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公开(公告)号：EP3102552A1
公开(公告)日：2016-12-14
申请号：EP14824195.3
申请日：2014-12-04
Applicant: ExxonMobil Research and Engineering Company
Inventor： McCARTHY, Stephen J. , VIJAY, Rohit , RATERMAN, Michael Francis , PETERSON, Brian , HICKEY, Karlton J. , DAAGE, Michel , LOVELESS, Brett , GUPTA, Ramesh , BIELENBERG, Patricia A.
CPC classification number: B01J29/405 , B01J21/04 , B01J23/06 , B01J27/14 , B01J29/061 , B01J29/7049 , B01J29/90 , B01J35/10 , B01J35/1014 , B01J35/1019 , B01J35/1023 , B01J35/1057 , B01J35/108 , B01J35/109 , B01J37/0009 , B01J37/0201 , B01J38/02 , B01J38/12 , B01J2229/186 , B01J2229/20 , B01J2229/42 , C07C1/20 , C07C1/22 , C07C2523/06 , C07C2529/40 , C07C2529/70 , C10G3/45 , C10G3/49 , C10G3/55 , C10L1/06 , C10L2200/0423 , C10L2200/0469 , C10L2270/023 , Y02P20/584 , Y02P30/20 , Y02P30/42 , C07C11/02 , C07C15/02
Abstract: A catalyst composition comprises a self-bound zeolite and a Group 12 transition metal selected from the group consisting of Zn, Cd, or a combination thereof, the zeolite having a silicon to aluminum ratio of at least about 10, the catalyst composition having a micropore surface area of at least about 340 m2/g, a molar ratio of Group 12 transition metal to aluminum of about 0.1 to about 1.3, and at least one of: (a) a mesoporosity of greater than about 20 m2/g; (b) a diffusivity for 2,2-dimethylbutane of greater than about 1×10−2 sec−1 when measured at a temperature of about 120° C. and a 2,2-dimethylbutane pressure of about 60 torr (about 8 kPa).
Abstract translation: 公开了有机化合物转化方法。 具体方法包括提供基于第一混合物的重量的包含≥10.0wt％的至少一种含氧化合物的第一混合物; 在有效将第一混合物的至少一部分转化成包含水，氢和一种或多种烃的产物流的条件下，使至少第一移动床反应器中的第一混合物与催化剂接触; 并从所述产物流（i）中分离出至少一种轻质物流，和ii）至少一种重质流，其中所述方法的特征在于再循环比为＆lt;
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公开(公告)号：EP3237111A1
公开(公告)日：2017-11-01
申请号：EP15819917.4
申请日：2015-12-02
Applicant: ExxonMobil Research and Engineering Company
Inventor： ILIAS, Samia , LOVELESS, Brett , MCCARTHY, Stephen, J. , VIJAY, Rohit
CPC classification number: C07C1/20 , B01J23/06 , B01J29/405 , B01J35/023 , B01J35/1019 , B01J37/04 , B01J37/28 , C07C2523/06 , C07C2529/40 , C10G3/49 , C10G2400/20 , C10G2400/22 , C10G2400/30 , C07C11/02 , C07C15/00 , C07C9/00
Abstract: Described herein are processes for production of hydrocarbon products comprising contacting a feed comprising methanol and/or dimethyl ether with a catalyst composition, which comprises a zeolite having a constraint index from 1-12 and an active binder comprising a metal oxide with a dehydrogenation function, under conditions sufficient to form the hydrocarbon product, wherein the hydrocarbon product comprises aromatics, olefins, and/or paraffins. Also described herein are catalyst compositions comprising a zeolite having a 10-/12-membered ring framework and a microporous surface area of at least 150 m
2 /g, and from ~1 wt% to ~10 wt% of a zinc oxide binder, the catalyst composition having a zinc to aluminum atomic ratio from ~0.08 to ~8.5.Abstract translation: 本文描述了用于生产烃产物的方法，其包括使包含甲醇和/或二甲醚的进料与催化剂组合物接触，所述催化剂组合物包含约束指数为1-12的沸石和包含具有脱氢功能的金属氧化物的活性粘合剂， 在足以形成烃产物的条件下，其中烃产物包含芳族化合物，烯烃和/或链烷烃。 本文还描述了包含具有10- / 12-元环骨架和微孔表面积为至少150m 2 / g的沸石和约1重量％〜约10重量％的氧化锌粘合剂的催化剂组合物， 该催化剂组合物具有约0.08至约8.5的锌与铝的原子比。
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3.发明公开METHODS FOR CONVERTING OXYGENATES INTO HYDROCARBONS 审中-公开富勒华ZUR UMWANDLUNG VON OXYGENATEN在KOHLENWASSERSTOFFE
公开(公告)号：EP3114100A1
公开(公告)日：2017-01-11
申请号：EP14816061.7
申请日：2014-12-04
Applicant: ExxonMobil Research and Engineering Company
Inventor： LOVELESS, Brett , ELIA, Christine N. , McCARTHY, Stephen J.
