公开(公告)号：EP2537596B1

公开(公告)日：2016-06-08

申请号：EP11798015.1

申请日：2011-06-14

Applicant: Nippon Paint Marine Coatings Co., Ltd.

Inventor： EHARA, Ryo ,  MINAMI, Haruyasu ,  TOMIYAMA, Soichiro

IPC: B05D5/00 ,  B05D5/08 ,  B05D7/24 ,  C09D5/16 ,  C09D133/08 ,  C09D133/12 ,  C09D143/00 ,  C09D143/04 ,  C09D201/10 ,  C04B41/48 ,  C23C28/00

CPC classification number: C09D5/165 ,  B05D5/083 ,  B05D2201/00 ,  B05D2202/00 ,  B05D2203/30 ,  C04B41/483 ,  C09D5/1675 ,  C09D133/08 ,  C09D133/12 ,  C09D143/04 ,  C09D201/10 ,  C23C28/00 ,  Y10T428/31855 ,  Y10T428/31935

Abstract: Provided is a method of forming an antifouling coating film including the steps of [1] preparing a colored antifouling paint containing a prescribed Si-containing hydrolyzable resin and a color pigment such that a coating film having a target dry film thickness T completely hides a surface of an object to be coated, the colored antifouling paint has a color difference ”E1 between the coating film having the thickness T and a coating film having a dry film thickness of 0.8 T, at least 2.0, and preferably the colored antifouling paint has a color difference ”E2 between the coating film having the thickness T and a coating film having a dry film thickness of 1.2 T, less than 1, and [2] coating a surface of the object with the colored antifouling paint until the surface of the object is completely hidden by the coating film formed from the colored antifouling paint.

Abstract translation: 提供一种形成防污涂膜的方法，其包括以下步骤：[1]制备含有规定的含Si水解树脂和着色颜料的着色防污漆，使得具有目标干膜厚度T的涂膜完全隐藏表面 被涂物的颜色的防污涂料在厚度为T的涂膜和干膜厚度为0.8T的涂膜之间的色差“E1”至少为2.0，优选着色防污涂料具有 具有厚度T的涂膜和干膜厚度为1.2T，小于1的涂膜之间的色差“E2”，[2]用着色防污涂料涂覆物体的表面直到物体的表面 被彩色防污涂料形成的涂膜完全隐藏。

公开(公告)号：EP2816047A4

公开(公告)日：2015-11-25

申请号：EP13749533

申请日：2013-02-07

Applicant: ASAHI GLASS CO LTD

Inventor： MUROTANI EISUKE ,  HOSHINO TAIKI ,  KUNIMOTO AKINOBU ,  JOMUTA DAISUKE ,  OTOZAWA NOBUYUKI

IPC: C07F7/18 ,  C08G65/00 ,  C08G65/336 ,  C09D171/00 ,  C09K3/18

CPC classification number: C07F7/1836 ,  B05D1/005 ,  B05D1/02 ,  B05D1/18 ,  B05D1/204 ,  B05D1/28 ,  B05D1/30 ,  C03C17/30 ,  C03C17/328 ,  C03C2217/76 ,  C07F7/18 ,  C08G65/007 ,  C08G65/336 ,  C08G2650/48 ,  C09D7/1233 ,  C09D7/63 ,  C09D171/00 ,  C09D201/10 ,  C09K3/18 ,  C23C14/06 ,  C23C14/12 ,  Y10T428/31663

Abstract: To provide a fluorinated ether compound, a fluorinated ether composition and a coating liquid, whereby it is possible to form a surface-treated layer which has high initial water/oil repellency and which is excellent in abrasion resistance and fingerprint stain removability, and a substrate having a surface-treated layer and a method for its production. A fluorinated ether compound which has a poly(oxyperfluoroalkylene) chain ((±²) n ) made of at least two units (±²) linked to one another, and which has a hydrolysable silyl group on at least one terminal of the chain ((±²) n ) via a linking group, wherein each unit (±²) is a poly(oxyperfluoroalkylene) group comprising one to three groups (±) made of at least one type of a C 1-2 oxyperfluoroalkylene group and one to three groups (²) made of at least one type of a C 3-6 oxyperfluoroalkylene group.

