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    Process for the preparation of nickel ylides containing sulfonated group V ligands
    91.
    发明公开
    Process for the preparation of nickel ylides containing sulfonated group V ligands 失效
    制备含有硫化V族配体的镍丝的方法

    公开(公告)号：EP0046330A3

    公开(公告)日：1982-05-19

    申请号：EP81302657

    申请日：1981-06-15

    申请人： GULF RESEARCH & DEVELOPMENT COMPANY

    发明人： Beach, David L. ,  Harrison, James J.

    IPC分类号： C07F15/04 ,  B01J31/28 ,  C07C02/08

    CPC分类号： C07F15/04 ,  B01J31/1895 ,  B01J31/2247 ,  B01J31/2404 ,  B01J2231/20 ,  B01J2531/847 ,  B01J2540/32 ,  C07C2/36

    摘要： A process is provided for preparing nickel ylides wich are themselves novel compounds defined by the following Formula I:
    wherein R,, R 2 , R 3 , R 4 , R 5 , R 6 , R 7 and R 8 are either alike or different members selected from the group consisting of hydrogen, alkyl radicals having from about one to about 24 carbon atoms, preferably from about one to about 10 carbon atoms; aryl radicals having from about six to about 20 carbon atoms, preferably from about six to about 10 carbon atoms; alkenyl radicals having from about two to about 30 carbon atoms, preferably from about two to about 20 carbon atoms; cycloalkyl radicals having from about three to about 40 carbon atoms, preferably from about three to about 30 carbon atoms; aralkyl and alkaryl radicals having from about six to about 40 carbon atoms, preferably from about six to about 30 carbon atoms; a halogen radical selected from the group consisting of fluorine, chlorine, bromine and iodine, preferably chlorine; a hydroxyl group; an alkoxy or aryloxy group; a hydrocarbyl group, such as defined above, carrying halogen, hydroxyl or alkoxy or aryloxy; and a sulfonato group (-SO 3 - ) or an alkyl, aryl, alkenyl, cycloalkyl, aralkyl or alkaryl group carrying a sulfonato group; provided that at least one sulfonato group is located in R 4 , R s and R. and at least one of R 4 , R s and R 6 is aryl; M is sulfur or oxygen, preferably oxygen; E is phosphorus, arsenic, antimony or nitrogen, preferably phosphorus; and F is phosphorus, arsenic or antimony, preferably phosphorus. The process comprises sulfonating a ligand defined by the following formula:
    and then reacting the resulting sulfonated ligand with (1) a zero valent nickel compound and (2) a ylide defined by the following formula: wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , E, F and M are as defined above, provided that at least one of R 4 , R 5 and R 6 is an aryl group.

    摘要翻译： 提供了一种制备本发明化合物的方法，该方法本身是由下式I定义的新化合物：其中R 1，R 2，R 3，R 4，R 5，R 6，R 7和R 8是相同或不同的选自 的氢，具有约1至约24个碳原子，优选约1至约10个碳原子的烷基; 具有约6至约20个碳原子，优选约6至约10个碳原子的芳基; 具有约2至约30个碳原子，优选约2至约20个碳原子的烯基; 具有约3至约40个碳原子，优选约3至约30个碳原子的环烷基; 具有约6至约40个碳原子，优选约6至约30个碳原子的芳烷基和烷芳基; 选自氟，氯，溴和碘的卤素，优选氯; 羟基; 烷氧基或芳氧基; 如上所定义的烃基，其含有卤素，羟基或烷氧基或芳氧基; 和磺酸基（-SO 3 - ）或具有磺酸基的烷基，芳基，烯基，环烷基，芳烷基或烷芳基; 条件是至少一个磺酸根基团位于R 4，R 5和R 6中，并且R 4，R 5和R 6中的至少一个是芳基; M是硫或氧，优选氧; E是磷，砷，锑或氮，优选磷; F是磷，砷或锑，优选磷。 该方法包括将由下式定义的配体磺化：，然后使所得磺化配体与（1）零价镍化合物和（2）由下式定义的叶立德反应：其中R1，R2 R 3，R 4，R 5，R 6，R 7，R 8，E，F和M如上所定义，条件是R 4，R 5和R 6中的至少一个为芳基。

    Process for the preparation of nickel ylides containing directly sulfonated ylide ligands
    92.
    发明公开
    Process for the preparation of nickel ylides containing directly sulfonated ylide ligands 失效
    Verfahren zur Herstellung von direktulfierte Ylideligande enthaltenden Nickelyliden。

    公开(公告)号：EP0046628A2

    公开(公告)日：1982-03-03

    申请号：EP81302655.6

    申请日：1981-06-15

    申请人： GULF RESEARCH & DEVELOPMENT COMPANY

    发明人： Beach, David L. ,  Harrison, James J.

