摘要:
Methods and compositions are provided for inhibiting the polymerization of vinyl aromatic monomers under distillation conditions. The compositions comprise a combination of a phenylenediamine compound and a hydroxylamine compound.
摘要:
There is disclosed a mass production process of 1,4,5,8-naphthalene tetracarboxylic acid with high collection efficiency. In the presence of an alkaline metallic catalyst, 1,3-butadiene was added to the ethyl radicals of ethyl-p-xylene, and cyclized to 1,4,5,8-tetramethyl-1,2,3,4-tetrahydronaphthalene which was further dehydrogenated and oxidized to obtain 1,4,5,8-naphthalene tetracarboxylic acid, so that a constant supply of inexpensive 1,4,5,8-naphthalene tetracarboxylic acid can be achieved as an intermediate raw material for dye, pigment, resins, or the like.
摘要:
In a process for producing an alkenylbenzene by the reaction of an alkylbenzene having 8 or more carbon atoms and a conjugated diolefin, the improvement in which the reaction is performed in the presence of a catalyst obtained by dispersing (a) an alkali metal and (b) potassium carbonate and/or potassium hydroxide in the presence of (c) an aromatic hydrocarbon having at least a substituent with a double bond.
摘要:
This invention relates to a process for the production of alpha, para-dimethyl styrene by catalytic dehydrogenation of para-cymene in the substantial absence of oxygen or an oxidising gas and in the presence of steam. The catalyst used is iron oxide, Fe₃O₄. The reaction is carried out at a temperature in the range from 500 to 700°C and a pressure from 0.1 to 10 atmospheres. The product is a valuable intermediate for the manufacture of perfumes.
摘要翻译:本发明涉及通过在基本上没有氧气或氧化气体和蒸气存在下催化脱氢对甲基异丙苯生产α-对二甲基苯乙烯的方法。 所使用的催化剂是氧化铁,Fe 3 O 4。 反应在500-700℃的温度和0.1-10个大气压的压力下进行。 该产品是制造香水的有价值的中间体。
摘要:
Vinylaromatic compounds are stabilized against undesired polymerization by adding to the vinylaromatic compounds small amounts of zinc or nickel salts of dialkyl dithiocarbamates, specifically p-diisopropenylbenzene can be stabilized by the use of zinc dibutyldithiocarbamate.
摘要:
Diisopropenylbenzene is a monomer that can be used in the preparation of many useful polymers and is also a chemical intermediate that can be employed in a number of chemical processes. Diisopropenylbenzene is normally synthesized by the dehydrogenation of diisopropylbenzene. Unfortunately in this dehydrogenation process a number of olefinic impurities are produced as by-products. This invention discloses a process for the separation of diisopropenylbenzene from these impurities and for recycling some of the impurities. In one embodiment of this invention this process comprises: (1) dehydrogenating diisopropylbenzene to form a dehydrogenation mixture containing diisopropenylbenzene and organic impurities, (2) continuously distilling said dehydrogenation mixture to separate said diisopropenylbenzene from said organic impurities in a continuous recovery column 10, (3) fully hydrogenating said organic impurities to form a mixture of regenerated diisopropylbenzene and saturated organic impurities, and (4) fractionally distilling said mixture of regenerated diisopropylbenzene and saturated organic impurities under conditions sufficient to separate said regenerated diisopropylbenzene from said saturated organic impurities. The regenerated diisopropylbenzene can then be recycled for dehydrogenation with fresh diisopropylbenzene in the first step of the above described process.
摘要:
A method for the catalytic dehydrogenation of p-ethyltoluene to p-methylstyrene in which the formation of proliferous polymer in the condenser is prevented by adding minor amounts of H 2 S continuously to the gaseous product effluent entering the condenser.