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    VERFAHREN ZUR HERSTELLUNG VON BENZOL AUS METHAN
    13.
    发明公开
    VERFAHREN ZUR HERSTELLUNG VON BENZOL AUS METHAN 审中-公开
    VERFAHREN ZUR HERSTELLUNG冯BENZOL AUS METHAN

    公开(公告)号：EP2473463A2

    公开(公告)日：2012-07-11

    申请号：EP10747846.3

    申请日：2010-08-23

    Applicant: BASF SE

    Inventor： SCHNEIDER, Christian ,  KARCHES, Martin ,  TSOU, Joana, Coelho ,  AHRENS, Sebastian ,  STÜTZER, Dieter

    IPC: C07C2/76 ,  C07C15/02

    CPC classification number: C07C2/76 ,  Y02P20/584 ,  C07C15/02

    Abstract: The present invention relates to a process for the non-oxidative dehydroaromatization of a feed stream containing C1-C4 aliphatics comprising the steps I, feeding the feed stream E into a reaction zone 1, reacting the feed stream E under non-oxidative conditions in the presence of a particulate catalyst to give a product stream P containing aromatic hydrocarbons, and removing the product stream P from the reaction zone 1; II, transferring the catalyst that is reduced in its activity by deposited coke into a reaction zone 2; III, at least partial regeneration of the catalyst with feed of a hydrogen-containing gas stream H in a reaction zone 2, wherein at least some of the deposited coke is converted into methane and a methane-containing gas stream M is formed that is fed at least in part to the reaction zone 1; IV, removing the catalyst from the reaction zone 2 and V, recirculating at least some of the catalyst that is removed to the reaction zone 1, wherein reaction zone 1 and reaction zone 2 are arranged spatially adjacently in the same reactor.

    Abstract translation: 本发明涉及一种使含有C 1 -C 4脂族化合物的反应物流非氧化脱氢芳构化的方法，包括以下步骤：将反应物流E加入到反应区1中，在非氧化条件下在颗粒催化剂存在下将反应物流E转化 涉及包含芳烃并从反应区1排出产物流P的产物流P，II。 由于沉积的焦炭进入反应区域2，III而导致活性降低的催化剂。 在反应区2中供应含氢气流H至少部分地再生催化剂，至少部分沉积的焦炭转化成甲烷以形成含甲烷的气流M，其至少部分地进料至反应 区域1，IV。 将催化剂从反应区2排出，并将至少一部分排出的催化剂再循环到反应区1中，反应区1和反应区2在相同的反应器中彼此空间上相邻布置。

    VERFAHREN ZUR HERSTELLUNG VON CHLOR AUS HCI
    19.
    发明公开
    VERFAHREN ZUR HERSTELLUNG VON CHLOR AUS HCI 有权
    用于生产氯FROM HCI

    公开(公告)号：EP2445831A1

    公开(公告)日：2012-05-02

    申请号：EP10725697.6

    申请日：2010-06-17

    Applicant: BASF SE

    Inventor： KARCHES, Martin ,  BACHMANN, Kati ,  SESING, Martin ,  SEIDEMANN, Lothar ,  JACOBSEN, Knud

    IPC: C01B7/04

    CPC classification number: C01B7/04

    Abstract: The invention relates to a method for producing chlorine by the oxidation of hydrogen chloride with oxygen in a fluidized bed reactor in the presence of a particulate catalyst, the reaction heat produced by the exothermic hydrogen chloride oxidation being carried away by water which circulates in the tubes of a shell-and-tube heat exchanger. The method comprises the following steps: (i) heating the fluidized bed reactor to an operating temperature in the range of 350 to 420°C in a heating phase and (ii) reacting the hydrogen chloride with oxygen at the operating temperature in an operating phase. The method is characterized in that (i-1) the fluidized bed reactor is heated to a temperature below the operating temperature in a first heating phase, and (i-2) hydrogen chloride and oxygen are fed to the fluidized bed reactor and reacted in a second heating phase, the fluidized bed reactor being heated to the operating temperature by the reaction heat produced by the exothermic hydrogen chloride oxidation.

    VERFAHREN ZUR HERSTELLUNG VON CHLOR
    20.
    发明授权
    VERFAHREN ZUR HERSTELLUNG VON CHLOR 有权
    用于生产氯

    公开(公告)号：EP1866239B1

    公开(公告)日：2012-01-18

    申请号：EP06743192.4

    申请日：2006-02-20

    Applicant: BASF SE

    Inventor： SESING, Martin ,  DIEFENBACHER, Armin ,  VOSS, Hartwig ,  SCHUBERT, Olga ,  SEIDEMANN, Lothar ,  KARCHES, Martin ,  GRASSLER, Thomas ,  STROEFER, Eckhard

    IPC: C01B7/04

    CPC classification number: C01B7/075 ,  C01B7/04 ,  C01B7/0743

    Abstract: The invention concerns a method for producing chlorine and a hydrochloric gas including the following steps: a) supplying via a stream containing hydrochloric gas (a1) and a stream containing oxygen (a2) an oxidation zone and a hydrochloric gas catalytic oxidation with chlorine, a stream of gaseous product (a3) containing chlorine, water, oxygen, carbon dioxide, and the inert gases obtained; b) cooling the stream of gaseous products (a3) and separating the water from the hydrochloric gas in the form of hydrochloric acid, a gas stream (b) containing chlorine, water, oxygen, carbon dioxide, and the inert gases still remaining; c) optionally drying the gas stream (b), and obtaining a gas stream (c) substantially water-free, containing chlorine, oxygen, carbon dioxide and inert gases; d) liquefying at least partly the gas stream (c) and a return stream (f1) rich in chlorine, containing chlorine, oxygen, carbon dioxide through thickening and cooling, a partly liquefied stream (d) being preserved; e) gas-liquid separation of the stream (d) into a gas stream (e1) containing chlorine, oxygen, carbon dioxide, and inert gases and into a liquid stream (e2) containing chlorine, oxygen, and carbon dioxide; f) introducing at least part of the gas stream (e1) into a unit with membrane and separating a return stream (f1) rich in chlorine and a gas flow (f2) poor in chlorine, containing chlorine, oxygen, carbon dioxide, via a separation by the membrane and reintroducing the return flux (f1) rich in chlorine in step d); g) separating the liquid stream (e2) by distillation into a stream of chlorine (g1) and a stream (g2) comprising substantially oxygen and carbon dioxide.

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