Zeolites
    154.
    发明公开
    Zeolites 失效
    沸石

    公开(公告)号:EP0055529A1

    公开(公告)日:1982-07-07

    申请号:EP81305735.3

    申请日:1981-12-04

    摘要: A synthetic zeolite material, designated zeolite FU9, having a molar composition expressed by the formula 0.5 to 1.5 R 2 0 : Y 2 O 3 : 15 to 30 X0 2 : 0 to 500 H 2 0, in which R is a monovalent cation or 1/n of a cation of valency n, X is silicon and/or germanium, Y is one or more of aluminium, iron, chromium, vanadium, molybdenum, arsenic, manganese, gallium or boron, and H 2 O is water of hydration additional to water notionally present when R is H, and having an X-ray diffraction pattern, the most significant lines of which are zeolite FU9 being a useful catalyst for xylenes isomerisation and the like.
    The zeolite is prepared starting from an aqueous reaction mixture containing at least one tetramethyl ammonium compound (TMA). Molar composition: XO 2 /Y 2 O 3 = 5-50 free MO 2 /XO 2 = 0.1-10 Z - /Y 2 O 3 = 0-5000 O/Y 2 O 3 = 01-150 H 2 0/X0 2 = 5-20Q, in which X and Y have the above-mentioned meanings, M is an alkali metal or ammonium, Z - is a strong acid radical and Q = (TMA) 2 + xA in which A is a trialkyl amine or alkanol amine or salt thereof and x is 0,2 to 2,0 moles.

    摘要翻译: 称为沸石FU9的合成沸石材料具有由式0.5至1.5表示的摩尔组成:R20:Y2O3:15至30 XO2:0至500 H20,其中R是单价阳离子或1 / n价态阳离子 n,X是硅和/或锗,Y是铝,铁,铬,钒,钼,砷,锰,镓或硼中的一种或多种,​​并且H 2是除了当R为H时在概念上存在的水之外的水合水, 并具有X射线衍射图,其中最显着的线是沸石FU9,它是用于二甲苯异构化等的有用催化剂。 沸石从含有至少一种四甲基铵化合物(TMA)的含水反应混合物开始制备。 摩尔组成:XO 2 / Y 2 O 3 = 5-50游离MO 2 / XO 2 = 0.1-10Z- / Y 2 O 3 = 0-5000O / Y 2 O 3 = 01-150H 2 O / XO 2 = 5-20Q,其中X和Y具有上述式 M是碱金属或铵,Z-是强酸基,Q =(TMA)2 + xA,其中A是三烷基胺或链烷醇胺或其盐,x是0.2-2.0 摩尔。

    A fluidized bed reactor system
    155.
    发明公开
    A fluidized bed reactor system 失效
    流化床反应器系统

    公开(公告)号:EP0019422A3

    公开(公告)日:1981-01-07

    申请号:EP80301506

    申请日:1980-05-08

    IPC分类号: B01J08/18 C01G31/04

    CPC分类号: C01G31/04 B01J8/1818

    摘要: A fluidized bed reactor system comprises a vessel (10) adapted to contain a fluidized bed, a plurality of fluid injector means (24) mounted through the vessel wall (20) for injecting and distributing a fluidizing medium into the lower portion of the vessel, each injector means being made up of an elongated injector having a nozzle end (26) projecting into the vessel. The injector is withdrawably mounted through the vessel wall and has at least one downwardly directed orifice (28). Shield means (32) are provided which are mounted on the vessel wall above the injector extending along the length of the injector for maintaining an opening in the bed when the injector is withdrawn. The opening is substantially equivalent to the length of the injector. The reactor system further includes fluid supply means (48) in fluid communication with each elongated injector (24) for supplying the fluidizing medium to each nozzle end (26). When it is required to replace the injector due, for example, to clogging of the orifices or deterioration, the injector is withdrawn from the vessel, replaced or repaired and then inserted into the vessel, The shield means allows for the easy insertion of the injector into the vessel by maintaining an opening in the bed, whether fluidized or non-fluidized. The fluidized bed reactor system allows for the replacement or repair of injectors without the necessity for shutting down and/or cleaning out the vessel.

