摘要:
A process for the preparation of pentavalent vanadium compounds by reprocessing acid extracts of vanadium-containing catalysts spent in the hydrotreatment of crude or residual oils, characterized in the extracts containing trivalent and tetravalent vanadium are oxidized at a pH between 0.5 and 2.6 with an oxygen-containing gas to form concentrates of tetravalent vanadium, after which oxidation is carried out at a pH between 2.6 and 4.0 with an oxygen-containing gas to form concentrates of pentavalent vanadium and in that solid vanadium compounds are subsequently recovered by separating them from the liquid phase.
摘要:
A synthetic zeolite material, designated zeolite Nu-13, is a member of the ZSM-12 family of zeolites and is prepared from an aqueous reaction mixture containing the oxide X0 2 , the oxide Y 2 0 3 and a piperazine compound where X is silicon or germanium and Y is aluminium, gallium, boron, iron, chromium, vanadium, molybdenum, arsenic, antimony or manganese.
摘要翻译:称为沸石Nu-13的合成沸石材料是ZSM-12沸石家族的成员,并由含有氧化物XO 2,氧化物Y 2 O 3和哌嗪化合物的含水反应混合物制备,其中X是硅或锗,Y 是铝,镓,硼,铁,铬,钒,钼,砷,锑或锰。
摘要:
A synthetic zeolite material, designated zeolite FU9, having a molar composition expressed by the formula 0.5 to 1.5 R 2 0 : Y 2 O 3 : 15 to 30 X0 2 : 0 to 500 H 2 0, in which R is a monovalent cation or 1/n of a cation of valency n, X is silicon and/or germanium, Y is one or more of aluminium, iron, chromium, vanadium, molybdenum, arsenic, manganese, gallium or boron, and H 2 O is water of hydration additional to water notionally present when R is H, and having an X-ray diffraction pattern, the most significant lines of which are zeolite FU9 being a useful catalyst for xylenes isomerisation and the like. The zeolite is prepared starting from an aqueous reaction mixture containing at least one tetramethyl ammonium compound (TMA). Molar composition: XO 2 /Y 2 O 3 = 5-50 free MO 2 /XO 2 = 0.1-10 Z - /Y 2 O 3 = 0-5000 O/Y 2 O 3 = 01-150 H 2 0/X0 2 = 5-20Q, in which X and Y have the above-mentioned meanings, M is an alkali metal or ammonium, Z - is a strong acid radical and Q = (TMA) 2 + xA in which A is a trialkyl amine or alkanol amine or salt thereof and x is 0,2 to 2,0 moles.
摘要翻译:称为沸石FU9的合成沸石材料具有由式0.5至1.5表示的摩尔组成:R20:Y2O3:15至30 XO2:0至500 H20,其中R是单价阳离子或1 / n价态阳离子 n,X是硅和/或锗,Y是铝,铁,铬,钒,钼,砷,锰,镓或硼中的一种或多种,并且H 2是除了当R为H时在概念上存在的水之外的水合水, 并具有X射线衍射图,其中最显着的线是沸石FU9,它是用于二甲苯异构化等的有用催化剂。 沸石从含有至少一种四甲基铵化合物(TMA)的含水反应混合物开始制备。 摩尔组成:XO 2 / Y 2 O 3 = 5-50游离MO 2 / XO 2 = 0.1-10Z- / Y 2 O 3 = 0-5000O / Y 2 O 3 = 01-150H 2 O / XO 2 = 5-20Q,其中X和Y具有上述式 M是碱金属或铵,Z-是强酸基,Q =(TMA)2 + xA,其中A是三烷基胺或链烷醇胺或其盐,x是0.2-2.0 摩尔。
摘要:
A fluidized bed reactor system comprises a vessel (10) adapted to contain a fluidized bed, a plurality of fluid injector means (24) mounted through the vessel wall (20) for injecting and distributing a fluidizing medium into the lower portion of the vessel, each injector means being made up of an elongated injector having a nozzle end (26) projecting into the vessel. The injector is withdrawably mounted through the vessel wall and has at least one downwardly directed orifice (28). Shield means (32) are provided which are mounted on the vessel wall above the injector extending along the length of the injector for maintaining an opening in the bed when the injector is withdrawn. The opening is substantially equivalent to the length of the injector. The reactor system further includes fluid supply means (48) in fluid communication with each elongated injector (24) for supplying the fluidizing medium to each nozzle end (26). When it is required to replace the injector due, for example, to clogging of the orifices or deterioration, the injector is withdrawn from the vessel, replaced or repaired and then inserted into the vessel, The shield means allows for the easy insertion of the injector into the vessel by maintaining an opening in the bed, whether fluidized or non-fluidized. The fluidized bed reactor system allows for the replacement or repair of injectors without the necessity for shutting down and/or cleaning out the vessel.