CPC classification number: B01J29/405 , B01J21/04 , B01J23/06 , B01J27/14 , B01J29/061 , B01J29/7049 , B01J29/90 , B01J35/10 , B01J35/1014 , B01J35/1019 , B01J35/1023 , B01J35/1057 , B01J35/108 , B01J35/109 , B01J37/0009 , B01J37/0201 , B01J38/02 , B01J38/12 , B01J2229/186 , B01J2229/20 , B01J2229/42 , C07C1/20 , C07C1/22 , C07C2523/06 , C07C2529/40 , C07C2529/70 , C10G3/45 , C10G3/49 , C10G3/55 , C10L1/06 , C10L2200/0423 , C10L2200/0469 , C10L2270/023 , Y02P20/584 , Y02P30/20 , Y02P30/42 , C07C11/02 , C07C15/02
Abstract: A catalyst composition comprises a self-bound zeolite and a Group 12 transition metal selected from the group consisting of Zn, Cd, or a combination thereof, the zeolite having a silicon to aluminum ratio of at least about 10, the catalyst composition having a micropore surface area of at least about 340 m2/g, a molar ratio of Group 12 transition metal to aluminum of about 0.1 to about 1.3, and at least one of: (a) a mesoporosity of greater than about 20 m2/g; (b) a diffusivity for 2,2-dimethylbutane of greater than about 1×10−2 sec−1 when measured at a temperature of about 120° C. and a 2,2-dimethylbutane pressure of about 60 torr (about 8 kPa).
Abstract translation: 公开了有机化合物转化方法。 具体方法包括提供基于第一混合物的重量的包含≥10.0wt％的至少一种含氧化合物的第一混合物; 在有效将第一混合物的至少一部分转化成包含水，氢和一种或多种烃的产物流的条件下，使至少第一移动床反应器中的第一混合物与催化剂接触; 并从所述产物流（i）中分离出至少一种轻质物流，和ii）至少一种重质流，其中所述方法的特征在于再循环比为＆lt;
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4.发明公开
公开(公告)号：EP3083535A1
公开(公告)日：2016-10-26
申请号：EP14821943.9
申请日：2014-12-04
Applicant: ExxonMobil Research and Engineering Company
Inventor： MCCARTHY, Stephen J. , VIJAY, Rohit , LOVELESS, Brett
IPC: C07C15/08 , C07C1/20 , C07C15/02 , C10G3/00 , B01J38/02 , B01J38/12 , B01J21/04 , B01J23/06 , B01J29/40 , B01J29/90 , B01J35/10 , B01J37/02
CPC classification number: B01J29/405 , B01J21/04 , B01J23/06 , B01J27/14 , B01J29/061 , B01J29/7049 , B01J29/90 , B01J35/10 , B01J35/1014 , B01J35/1019 , B01J35/1023 , B01J35/1057 , B01J35/108 , B01J35/109 , B01J37/0009 , B01J37/0201 , B01J38/02 , B01J38/12 , B01J2229/186 , B01J2229/20 , B01J2229/42 , C07C1/20 , C07C1/22 , C07C2523/06 , C07C2529/40 , C07C2529/70 , C10G3/45 , C10G3/49 , C10G3/55 , C10L1/06 , C10L2200/0423 , C10L2200/0469 , C10L2270/023 , Y02P20/584 , Y02P30/20 , Y02P30/42 , C07C11/02 , C07C15/02
Abstract: A catalyst composition comprises a self-bound zeolite and a Group 12 transition metal selected from the group consisting of Zn, Cd, or a combination thereof, the zeolite having a silicon to aluminum ratio of at least about 10, the catalyst composition having a micropore surface area of at least about 340 m2/g, a molar ratio of Group 12 transition metal to aluminum of about 0.1 to about 1.3, and at least one of: (a) a mesoporosity of greater than about 20 m2/g; (b) a diffusivity for 2,2-dimethylbutane of greater than about 1×10−2 sec−1 when measured at a temperature of about 120° C. and a 2,2-dimethylbutane pressure of about 60 torr (about 8 kPa).