    IPC分类号： C07F15/04 ,  B01J31/28 ,  C07C2/08

    CPC分类号： C07F15/04 ,  B01J31/1895 ,  B01J31/2247 ,  B01J31/2404 ,  B01J2231/20 ,  B01J2531/847 ,  B01J2540/32 ,  C07C2/36 ,  C07F9/5352 ,  C07F9/743 ,  C07F9/904

    摘要： A process is provided for preparing nickel ylides which are themselves novel compounds defined by the following Formula I
    wherein R i , R 2 , R 3 , and R 7 are either alike or different members selected from the group consisting of hydrogen, alkyl radicals having from about one to about 24 carbon atoms, preferably from about one to about 10 carbon atoms; aryl radicals having from about six to about 20 carbon atoms, preferably from about six to about 10 carbon atoms; alkenyl radicals having from about two to about 30 carbons atoms, preferably from about two to about 20 carbon atoms; cycloalkyl radicals having from about three to about 40 carbon atoms, preferably from about three to about 30 carbon atoms; aralkyl and alkaryl radicals having from about six to about 40 carbon atoms, preferably from about six to about 30 carbon atoms; a halogen radical selected from the group consisting of fluorine, chlorine, bromine and iodine, preferably chlorine; a hydroxyl group; an alkoxy or aryloxy group; and a hydrocarbyl group, such as defined above, carrying halogen, hydroxyl or alkoxy or aryloxy; R 4 , R 5 and R 6 are either alike or different members selected from the group consisting of a hydrocarbyl group as defined above, a sulfonato group (-SO 3 - ) or a sulfonated hydrocarbyl group; M is sulfur or oxygen, preferably oxygen; E is phosphorus, arsenic, antimony or nitrogen, preferably phosphorus; and F is phosphorus, arsenic or antimony, preferably phosphorus. The process comprises sulfonating a metal ylide defined by the following Formula II:
    to obtain the sulfonated ylide defined by the following Formula III:
    wherein R 1 , R 2 , R 3 , R 7 , F and M are as defined above. The sulfonated ylide is reacted with a base to obtain the metal ylide defined by the following Formula IV:
    wherein R 1 , R 2 , R 3 , R 7 , F and M are as defined above and A is the cationic portion of the base used. This ylide is then reacted with (1) a zero valent nickel compound and (2) a ligand having the formula:
    wherein R 4 , R 5 , R 6 and E are as defined above.

    摘要翻译： 提供了一种制备镍叶立德的方法，它本身是由下式I定义的新化合物：其中R 1，R 2，R 3和R 7是相同或不同的选自氢的基团， 约1至约24个碳原子，优选约1至约10个碳原子; 具有约6至约20个碳原子，优选约6至约10个碳原子的芳基; 具有约2至约30个碳原子，优选约2至约20个碳原子的烯基; 具有约3至约40个碳原子，优选约3至约30个碳原子的环烷基; 具有约6至约40个碳原子，优选约6至约30个碳原子的芳烷基和烷芳基; 选自氟，氯，溴和碘的卤素，优选氯; 羟基; 烷氧基或芳氧基; 和如上所定义的烃基，其含有卤素，羟基或烷氧基或芳氧基; R 4，R 5和R 6是选自如上定义的烃基，磺酸基（-SO 3 - ）或磺化烃基的组或不同的成员; M是硫或氧，优选氧; E是磷，砷，锑或氮，优选磷; F是磷，砷或锑，优选磷。 该方法包括将由下式II定义的金属叶立立磺化：以获得由下式III定义的磺化叶立德：其中R 1，R 2，R 3，R 7，F和M如上所定义。 将磺化叶立德与碱反应，得到由下式IV定义的金属叶酸：，