Abstract translation: 以提供的氟化醚化合物，氟化醚组合物和涂布液，由此可以形成具有高的初始拒水/油性的表面处理层和所有其具有优异的耐磨损性和指纹去污性，和一个基片 具有表面处理层和用于其生产的方法。 其中有聚（oxyperfluoroalkylene）链（（±²）N）制成彼此连接的至少两个单元（±²），并且其中A的氟化醚化合物具有链中的至少一个终端上的可水解的甲硅烷基（ （±²）N）经由连接基团，每worin单元（±²）是包括由至少一种类型的一个C 1-2 oxyperfluoroalkylene组和一比一至三个基团（±）聚（oxyperfluoroalkylene）组 三组（²）由至少一种类型的一个C 3-6 oxyperfluoroalkylene组的。

公开(公告)号：EP2817377A4

公开(公告)日：2015-10-07

申请号：EP13751261

申请日：2013-02-06

Applicant: 3M INNOVATIVE PROPERTIES CO

Inventor： OLSON ERIK D ,  FLYNN RICHARD M ,  VITCAK DANIEL R ,  MANSKE KARL J ,  BECHTOLD KEVIN J ,  TAN LIAN S

IPC: C09D127/20 ,  C03C17/32 ,  C09D7/12

CPC classification number: C09D171/00 ,  C03C17/32 ,  C08G77/24 ,  C08G77/46 ,  C09D183/08 ,  C09D183/12 ,  C09D201/10

Abstract: A polymeric coating for a glass substrate includes a hexafluoropropylene oxide derived silane polymer. The hexafluoropropylene oxide derived silane polymer has a molecular weight of greater than about 5500, a thickness of between about 2 and about 15 nanometers and a coefficient of friction constant of less than about 0.35. A water contact angle of the polymeric hexafluoropropylene oxide derived silane coating decreases by less than about 27% after being subjected to 10000 abrasion cycles.

公开(公告)号：EP1990370B2

公开(公告)日：2015-08-12

申请号：EP07714032.5

申请日：2007-02-09

Applicant: KANEKA CORPORATION

Inventor： YANO, Ayako ,  NORO, Noriko ,  OKAMOTO, Toshihiko

IPC: C08L101/10 ,  C08K5/00 ,  C08K5/31 ,  C08L23/26 ,  C08L33/14 ,  C08L71/02 ,  C09J123/26 ,  C09J133/04 ,  C09J143/04 ,  C09J171/02 ,  C09J201/10 ,  C09K3/10

CPC classification number: C09K3/1018 ,  C08G65/336 ,  C08K5/0016 ,  C08K5/31 ,  C08L71/02 ,  C08L101/10 ,  C08L2666/22 ,  C09D201/10 ,  C09J133/14

Abstract: The present invention has its object to provide a curable composition which comprises a guanidine compound as a non-organotin type catalyst, is less discolored, has good surface curability, depth curability, strength rise and adhesiveness, and can retain the curability even after storage; the above object can be achieved by a curable composition which comprises: (A) an organic polymer containing a silyl group capable of crosslinking under siloxane bond formation, the silyl group being a group represented by the general formula (1): -SiX 3 (1) (wherein X represents a hydroxyl group or a hydrolyzable group and the three X groups may be mutually the same or different), (B) a guanidine compound (B-1) as a silanol condensation catalyst, and (C) a plasticizer, wherein the content of the component (B-1) is not lower than 0.1 part by weight but lower than 8 parts by weight per 100 parts by weight of the component (A), and a non-phthalate ester plasticizer accounts for 80 to 100% by weight of the (C) component plasticizer.

公开(公告)号：EP2561024A1

公开(公告)日：2013-02-27

申请号：EP11714268.7

申请日：2011-04-11

Applicant: Wacker Chemie AG

Inventor： STANJEK, Volker ,  BACHMEIER, Bernd-Josef ,  BAUER, Andreas

IPC: C09D183/04 ,  C08G65/336

CPC classification number: C09D167/00 ,  C08F8/42 ,  C08G65/336 ,  C08J3/243 ,  C08J2300/108 ,  C08K3/013 ,  C08K3/20 ,  C08K2003/2227 ,  C08K2003/265 ,  C09D133/00 ,  C09D171/02 ,  C09D183/04 ,  C09D201/10 ,  C08G63/695 ,  C08J3/24 ,  C08K5/5419 ,  C08K5/544 ,  C08L101/10

Abstract: The invention relates to a moisture-curing coating composition (C) containing A) 100 parts by weight of silane-terminated polymer (P) having end groups of the general formula (I) -A-Si(OR
1 )xR
2 3-x, B) from 7 to 200 parts by weight of reactive plasticizers (RP) of the general formula (II) R
3 -Si(OR
4 )yR
5 3-y, C) from 0 to 400 parts by weight of filler (F) and D) from 0.1 to 20 parts by weight of curing catalyst (K), where A is a linear or branched alkylene group having from 1 to 10 carbon atoms, R
1 , R
4 are each a linear or branched unsubstituted or halogen-substituted alkyl group having from 1 to 10 carbon atoms, R
2 , R
5 are each a linear or branched unsubstituted or halogen-substituted alkyl group having from 1 to 5 carbon atoms, R
3 is an aryl group or a linear, branched or cyclic alkyl group or alkenyl group having from 6 to 40 carbon atoms, in which individual carbon atoms can be replaced by organic radicals, where, if R
3 is a linear, branched or cyclic alkyl group or alkenyl group, the carbon chain may be interrupted by oxygen atoms, and x, y are each 1, 2 or 3, and also a method of sealing surfaces.

