公开(公告)号：WO2021055272A1

公开(公告)日：2021-03-25

申请号：PCT/US2020/050657

申请日：2020-09-14

Applicant: CHEVRON PHILLIPS CHEMICAL COMPANY LP ,  CLEAR, Kathy, S.

Inventor： BARR, Jared, L. ,  CRUZ, Carlos, A. ,  MONWAR, Masud, M. ,  MCDANIEL, Max, P.

IPC: C07C29/48 ,  C07C27/10

Abstract: Processes for converting an olefin reactant into a diol compound are disclosed, and these processes include the steps of contacting the olefin reactant and a supported chromium catalyst comprising chromium in a hexavalent oxidation state to reduce at least a portion of the supported chromium catalyst to form a reduced chromium catalyst, and hydrolyzing the reduced chromium catalyst to form a reaction product comprising the diol compound. While being contacted, the olefin reactant and the supported chromium catalyst can be irradiated with a light beam at a wavelength in the UV-visible spectrum. Optionally, these processes can further comprise a step of calcining at least a portion of the reduced chromium catalyst to regenerate the supported chromium catalyst.

公开(公告)号：WO2018031749A1

公开(公告)日：2018-02-15

申请号：PCT/US2017/046258

申请日：2017-08-10

Applicant: UNIVERSITY OF KANSAS

Inventor： SUBRAMANIAM, Bala ,  DANBY, Andrew M. ,  LUNDIN, Michael D.

IPC: C07C29/50 ,  C07C9/02 ,  C07C27/10

Abstract: A process for the ozonolysis of an alkane may comprise combining an alkane and ozone in a liquid phase medium comprising CO 2 under conditions sufficient to oxidize the alkane to produce one or more non-combustion products. The liquid phase medium may be free of a super acid.

Abstract translation: 用于烷烃臭氧分解的方法可以包括在足以氧化烷烃以产生一种或多种烃的条件下，在包含CO 2的液相介质中混合烷烃和臭氧 非燃烧产品。 液相介质可以不含超强酸。

公开(公告)号：WO2017042088A1

公开(公告)日：2017-03-16

申请号：PCT/EP2016/070648

申请日：2016-09-01

Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： SUBRAMANIAN, Selvakumar ,  DANIËLS, Dimitri ,  WONG, Kae ,Shin ,  WARD, Andrew Mark

IPC: C07C2/66 ,  C07C15/02 ,  C07C15/085 ,  C07C27/10 ,  C07C37/58 ,  C07C39/04 ,  C07C45/36 ,  C07C49/08 ,  C07C49/10

CPC classification number: C07C2/66 ,  B01J29/084 ,  B01J29/18 ,  B01J29/7007 ,  C07C1/20 ,  C07C2/00 ,  C07C37/58 ,  C07C45/36 ,  C07C407/00 ,  C07C2529/08 ,  C07C2529/70 ,  C07C15/085 ,  C07C39/04 ,  C07C49/08 ,  C07C49/10 ,  C07C15/073

Abstract: The present invention relates to a process for producing cumene and/or sec- butylbenzene comprising contacting benzene with a mixed olefins stream comprising ethylene and an alkylation agent in the presence of a selective alkylation catalyst under selective alkylation conditions.

Abstract translation: 本发明涉及生产异丙苯和/或仲丁基苯的方法，包括在选择性烷基化条件下，在选择性烷基化催化剂存在下，使苯与包含乙烯和烷基化剂的混合烯烃流接触。

公开(公告)号：WO2014039711A1

公开(公告)日：2014-03-13

申请号：PCT/US2013/058315

申请日：2013-09-05

Applicant: POWERDYNE, INC.

Inventor： HIRSON, Geoffrey ,  SHOUSE, Gus F.