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Patent Agency Ranking5.发明公开VEHICLE POWERTRAIN WITH ONBOARD CATALYTIC REFORMER 审中-公开FAHRZEUGGETRIEBE MIT INTEGRIERTEM KATALYTISCHEN改良剂
公开(公告)号：EP3080040A1
公开(公告)日：2016-10-19
申请号：EP14827309.7
申请日：2014-12-11
Applicant: Exxonmobil Research And Engineering Company
Inventor： WEISS, Brian M. , WEISSMAN, Walter , BEUTEL, Tilman W. , BRODY, John F. , CHOI, Eugine , LI, Wenjun , MADIARA, Paul D. , KLIEWER, Chris E. , STROHMAIER, Karl G. , WEIGEL, Scott J. , LOVELESS, Brett , KOIKE, Makota , MYAGAWA, Hiroshi
CPC classification number: F02M27/02 , B01J21/04 , B01J21/08 , B01J23/10 , B01J23/464 , B01J23/63 , B01J29/005 , B01J29/068 , B01J29/44 , B01J29/70 , B01J29/743 , B01J29/80 , B01J29/85 , B01J2523/00 , C01B3/40 , C01B2203/0233 , C01B2203/0238 , C01B2203/1047 , C01B2203/1064 , C01B2203/107 , C01B2203/1082 , C01B2203/1241 , C01B2203/1247 , C01B2203/84 , C10L3/00 , C10L3/08 , C10L3/10 , C10L2230/22 , C10L2270/02 , C10L2290/02 , C10L2290/06 , C10L2290/24 , F01N3/20 , F02B37/013 , F02B43/12 , F02B51/02 , F02B61/02 , F02B2043/103 , F02M21/0227 , F02M26/05 , F02M26/20 , F02M26/35 , F02M26/36 , Y02P20/142 , Y02P20/52 , Y02T10/126 , Y02T10/32 , B01J2523/31 , B01J2523/3706 , B01J2523/3712 , B01J2523/48 , B01J2523/822
Abstract: Catalyst compositions suitable for use in the exhaust gas recycle stream of an internal combustion engine are provided. Such catalyst compositions typically provide significant amounts of methane in addition to syngas. A reformer incorporating such a catalyst for use in an exhaust gas recycle portion of an internal combustion engine powertrain is described. A powertrain incorporating such a reformer, a method of increasing the octane rating of an exhaust gas recycle stream, and a method of operating an internal combustion engine using methane-assisted combustion are also described.
