜的方法。 交联的聚苯并恶唑和聚苯并噻唑聚合物膜是通过以下步骤制备的：1）首先合成聚酰亚胺聚合物，其包含与杂环酰亚胺氮邻接的侧基官能团（例如-OH或-SH）和聚合物主链中的可交联官能团; 2）从这些聚合物制造聚酰亚胺膜; 3）通过在惰性气氛如氮气或真空下加热将聚酰亚胺膜转化为聚苯并恶唑或聚苯并噻唑膜; 和4）最后通过交联处理，优选UV辐射将膜转化成高性能交联聚苯并恶唑或聚苯并噻唑膜。 膜可以制造成任何方便的几何形状。 本发明的高性能交联聚苯并恶唑和聚苯并噻唑聚合物膜适用于各种液体，气体和蒸气分离。

    COPOLYMERS CONTAINING POLYBENZOXAZOLE, POLYBENZOTHIAZOLE AND POLYBENZIMIDAZOLE MOIETIES
    8.
    发明申请
    COPOLYMERS CONTAINING POLYBENZOXAZOLE, POLYBENZOTHIAZOLE AND POLYBENZIMIDAZOLE MOIETIES 审中-公开
    聚苯并唑，聚苯并唑和聚苯并咪唑的共聚物

    公开(公告)号：WO1990003995A1

    公开(公告)日：1990-04-19

    申请号：PCT/US1989004464

    申请日：1989-10-06

    Applicant: THE DOW CHEMICAL COMPANY

    Inventor： THE DOW CHEMICAL COMPANY ,  HARRIS, William, J. ,  HWANG, Wen-Fang

    IPC: C08G75/32

    CPC classification number: C08G81/00 ,  C08G65/4012 ,  C08G73/18 ,  C08G73/22 ,  C08G75/32 ,  C08L71/00 ,  C08L2205/05 ,  C08L2666/20

    Abstract: Block copolymers can be formed from heterocyclic polymers such as PBO and thermoplastic polymers such as polyamide or poly(aromatic ether ketone). The block copolymer compositions are thermoplastic and do not experience substantial phase separation, even at about their glass transition temperature. The block copolymer compositions can be formed into fibers, films and laminate or compression-molded articles. PBO, PBI and PBT polymers terminated by active aromatic rings or acylating groups are particularly useful for making the block copolymers.

    Abstract translation: 嵌段共聚物可以由诸如PBO和热塑性聚合物如聚酰胺或聚（芳族醚酮）的杂环聚合物形成。 嵌段共聚物组合物是热塑性的，并且即使在其玻璃化转变温度附近也不会发生相当大的相分离。 嵌段共聚物组合物可以形成纤维，膜和层压体或压缩成型制品。 通过活性芳环或酰化基团封端的PBO，PBI和PBT聚合物特别可用于制备嵌段共聚物。

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