IPC: G01N21/75 ,  H05H1/42 ,  C07C27/10

CPC classification number: C10L1/04 ,  B01D21/0009 ,  B01D21/01 ,  B01J12/002 ,  B01J19/088 ,  B01J2219/00063 ,  B01J2219/00162 ,  B01J2219/00186 ,  B01J2219/0809 ,  B01J2219/0815 ,  B01J2219/0871 ,  B01J2219/0875 ,  B01J2219/0877 ,  B01J2219/0879 ,  B01J2219/0892 ,  B01J2219/0898 ,  B09B3/005 ,  C01B3/02 ,  C01B3/042 ,  C01B3/12 ,  C01B2203/0283 ,  C01B2203/062 ,  C01B2203/0861 ,  C07C1/04 ,  C10G2/32 ,  C10G2/332 ,  C10G2/333 ,  C10G2/50 ,  C10J3/00 ,  C10J2300/1238 ,  C10J2300/1671 ,  C10J2300/1675 ,  C10L1/06 ,  C10L1/08 ,  C10L2200/0415 ,  C10L2200/0423 ,  C10L2200/043 ,  C10L2200/0446 ,  C10L2200/0492 ,  C10L2270/023 ,  C10L2270/026 ,  C10L2270/04 ,  C10L2290/06 ,  C10L2290/30 ,  C10L2290/38 ,  C10L2290/42 ,  F01K25/06 ,  F02C1/05 ,  H05H1/34 ,  H05H1/42 ,  H05H1/44 ,  H05H1/48 ,  Y02E50/32 ,  Y02E60/364 ,  Y02P20/13

Abstract: Methods of making fuel are described herein. A method may include providing a first working fluid, a second working fluid, and a third working fluid. The method may also include exposing the first working fluid to a first high voltage electric field to produce a first plasma, exposing the second working fluid to a second high voltage electric field to produce a second plasma, and exposing the third working fluid to a third high voltage electric field to produce a third plasma. The method may also include providing and contacting a carbon-based feedstock with the third plasma, the second plasma, and the first plasma within a processing chamber to form a mixture, cooling the mixture using a heat exchange device to form a cooled mixture, and contacting the cooled mixture with a catalyst to form a fuel.

Abstract translation: 本文描述了制备燃料的方法。 一种方法可以包括提供第一工作流体，第二工作流体和第三工作流体。 该方法还可以包括将第一工作流体暴露于第一高压电场以产生第一等离子体，将第二工作流体暴露于第二高压电场以产生第二等离子体，并将第三工作流体暴露于第三等离子体 高压电场产生第三等离子体。 该方法还可以包括在处理室内提供和接触基于碳的原料与第三等离子体，第二等离子体和第一等离子体以形成混合物，使用热交换装置冷却混合物以形成冷却的混合物，以及 使冷却的混合物与催化剂接触以形成燃料。

公开(公告)号：WO2013101335A1

公开(公告)日：2013-07-04

申请号：PCT/US2012/060733

申请日：2012-10-18

Applicant: UOP LLC

Inventor： BHATTACHARYYA, Alakananda

IPC: C07C27/10 ,  C07C29/48 ,  C07C45/28 ,  C07C51/265 ,  C07C65/30

CPC classification number: C07C51/265 ,  C07C63/26

Abstract: A process for oxidizing an alkyl-aromatic compound is described. The process includes contacting the alkyl-aromatic compound, a solvent comprising a precursor of at least one ionic liquid, a bromine source, a catalyst, and an oxidizing agent to produce an oxidation product comprising at least one of an aromatic alcohol, an aromatic aldehyde, an aromatic ketone, and an aromatic carboxylic acid.

Abstract translation: 描述了一种氧化烷基 - 芳族化合物的方法。 该方法包括使烷基芳族化合物，包含至少一种离子液体的前体，溴源，催化剂和氧化剂的溶剂接触，以产生包含芳族醇，芳族醛 ，芳族酮和芳族羧酸。

公开(公告)号：WO2010077823A2

公开(公告)日：2010-07-08

申请号：PCT/US2009/067907

申请日：2009-12-14

Applicant: H R D CORPORATION ,  HASSAN, Abbas ,  BHATT, Harshad ,  HASSAN, Aziz ,  BORSINGER, Gregory, G.

Inventor： HASSAN, Abbas ,  BHATT, Harshad ,  HASSAN, Aziz ,  BORSINGER, Gregory, G.