公开(公告)号：EP1360254B2

公开(公告)日：2012-12-26

申请号：EP01991619.6

申请日：2001-11-29

Applicant: KIMBERLY-CLARK WORLDWIDE, INC.

Inventor： SOERENS, Dave, A. ,  MALIK, Sohail ,  ROUNS, Cameron, G. ,  GREENE, Sharon, L. ,  AMBROSIO, Archel, A.

IPC: C09D201/10 ,  C09D171/00 ,  D06M15/19 ,  C08J7/04 ,  C09D101/10 ,  C09D157/06 ,  C08G65/336 ,  C09D171/02 ,  A61L33/00 ,  A61L29/00

CPC classification number: A61L29/085 ,  A61L15/60 ,  A61L31/10 ,  C08G65/336 ,  C08L71/02 ,  C09D201/10 ,  D06M15/19 ,  D06M15/53 ,  D06M2200/40 ,  Y10T428/31663 ,  Y10T442/20 ,  Y10T442/2311 ,  Y10T442/2328 ,  C08L2666/04

公开(公告)号：EP2493992A1

公开(公告)日：2012-09-05

申请号：EP10779109.7

申请日：2010-10-26

Applicant: PPG Industries Ohio, Inc.

Inventor： SCHMELTZER, Robert ,  DONALDSON, Susan F. ,  OLSON, Kevin C. ,  OLSON, Kurt G. ,  SCHWENDEMAN, John E. ,  SIMPSON, Dennis A. ,  WILLIAMS, Frank C.

IPC: C09D183/04 ,  C09D183/06 ,  C09D183/08 ,  C08G18/83 ,  C09D201/10

CPC classification number: C09D183/04 ,  C08G18/792 ,  C08K3/22 ,  C08K3/36 ,  C09D183/06 ,  C09D183/08 ,  C09D201/10 ,  C08L2666/02

Abstract: The present invention is directed to a coating composition, such as a substantially clear coating composition, which comprises (1) an alkoxysilane, (2) a polysiloxane, (3) a plurality of particles, and (4) curing agent that is reactive with the polysiloxane. The coating composition of the present invention can exhibit increased physical properties, such as scratch resistance, when compared to similar coating compositions that lack the components disclosed herein.

公开(公告)号：EP1985666B1

公开(公告)日：2010-12-15

申请号：EP07714031.7

申请日：2007-02-09

Applicant: Kaneka Corporation

Inventor： NORO , Noriko ,  WAKABAYASHI, Katsuyu ,  OKAMOTO, Toshihiko

IPC: C08L101/10 ,  C08K5/09 ,  C08K5/31 ,  C08L23/26 ,  C08L33/14 ,  C08L71/02 ,  C09J123/00 ,  C09J133/04 ,  C09J171/02 ,  C09J201/10 ,  C09K3/10 ,  C08G65/00 ,  C08G65/06 ,  C08G65/336

CPC classification number: C09K3/1018 ,  C08G65/336 ,  C08K5/0016 ,  C08K5/31 ,  C08L71/02 ,  C08L101/10 ,  C08L2666/22 ,  C09D201/10 ,  C09J133/14

Abstract: The present invention has its object to provide a curable composition which comprises a guanidine compound as a non-organotin type catalyst, is less discolored, has good surface curability, depth curability, strength rise and adhesiveness, and can retain the curability even after storage; the above object can be achieved by a curable composition which comprises: (A) an organic polymer containing a silyl group capable of crosslinking under siloxane bond formation, the silyl group being a group represented by the general formula (1): -SiX 3 (1) (wherein X represents a hydroxyl group or a hydrolyzable group and the three X groups may be mutually the same or different), (B) a guanidine compound (B-1) as a silanol condensation catalyst, and (C) a plasticizer, wherein the content of the component (B-1) is not lower than 0.1 part by weight but lower than 8 parts by weight per 100 parts by weight of the component (A), and a non-phthalate ester plasticizer accounts for 80 to 100% by weight of the (C) component plasticizer.