摘要:
An improved process for the production of vanadium chlorides is provided wherein vanadium oxide is reacted with chlorine and reactant carbon to produce substantially pure vanadium chlorides and an effluent stream containing vanadium chlorides and unreacted chlorine and the effluent stream is contacted with adsorptive carbon to adsorb the vanadium chlorides and chlorine in the effluent and the adsorptive carbon containing the adsorbed vanadium chlorides and chlorine is recycled as reactant carbon. In the process vanadium oxide and chlorine are fed to a reactor (22) containing reactant carbon in fluidized form. The reaction mixture is fed via a cyclone (34) first to a condensers (36) and (40). The gaseous material from condenser (40) forms a part of an effluent stream (66). The effluent stream (66) is passed through an adsorber (68) containing adsorptive carbon. The adsorptive carbon having adsorbed therein vanadium chlorides and chlorine is passed to a storage area (78) where it is mixed with make up reactant carbon and recycled as reactant carbon.
摘要:
The present invention relates to a method for manufacturing a crystalline oxidic compound comprising an alkaline metal and a valve metal, to a crystalline oxidic compound as obtained by the method, and to its use as a ferroelectric material; as a coating material for electrode materials in batteries, specifically in solid-state batteries; or in digital printing, especially on a polymeric substrate. Herein, the method for manufacturing a crystalline oxidic compound comprising an alkaline metal and a valve metal comprises the following steps: a) mixing an alcoholate of an alkaline metal and an alcoholate of a valve metal in a composition of an oxygenated organic solvent and hydrogen peroxide at room temperature; b) adding an acid selected from at least one of nitric acid or hydrochloric acid at room temperature, whereby a solution is obtained; c) drying the solution at an elevated temperature of 50 °C to 150 °C, whereby a powder comprising the at least one crystalline oxidic compound comprising the alkaline metal and the valve metal is obtained. This manufacturing method operates at a low ambient working temperature, especially below 200 °C, and, thus, allows a direct manufacturing of crystalline oxidic compounds without interaction with a substrate and/or on a substrate which is not capable of tolerating higher temperatures during the manufacturing of crystalline oxidic compounds without deformation and/or deterioration. A further advantage of the low ambient working temperature is that a diffusion of elements from the at least one crystalline oxidic compound as coating material into the substrate can be avoided.
摘要:
An object is to provide an electrode active material that can provide an alkali metal battery having a longer charge/discharge life and a higher capacity. The problem is solved by means of an electrode active material for an alkali metal battery, represented by formula: A a1 MS a2 X a3 wherein A is selected from Li and Na; M is selected from V, Nb, Ta, Ti, Zr, Hf, Cr, Mo, and W which are group 4 to 6 elements; X is selected from F, Cl, Br, I, CO 3 , SO 4 , NO 3 , BH 4 , BF 4 , PF 6 , ClO 4 , CF 3 SO 3 , (CF 3 SO 2 ) 2 N, (C 2 F 5 SO 2 ) 2 N, (FSO 2 ) 2 N, and [B(C 2 O 4 ) 2 ]; a1 is 1 to 9; a2 is 2 to 6; when a3 is 3 and a3 is 0, a2 is not 4; and when M does not include V, a3 > 0.