Abstract translation: 提供了适合用于内燃机废气再循环流的催化剂组合物。 除了合成气之外，这种催化剂组合物通常提供大量的甲烷。 描述了一种包含用于内燃机动力总成的废气再循环部分的催化剂的重整器。 还描述了结合这种重整器的动力总成，增加废气再循环流的辛烷值的方法以及使用甲烷辅助燃烧来操作内燃机的方法。
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6.发明公开APPARATUS AND PROCESS FOR PRODUCING GASOLINE, OLEFINS AND AROMATICS FROM OXYGENATES 审中-公开从氧化物生产汽油，烯烃和芳香剂的装置和方法
公开(公告)号：EP3204467A1
公开(公告)日：2017-08-16
申请号：EP15782153.9
申请日：2015-10-01
Applicant: Exxonmobil Research And Engineering Company
Inventor： DU, Bing , TABAK, Samuel, A. , HINDMAN, Mitch, L. , SHEN, Eric, B. , JOHNSON, David, L. , HARANDI, Mohsen, N. , SUTTON, Clay, R. , HAN, Lu , RATERMAN, Michael, F. , WANG, Zhongcheng , ILLIAS, Samia , LOVELESS, Brett , McCARTHY, Stephen, J.
CPC classification number: C07C1/20 , B01J8/0055 , B01J8/1836 , B01J8/24 , B01J8/26 , B01J8/34 , B01J2208/00256 , B01J2208/00274 , B01J2208/0084 , B01J2208/00893 , C07C2/56 , C07C2/864 , C07C2/865 , C07C2521/16 , C07C2529/40 , C10G3/49 , C10G3/57 , C10G3/62 , C10G2300/4081 , C10G2400/02 , C10G2400/20 , C10G2400/28 , C10G2400/30 , C10L1/06 , Y02P30/20 , Y02P30/42
Abstract: Apparatuses and processes for converting an oxygenate feedstock, such as methanol and dimethyl ether, in a fluidized bed containing a catalyst to hydrocarbons, such as gasoline boiling components, olefins and aromatics are provided herein.
Abstract translation: 本文提供了将含有催化剂的流化床中的含氧化合物原料例如甲醇和/或二甲醚转化为烃例如汽油沸点组分，烯烃和芳族化合物的装置和方法。
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7.发明公开ALUMINA BOUND CATALYST FOR SELECTIVE CONVERSION OF OXYGENATES TO AROMATICS 审中-公开粘土结合催化剂的芳烃含氧化合物选择性转化
公开(公告)号：EP3083534A1
公开(公告)日：2016-10-26
申请号：EP14821942.1
申请日：2014-12-04
Applicant: ExxonMobil Research and Engineering Company
Inventor： MCCARTHY, Stephen J. , VIJAY, Rohit , LOVELESS, Brett
IPC: C07C15/08 , C07C1/20 , C07C15/02 , C10G3/00 , B01J38/02 , B01J38/12 , B01J21/04 , B01J23/06 , B01J29/40 , B01J29/90 , B01J35/10 , B01J37/02
CPC classification number: B01J29/405 , B01J21/04 , B01J23/06 , B01J27/14 , B01J29/061 , B01J29/7049 , B01J29/90 , B01J35/10 , B01J35/1014 , B01J35/1019 , B01J35/1023 , B01J35/1057 , B01J35/108 , B01J35/109 , B01J37/0009 , B01J37/0201 , B01J38/02 , B01J38/12 , B01J2229/186 , B01J2229/20 , B01J2229/42 , C07C1/20 , C07C1/22 , C07C2523/06 , C07C2529/40 , C07C2529/70 , C10G3/45 , C10G3/49 , C10G3/55 , C10L1/06 , C10L2200/0423 , C10L2200/0469 , C10L2270/023 , Y02P20/584 , Y02P30/20 , Y02P30/42 , C07C11/02 , C07C15/02
Abstract: A catalyst composition comprises a self-bound zeolite and a Group 12 transition metal selected from the group consisting of Zn, Cd, or a combination thereof, the zeolite having a silicon to aluminum ratio of at least about 10, the catalyst composition having a micropore surface area of at least about 340 m2/g, a molar ratio of Group 12 transition metal to aluminum of about 0.1 to about 1.3, and at least one of: (a) a mesoporosity of greater than about 20 m2/g; (b) a diffusivity for 2,2-dimethylbutane of greater than about 1×10−2 sec−1 when measured at a temperature of about 120° C. and a 2,2-dimethylbutane pressure of about 60 torr (about 8 kPa).