Abstract translation: 公开了使用脒化合物作为非有机锡催化剂的可固化组合物，其具有良好的伸长率，挠性，表面固化性，深部固化性和粘合性。 具体而言，公开了一种固化性组合物，其含有（A）具有下述通式（1）所示的含硅基团的有机聚合物：-SiR1X2，该聚合物可通过形成硅氧烷键而交联;（B）脒化合物 B-1）作为硅烷醇缩合催化剂，和（C）羧酸。 在该可固化组合物中，组分（B-1）中氮原子的总摩尔数（b）与组分（C）中羧基的总摩尔数（c）之比（（b）/（c） ））高于2。

公开(公告)号：EP1985666A4

公开(公告)日：2009-07-22

申请号：EP07714031

申请日：2007-02-09

Applicant: KANEKA CORP

Inventor： NORO NORIKO ,  WAKABAYASHI KATSUYU ,  OKAMOTO TOSHIHIKO

IPC: C08L101/10 ,  C08K5/09 ,  C08K5/31 ,  C08L23/26 ,  C08L33/14 ,  C08L71/02 ,  C09J123/00 ,  C09J133/04 ,  C09J171/02 ,  C09J201/10 ,  C09K3/10

CPC classification number: C09K3/1018 ,  C08G65/336 ,  C08K5/0016 ,  C08K5/31 ,  C08L71/02 ,  C08L101/10 ,  C08L2666/22 ,  C09D201/10 ,  C09J133/14

Abstract: The present invention has its object to provide a curable composition which comprises a guanidine compound as a non-organotin type catalyst, is less discolored, has good surface curability, depth curability, strength rise and adhesiveness, and can retain the curability even after storage; the above object can be achieved by a curable composition which comprises: (A) an organic polymer containing a silyl group capable of crosslinking under siloxane bond formation, the silyl group being a group represented by the general formula (1): -SiX 3 (1) (wherein X represents a hydroxyl group or a hydrolyzable group and the three X groups may be mutually the same or different), (B) a guanidine compound (B-1) as a silanol condensation catalyst, and (C) a plasticizer, wherein the content of the component (B-1) is not lower than 0.1 part by weight but lower than 8 parts by weight per 100 parts by weight of the component (A), and a non-phthalate ester plasticizer accounts for 80 to 100% by weight of the (C) component plasticizer.

Abstract translation: 公开了使用脒化合物作为非有机锡催化剂的可固化组合物，其具有良好的伸长率，挠性，表面固化性，深部固化性和粘合性。 具体而言，公开了一种固化性组合物，其含有（A）具有下述通式（1）所示的含硅基团的有机聚合物：-SiR1X2，该聚合物可通过形成硅氧烷键而交联;（B）脒化合物 B-1）作为硅烷醇缩合催化剂，和（C）羧酸。 在该可固化组合物中，组分（B-1）中氮原子的总摩尔数（b）与组分（C）中羧基的总摩尔数（c）之比（（b）/（c） ））高于2。

公开(公告)号：EP1992665A1

公开(公告)日：2008-11-19

申请号：EP07714033.3

申请日：2007-02-09

Applicant: Kaneka Corporation

Inventor： YANO, Ayako c/o KANEKA CORPORATION ,  NORO, Noriko c/o KANEKA CORPORATION ,  OKAMOTO, Toshihiko c/o KANEKA CORPORATION

IPC: C08L101/10 ,  C08K5/00 ,  C08K5/31 ,  C08L23/26 ,  C08L33/14 ,  C08L71/02 ,  C09J123/26 ,  C09J133/04 ,  C09J143/04 ,  C09J171/02 ,  C09J201/10 ,  C09K3/10

CPC classification number: C09K3/1018 ,  C08G65/336 ,  C08K5/0016 ,  C08K5/31 ,  C08L71/02 ,  C08L101/10 ,  C08L2666/22 ,  C09D201/10 ,  C09J133/14

Abstract: The present invention ha's its object to provide a curable composition which shows practical level of curability, without using any toxic organotin type curing catalyst. Further, The present invention has its object to provide a curable composition which has good tensile characteristics and good weather resistance while retaining practical levels of surface curability and depth curability; the above objects can be achieved by a curable composition which comprises: (A) 1 to 80 parts by weight of an organic polymer containing a reactive silyl group such as an alkyldialkoxysilyl group in a molecule; (B) 99 to 20 parts by weight of an organic polymer containing a reactive silyl group such as an alkyldialkoxysilyl group in a molecule, and having a main chain skeleton comprising a repeating unit different from that of the component (A); and (C) 0.1 to 30 parts by weight of a guanidine compound per 100 parts by weight of the sum of the component (A) and the component (B).

Abstract translation: 本发明的目的是提供不使用任何毒性有机锡型固化催化剂而显示出实用水平的固化性的可固化组合物。 此外，本发明的目的在于提供一种固化性组合物，其具有良好的拉伸特性和良好的耐候性，同时保持实用水平的表面固化性和深度固化性; （A）1-80重量份分子中含有反应性甲硅烷基如烷基二烷氧基甲硅烷基的有机聚合物; （B）分子内含有烷基二烷氧基甲硅烷基等具有反应性甲硅烷基的有机聚合物99〜20重量份，且具有与构成要素（A）不同的重复单元的主链骨架。 和（C）每100重量份组分（A）和组分（B）之和0.1至30重量份胍化合物。