IPC: B01J19/18 ,  B01F3/04 ,  C07C27/10 ,  C07B33/00 ,  C08F8/06

CPC classification number: B01F7/00766 ,  B01F13/1013 ,  B01F13/1016 ,  Y02P20/582

Abstract: In this disclosure, a system is described, comprising a shear device with at least one inlet and at least one outlet and a mixing vessel with at least one inlet and at least one outlet, wherein an inlet of the shear device is in fluid communication with an outlet of the mixing vessel. In certain embodiments, the shear device and the mixing vessel form a loop for fluid communication. Also disclosed herein is a method of high shear oxidation, comprising mixing an oxidant with a substrate to form a substrate-oxidant mixture and applying shear to the substrate-oxidant mixture to form a product. The product includes ethylene oxide, propylene oxide, terephthalic acid, phenol, acrylonitrile, maleic anhydride, phthalic anhydride, nitric acid, caprolactam, oxidized polyethylene, oxidized polypropylene, oxidized polyethylene copolymers, and oxidized polypropylene copolymers. Suitable oxidant includes air, oxygen, ozone, peroxide, organic peroxide, halogen, oxygen-containing gas, and halogen-containing gas.

Abstract translation: 在本公开中，描述了一种系统，其包括具有至少一个入口和至少一个出口的剪切装置以及具有至少一个入口和至少一个出口的混合容器，其中入口 剪切装置与混合容器的出口流体连通。 在某些实施例中，剪切装置和混合容器形成用于流体连通的回路。 本文还公开了高剪切氧化的方法，包括将氧化剂与底物混合以形成底物 - 氧化剂混合物，并对底物 - 氧化剂混合物施加剪切以形成产物。 该产品包括环氧乙烷，环氧丙烷，对苯二甲酸，苯酚，丙烯腈，马来酸酐，邻苯二甲酸酐，硝酸，己内酰胺，氧化聚乙烯，氧化聚丙烯，氧化聚乙烯共聚物和氧化聚丙烯共聚物。 合适的氧化剂包括空气，氧气，臭氧，过氧化物，有机过氧化物，卤素，含氧气体和含卤素气体。

公开(公告)号：WO2008008498A3

公开(公告)日：2008-09-18

申请号：PCT/US2007016012

申请日：2007-07-13

Applicant: UNIV IOWA RES FDTN ,  BAKER MAX T

Inventor： BAKER MAX T

IPC: C07C27/10 ,  C07C29/10 ,  C07C35/00

CPC classification number: C07C39/24

Abstract: Trisubstituted phenol compounds and methods of using the compounds, e.g., for anesthetizing a subject, are disclosed.

Abstract translation: 公开了三取代的酚化合物和使用该化合物的方法，例如用于麻醉受试者。

公开(公告)号：WO03062172B1

公开(公告)日：2004-04-08

申请号：PCT/US0222817

申请日：2002-07-17

Applicant: GRT INC ,  UNIV CALIFORNIA

Inventor： ZHOU XIAO PING ,  LORKOVIC IVAN MARC ,  SHERMAN JEFFREY A

IPC: C07C29/48 ,  C07B61/00 ,  C07C17/10 ,  C07C29/124 ,  C07C31/04 ,  C07C41/01 ,  C07C45/27 ,  C07C27/10 ,  B01J8/02 ,  B01J8/04 ,  B01J8/08 ,  B01J10/00 ,  B01J35/02 ,  C07B41/02 ,  C07C27/12 ,  C07C27/14 ,  C07C27/16

CPC classification number: C07C29/124 ,  C07C17/10 ,  C07C41/01 ,  C07C45/27 ,  Y02P20/125 ,  C07C19/075 ,  C07C31/08 ,  C07C43/06 ,  C07C47/06

Abstract: Alcohols, ethers, and olefins are manufactured from alkanes by mixing an alkane and bromine in a reactor to form alkyl bromide and hydrogen bromide. The alkyl bromide only or the alkyl bromide and the hydrogen bromide are directed into contact with metal oxide to form an alcohol and/or an ether, or an olefin and metal bromide. The metal bromide is oxidized to form original metal oxide and bromine, both of which are recycled.