    Improved process for producing vanadium chlorides
    156.
    发明公开
    Improved process for producing vanadium chlorides 失效
    Verfahren zur Herstellung von Vanadium chloriden。

    公开(公告)号:EP0003436A1

    公开(公告)日:1979-08-08

    申请号:EP79300132.2

    申请日:1979-01-26

    IPC分类号: C01G31/04

    CPC分类号: C01G31/04

    摘要: An improved process for the production of vanadium chlorides is provided wherein vanadium oxide is reacted with chlorine and reactant carbon to produce substantially pure vanadium chlorides and an effluent stream containing vanadium chlorides and unreacted chlorine and the effluent stream is contacted with adsorptive carbon to adsorb the vanadium chlorides and chlorine in the effluent and the adsorptive carbon containing the adsorbed vanadium chlorides and chlorine is recycled as reactant carbon.
    In the process vanadium oxide and chlorine are fed to a reactor (22) containing reactant carbon in fluidized form. The reaction mixture is fed via a cyclone (34) first to a condensers (36) and (40). The gaseous material from condenser (40) forms a part of an effluent stream (66). The effluent stream (66) is passed through an adsorber (68) containing adsorptive carbon. The adsorptive carbon having adsorbed therein vanadium chlorides and chlorine is passed to a storage area (78) where it is mixed with make up reactant carbon and recycled as reactant carbon.

    摘要翻译: 提供了一种用于生产氯化钒的改进方法,其中氧化钒与氯和反应物碳反应以产生基本上纯的氯化钒和含有氯化钒和未反应的氯的流出物流,并且流出物流与吸附碳接触以吸附钒 流出物中的氯化物和氯以及含有吸附的氯化钒和氯的吸附碳被再循环作为反应物碳。 在该方法中,将氧化钒和氯加入到含有流化形式的反应物碳的反应器(22)中。 反应混合物首先通过旋流器(34)进料至冷凝器(36)和(40)。 来自冷凝器(40)的气态物质形成流出物流(66)的一部分。 流出物流(66)通过含有吸附碳的吸附器(68)。 吸附有氯化钒和氯的吸附碳被传送到存储区域(78),在该区域与补充反应物碳混合并作为反应物碳再循环。

    A METHOD FOR MANUFACTURING A CRYSTALLINE OXIDIC COMPOUND

    公开(公告)号:EP4186865A1

    公开(公告)日:2023-05-31

    申请号:EP21210780.9

    申请日:2021-11-26

    摘要: The present invention relates to a method for manufacturing a crystalline oxidic compound comprising an alkaline metal and a valve metal, to a crystalline oxidic compound as obtained by the method, and to its use as a ferroelectric material; as a coating material for electrode materials in batteries, specifically in solid-state batteries; or in digital printing, especially on a polymeric substrate.
    Herein, the method for manufacturing a crystalline oxidic compound comprising an alkaline metal and a valve metal comprises the following steps:
    a) mixing an alcoholate of an alkaline metal and an alcoholate of a valve metal in a composition of an oxygenated organic solvent and hydrogen peroxide at room temperature;
    b) adding an acid selected from at least one of nitric acid or hydrochloric acid at room temperature, whereby a solution is obtained;
    c) drying the solution at an elevated temperature of 50 °C to 150 °C, whereby a powder comprising the at least one crystalline oxidic compound comprising the alkaline metal and the valve metal is obtained.
    This manufacturing method operates at a low ambient working temperature, especially below 200 °C, and, thus, allows a direct manufacturing of crystalline oxidic compounds without interaction with a substrate and/or on a substrate which is not capable of tolerating higher temperatures during the manufacturing of crystalline oxidic compounds without deformation and/or deterioration. A further advantage of the low ambient working temperature is that a diffusion of elements from the at least one crystalline oxidic compound as coating material into the substrate can be avoided.