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公开(公告)号：EP3083533A1
公开(公告)日：2016-10-26
申请号：EP14821941.3
申请日：2014-12-04
Applicant: ExxonMobil Research and Engineering Company
Inventor： LOVELESS, Brett , VIJAY, Rohit , ILIAS, Samia , MCCARTHY, Stephen J.
IPC: C07C15/08 , C07C1/20 , C07C15/02 , C10G3/00 , B01J38/02 , B01J38/12 , B01J23/06 , B01J29/40 , B01J29/90 , B01J35/10 , B01J37/02
CPC classification number: B01J29/405 , B01J21/04 , B01J23/06 , B01J27/14 , B01J29/061 , B01J29/7049 , B01J29/90 , B01J35/10 , B01J35/1014 , B01J35/1019 , B01J35/1023 , B01J35/1057 , B01J35/108 , B01J35/109 , B01J37/0009 , B01J37/0201 , B01J38/02 , B01J38/12 , B01J2229/186 , B01J2229/20 , B01J2229/42 , C07C1/20 , C07C1/22 , C07C2523/06 , C07C2529/40 , C07C2529/70 , C10G3/45 , C10G3/49 , C10G3/55 , C10L1/06 , C10L2200/0423 , C10L2200/0469 , C10L2270/023 , Y02P20/584 , Y02P30/20 , Y02P30/42 , C07C11/02 , C07C15/02
Abstract: A catalyst composition comprises a self-bound zeolite and a Group 12 transition metal selected from the group consisting of Zn, Cd, or a combination thereof, the zeolite having a silicon to aluminum ratio of at least about 10, the catalyst composition having a micropore surface area of at least about 340 m2/g, a molar ratio of Group 12 transition metal to aluminum of about 0.1 to about 1.3, and at least one of: (a) a mesoporosity of greater than about 20 m2/g; (b) a diffusivity for 2,2-dimethylbutane of greater than about 1×10−2 sec−1 when measured at a temperature of about 120° C. and a 2,2-dimethylbutane pressure of about 60 torr (about 8 kPa).
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公开(公告)号：EP3083532A1
公开(公告)日：2016-10-26
申请号：EP14821940.5
申请日：2014-12-04
Applicant: Exxonmobil Research And Engineering Company
Inventor： MCCARTHY, Stephen J. , LOVELESS, Brett , VIJAY, Rohit
IPC: C07C15/08 , C07C1/20 , C07C15/02 , C10G3/00 , B01J38/02 , B01J38/12 , B01J21/04 , B01J23/06 , B01J29/40 , B01J29/90 , B01J35/10 , B01J37/02
CPC classification number: B01J29/405 , B01J21/04 , B01J23/06 , B01J27/14 , B01J29/061 , B01J29/7049 , B01J29/90 , B01J35/10 , B01J35/1014 , B01J35/1019 , B01J35/1023 , B01J35/1057 , B01J35/108 , B01J35/109 , B01J37/0009 , B01J37/0201 , B01J38/02 , B01J38/12 , B01J2229/186 , B01J2229/20 , B01J2229/42 , C07C1/20 , C07C1/22 , C07C2523/06 , C07C2529/40 , C07C2529/70 , C10G3/45 , C10G3/49 , C10G3/55 , C10L1/06 , C10L2200/0423 , C10L2200/0469 , C10L2270/023 , Y02P20/584 , Y02P30/20 , Y02P30/42 , C07C11/02 , C07C15/02
Abstract: A catalyst composition comprises a self-bound zeolite and a Group 12 transition metal selected from the group consisting of Zn, Cd, or a combination thereof, the zeolite having a silicon to aluminum ratio of at least about 10, the catalyst composition having a micropore surface area of at least about 340 m2/g, a molar ratio of Group 12 transition metal to aluminum of about 0.1 to about 1.3, and at least one of: (a) a mesoporosity of greater than about 20 m2/g; (b) a diffusivity for 2,2-dimethylbutane of greater than about 1×10−2 sec−1 when measured at a temperature of about 120° C. and a 2,2-dimethylbutane pressure of about 60 torr (about 8 kPa).
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