Abstract translation: 通过在反应器中混合烷烃和溴以形成烷基溴和溴化氢，由烷烃制备醇，醚和烯烃。 仅将烷基溴或烷基溴和溴化氢引导与金属氧化物接触以形成醇和/或醚，或烯烃和金属溴化物。 金属溴化物被氧化以形成原始的金属氧化物和溴，这两者都被再循环。

公开(公告)号：WO2021055270A1

公开(公告)日：2021-03-25

申请号：PCT/US2020/050650

申请日：2020-09-14

Applicant: CHEVRON PHILIPS CHEMICAL COMPANY LP

Inventor： MCDANIEL, Max, P. ,  CRUZ, Carlos, A. ,  MONWAR, Masud, M. ,  BARR, Jared, L. ,  ELLIS, William, C.

IPC: C07C45/29 ,  C07C31/20 ,  C07C47/02 ,  C07C49/04 ,  C07C29/48 ,  C07C27/10

Abstract: Processes for converting a hydrocarbon reactant into an alcohol compound and/or a carbonyl compound are disclosed, and these processes include the steps of irradiating the hydrocarbon reactant and a supported chromium catalyst comprising chromium in a hexavalent oxidation state with a light beam at a wavelength in the UV- visible spectrum to reduce at least a portion of the supported chromium catalyst to form a reduced chromium catalyst, and hydrolyzing the reduced chromium catalyst to form a reaction product comprising the alcohol compound and/or the carbonyl compound. In addition, these processes can further comprise a step of calcining all or a portion of the reduced chromium catalyst to regenerate the supported chromium catalyst.

公开(公告)号：WO2015076954A2

公开(公告)日：2015-05-28

申请号：PCT/US2014/061088

申请日：2014-10-17

Applicant: EXXONMOBIL CHEMICAL PATENTS INC.

Inventor： DAKKA, Jihad, M. ,  PATEL, Bryan, A.

IPC: C07C27/10

CPC classification number: C07C37/08 ,  B01J31/0247 ,  C07C7/10 ,  C07C37/72 ,  C07C45/53 ,  C07C407/00 ,  C07C407/003 ,  C07C2601/14 ,  C07C2601/16 ,  Y02P20/52 ,  C07C39/04 ,  C07C409/14 ,  C07C49/403 ,  C07C13/28

Abstract: A process for making phenol and/or cyclohexanone comprises: (A) oxidizing a cyclohexylbenzene feed to obtain an oxidation product comprising cyclohexylbenzene, cyclohexyl-1 -phenyl- 1 -hydroperoxide and phenol; (B) separating at least a portion of the oxidation product to obtain a first fraction comprising cyclohexyl- 1 -phenyl- 1 -hydroperoxide and a second fraction comprising cyclohexylbenzene and phenol; (C) removing at least a portion of the phenol from at least a portion of the second fraction to obtain a third fraction; (D) recycling at least a portion of the cyclohexylbenzene in the third fraction to the oxidizing step (A); and (E) contacting at least a portion of the cyclohexyl-1 -phenyl- 1 -hydroperoxide in the first fraction with an acid catalyst in a cleavage reactor under cleavage conditions to obtain a cleavage product comprising phenol and cyclohexanone.

Abstract translation: 制备苯酚和/或环己酮的方法包括：（A）氧化环己基苯进料以获得包含环己基苯，环己基-1-苯基-1-氢过氧化物和苯酚的氧化产物; （B）分离至少一部分氧化产物以获得包含环己基-1-苯基-1-氢过氧化物的第一馏分和包含环己基苯和苯酚的第二馏分; （C）从第二级分的至少一部分除去至少一部分苯酚以获得第三级分; （D）将第三馏分中的至少一部分环己基苯回收至氧化步骤（A）; 和（E）在裂解反应器中在裂解条件下将第一馏分中的环己基-1-苯基-1-氢过氧化物的至少一部分与酸催化剂接触，得到包含苯酚和环己酮的裂解产物。